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化学进展 2013, Vol. 25 Issue (07): 1113-1121 DOI: 10.7536/PC121153 前一篇   后一篇

• 综述与评论 •

新型多孔氮化硼材料

刘栋1,2, 唐成春1*, 薛彦明1, 李杰1   

  1. 1. 河北工业大学材料科学与工程学院 天津 300130;
    2. 河北联合大学化学工程学院 唐山 063009
  • 收稿日期:2012-11-01 修回日期:2013-01-01 出版日期:2013-07-25 发布日期:2013-04-16
  • 通讯作者: 唐成春 E-mail:tangcc@hebut.edu.cn
  • 基金资助:

    973计划前期研究专项(No. 2011CB612301)、国家自然科学基金项目(No. 10974041)和河北省杰出青年基金项目(No. E2011202145)资助

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New Porous Boron Nitride Materials

Liu Dong1,2, Tang Chengchun1*, Xue Yanming1, Li Jie1   

  1. 1. School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300130, China;
    2. College of Chemical Engineering, Hebei United University, Tangshan 063009, China
  • Received:2012-11-01 Revised:2013-01-01 Online:2013-07-25 Published:2013-04-16

多孔氮化硼材料是一种新型多孔非氧化物材料,具有高比表面积、可调孔径、良好的化学惰性和热稳定性等特点,在催化、储氢、气体吸附和分离等领域具有巨大的应用潜力,是材料领域研究热点之一。依孔径的不同,多孔氮化硼材料被分为微孔氮化硼、介孔氮化硼、大孔氮化硼和多级孔氮化硼。本文综述了微孔、介孔、大孔及多级孔等类型氮化硼材料的研究进展。重点介绍了不同类型氮化硼材料的制备和性能,并分析了各种制备方法的优缺点,最后探讨了多孔氮化硼材料的发展前景。

关键词： 多孔氮化硼, 模板合成, 高压反应合成, 催化剂载体

As a new porous non-oxide material, porous boron nitride has attracted increasing interests due to its plenty of unique properties such as large specific surface area, tunable pore size, excellent chemical inertness and thermal stability, which are useful in catalysis, hydrogen storage, gas adsorption and separation. Based on the different pore sizes, porous boron nitride is divided into four types, namely, microporous boron nitride, mesoporous boron nitride, macroporous boron nitirde and hierarchical boron nitride. In this review, recent development of porous boron nitride with different structures is summarized. The synthesis and properties of different types of boron nitride are emphatically described, and the advantages and disadvantages of various synthesis methods are discussed. Finally, the promising applications and development directions of porous boron nitride are highlighted. Contents
1 Introduction
2 Synthesis methods of porous boron nitride materials
2.1 Template synthesis
2.2 High pressure reaction synthesis
3 Microporous boron nitride materials
4 Mesoporous boron nitride materials
4.1 Ordered mesoporous boron nitride materials
4.2 Disordered mesoporous boron nitride materials
5 Macroporous boron nitride materials
6 Hierarchical porous boron nitride materials
7 Conclusion and outlook

Key words: porous boron nitride, template synthesis, high pressure reaction synthesis, catalyst carrier

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摘要

新型多孔氮化硼材料