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石墨烯纳米带

郑小青, 冯苗, 詹红兵*   

  1. 福州大学材料科学与工程学院 福州 350108
  • 收稿日期:2012-05-01 修回日期:2012-07-01 出版日期:2012-12-24 发布日期:2012-12-11
  • 通讯作者: 詹红兵 E-mail:hbzhan@fzu.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.51172045)、高等学校博士学科点专项科研基金(新教师类)项目( No.20113514120006)和福建省自然科学基金项目(No.2012J05113)资助

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Graphene Nanoribbons

Zheng Xiaoqing, Feng Miao, Zhan Hongbing*   

  1. College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China
  • Received:2012-05-01 Revised:2012-07-01 Online:2012-12-24 Published:2012-12-11
近年来,一种新型的准一维石墨烯基材料即石墨烯纳米带(graphene nanoribbons, GNRs)受到广泛关注,限域的宽度和丰富的边缘构型使其具有许多不同于二维结构大面积石墨烯的性质和应用。本文介绍了GNRs特殊的边缘效应以及由此产生的电学、磁学等特殊性质,在此基础上进一步介绍了GNRs典型的制备方法、缺陷种类、掺杂和化学改性等,并对功能化的GNRs的应用进行了展望。
关键词： 石墨烯纳米带(GNRs), 结构, 性质, 制备方法
In recent years, an interesting class of quasi one dimensional graphene-based material, known as graphene nanoribbons (GNRs), has attracted tremendous attention. Owing to the finite width and abundant edge geometries, GNRs present a lot of promising properties and applications, which are quite different from large-area graphene. In this paper we attempt to give an overview of their novel edge effect and the resulting electronic property, magnetic property, etc. We further present some typical preparation methods, defects types, doping, chemical modification and so on. We also provide an outlook of the applications of functional GNRs. Contents
1 Introduction
2 Edge effect of graphene nanoribbons
3 Properties of graphene nanoribbons
3.1 Electronic properties
3.2 Magnetic properties
3.3 Chemical reactivity
3.4 Other properties
4 Preparation of graphene nanoribbons
4.1 Etching method
4.2 Chemosynthesis
4.3 Graphene nanoribbons from carbon nanotubes
4.4 Other methods
5 Perspectives
Key words: graphene nanoribbons (GNRs), structure, property, preparation

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[1] Geim A K. Science, 2009, 324(5934): 1530-1534
[2] Gerstner E. Nat. Phys., 2010, 6(11): 836-836
[3] 徐秀娟(Xu X J), 秦金贵(Qin J G), 李振(Li Z). 化学进展(Progress in Chemistry), 2009, 21(12): 2559-2567
[4] Balog R, Jorgensen B, Nilsson L, Andersen M, Rienks E, Bianchi M, Fanetti M, Laegsgaard E, Baraldi A, Lizzit S, Sljivancanin Z, Besenbacher F, Hammer B, Pedersen T G, Hofmann P, Hornekaer L. Nat. Mater., 2010, 9(4): 315-319
[5] Wei D, Liu Y, Wang Y, Zhang H, Huang L, Yu G. Nano Lett., 2009, 9(5): 1752-1758
[6] Zhuang X D, Chen Y, Liu G, Li P P, Zhu C X, Kang E T, Neoh K G, Zhang B, Zhu J H, Li Y X. Adv. Mater., 2010, 22(15): 1731-1735
[7] Feng M, Zhan H, Chen Y. Appl. Phys. Lett., 2010, 96(3): art. no. 033103
[8] Feng M, Sun R, Zhan H, Chen Y. Nanotechnology, 2010, 21(7): 075601
[9] Wang X, Ouyang Y, Jiao L, Wang H, Xie L, Wu J, Guo J, Dai H. Nat. Nanotechnol., 2011, 6(9): 563-567
[10] Dutta S, Pati S K. J. Mater. Chem., 2010, 20(38): 8207-8223
[11] Li X, Wang X, Zhang L, Lee S, Dai H. Science, 2008, 319(5867): 1229-1232
[12] Schwierz F. Nat. Nanotechnol., 2010, 5(7): 487-496
[13] Haskins J, Knac A, Sevik C, Sevinli H, Cuniberti G, Cagn T. ACS Nano, 2011, 5(5): 3779-3787
[14] Basu D, Gilbert M J, Register L F, Banerjee S K, Macdonald A H. Appl. Phys. Lett., 2008, 92(4): art. no. 042114
[15] Wakabayashi K, Takane Y, Yamamoto M, Sigrist M. Carbon, 2009, 47(1): 124-137
[16] Querlioz D, Apertet Y, Valentin A, Huet K, Bournel A, Galdin-Retailleau S, Dollfus P. Appl. Phys. Lett., 2008, 92(4): art. no. 042108
[17] Jia X, Hofmann M, Meunier V, Sumpter B G, Campos-Delgado J, Romo-Herrera J M, Son H, Hsieh Y, Reina A, Kong J, Terrones M, Dresselhaus M S. Science, 2009, 323(5922): 1701-1705
[18] Jaiswal M, Lim C H Y X, Bao Q, Toh C T, Loh K P, Ozyilmaz B. ACS Nano, 2011, 5(2): 888-896
[19] Gunlycke D, Li J, Mintmire J W, White C T. Nano Lett., 2010, 10: 3638-3642
[20] Shemella P, Zhang Y, Mailman M, Ajayan P M, Nayak S K. Appl. Phys. Lett., 2007, 91(4): art. no. 042101
[21] Wassmann T, Seitsonen A P, Saitta A M, Lazzeri M, Mauri F. J. Am. Chem. Soc., 2010, 132: 3440-3451
[22] Kinder J M, Dorando J J, Wang H, Chan G K. Nano Lett., 2009, 9(5): 1980-1983
[23] Wang J Y, Liu Z F, Liu Z R. AIP Advances, 2012, 2: art. no. 0121031
[24] Huang B, Yan Q, Li Z, Duan W. Front. Phys. China, 2009, 4(3): 269-279
[25] Barone V, Hod O, Scuseria G E. Nano Lett., 2006, 6(12): 2748-2754
[26] Wang G. Chem. Phys. Lett., 2012, 533: 74-77
[27] Shimizu T, Haruyama J, Marcano D C, Kosinkin D V, Tour J M, Hirose K, Suenaga K. Nat. Nanotechnol., 2011, 6(1): 45-50
[28] Yu S S, Zheng W T, Wen Q B, Jiang Q. Carbon, 2008, 46: 537-543
[29] Kan E, Li Z, Yang J, Hou J G. J. Am. Chem. Soc., 2008, 130(13): 4224-4225
[30] Biel B, Triozon F, Blase X, Roche S. Nano Lett., 2009, 9(7): 2725-2729
[31] Huang B, Yan Q, Zhou G, Wu J, Liu F, Gu B, Duan W. Appl. Phys. Lett., 2007, 91(25): art. no. 253122
[32] Wu M, Wu X, Zeng X C. J. Phys. Chem. C, 2010, 114: 3937-3944
[33] Son Y, Cohen M L, Louie S G. Nature, 2006, 444(7117): 347-349
[34] Rao S S, Narayana J S, Stesmans A, Moshchalkov V V, Van T J, Kosynkin D V, Higginbotham A, Tour J M. Nano Lett., 2012, 12(3): 1210-1217
[35] Bai J, Cheng R, Xiu F, Liao L, Wang M, Shailos A, Wang K L, Huang Y, Duan X. Nat. Nanotechnol., 2010, 5(9): 655-659
[36] Kim W Y, Kim K S. Nat. Nanotechnol., 2008, 3(7): 408-412
[37] Barone V, Hod O, Scuseria G E. Nano lett., 2006, 6(12): 2748-2754
[38] Sharma R, Nair N, Strano M S. J. Phys. Chem. C, 2009, 113(33): 14771-14777
[39] Zheng Y, Xu L, Fan Z, Wei N, Huang Z. J. Mater. Chem., 2012, 22(19): 9798-9805
[40] Yang L, Cohen M L, Louie S G. Nano Lett., 2007, 7(10): 3112-3115
[41] Tapaszto L, Dobrik G, Lambin P, Biro L P. Nat. Nanotechnol., 2008, 3(7): 397-401
[42] Sprinkle M, Ruan M, Hu Y, Hankinson J, Rubio-Roy M, Zhang B, Wu X, Berger C, de Heer W A. Nat. Nanotechnol., 2010, 5(10): 727-731
[43] Masubuchi S, Ono M, Yoshida K, Hirakawa K, Machida T. Appl. Phys. Lett., 2009, 94(8): art. no. 082107
[44] Bai J, Huang Y. Mater. Sci. Eng. R, 2010, 70(3/6): 341-353
[45] Bai J, Duan X, Huang Y. Nano Lett., 2009, 9(5): 2083-2087
[46] Liu L, Zhang Y, Wang W, Gu C, Bai X, Wang E. Adv. Mater., 2011, 23: 1246-1251
[47] Shin Y, Son J Y, Jo M, Shin Y, Jang H M. J. Am. Chem. Soc., 2011, 133: 5623-5625
[48] Jia X, Campos-Delgado J, Terrones M, Meunier V, Dresselhaus M S. Nanoscale, 2011, 3(1): 86-95
[49] Campos-Delgado J, Romo-Herrera J M, Jia X, Cullen D A, Muramatsu H, Kim Y A, Hayashi T, Ren Z, Smith D J, Okuno Y, Ohba T, Kanoh H, Kaneko K, Endo M, Terrones H, Dresselhaus M S, Terrones M. Nano Lett., 2008, 8(9): 2773-2778
[50] Pan Z, Liu N, Fu L, Liu Z. J. Am. Chem. Soc., 2011, 133(44): 17578-17581
[51] Wei D, Liu Y, Zhang H, Huang L, Wu B, Chen J, Yu G. J. Am. Chem. Soc., 2009, 131(31): 11147-11154
[52] Pan M, Giro E C, Jia X, Bhaviripudi S, Li Q, Kong J, Meunier V, Dresselhaus M S. Nano Lett., 2012, 12(4): 1928-1933
[53] Cai J, Ruffieux P, Jaafar R, Bieri M, Braun T, Blankenburg S, Muoth M, Seitsonen A P, Saleh M, Feng X, Mullen K, Fasel R. Nature, 2010, 466(7305): 470-473
[54] Bjork J, Stafstrom S, Hanke F. J. Am. Chem. Soc., 2011, 133: 14884-14887
[55] Li X, Wang X, Zhang L, Lee S, Dai H. Science, 2008, 319(5867): 1229-1232
[56] Wu Z, Ren W, Gao L, Liu B, Zhao J, Cheng H. Nano Research, 2010, 3(1): 16-22
[57] Jiao L, Wang X, Diankov G, Wang H, Dai H. Nat. Nano, 2010, 5(5): 321-325
[58] Ci L, Xu Z, Wang L, Gao W, Ding F, Kelly K, Yakobson B, Ajayan P. Nano Research, 2008, 1: 116-122
[59] Campos L C, Manfrinato V R, Sanchez-Yamagishi J D, Kong J, Jarillo-Herrero P. Nano Lett., 2009, 9(7): 2600-2604
[60] Datta S S, Strachan D R, Khamis S M, Johnson A T C. Nano Lett., 2008, 8(7): 1912-1915
[61] Parashar U K, Bhandari S, Srivastava R K, Jariwala D, Srivastava A. Nanoscale, 2011, 3(9): 3876-3882
[62] Hirsch A. Angew. Chem. Int. Ed., 2009, 48(36): 6594-6596
[63] Vaughan O. Nat. Nanotechnol., 2009, 4(5): 283-283
[64] Terrones M, Botello-Méndez A R, Campos-Delgado J, López-Urías F, Vega-Cantú Y I, Rodríguez-Macías F J, Elías A L, Muñoz-Sandoval E, Cano-Márquez A G, Charlier J, Terrones H. Nano Today, 2010, 5(4): 351-372
[65] Matthias B. Surf. Sci. R., 2012, 67: 83-115
[66] Kosynkin D V, Lu W, Sinitskii A, Pera G, Sun Z, Tour J M. ACS Nano, 2011, 5(2): 968-974
[67] Kosynkin D V, Higginbotham A L, Sinitskii A, Lomeda J R, Dimiev A, Price B K, Tour J M. Nature, 2009, 458(7240): 872-876
[68] Cataldo F, Compagnini G, Patané G, Ursini O, Angelini G, Ribic P R, Margaritondo G, Cricenti A, Palleschi G, Valentini F. Carbon, 2010, 48(9): 2596-2602
[69] Higginbotham A L, Kosynkin D V, Sinitskii A, Sun Z, Tour J M. ACS Nano, 2010, 4(4): 2059-2069
[70] Shinde D B, Debgupta J, Kushwaha A, Aslam M, Pillai V K. J. Am. Chem. Soc., 2011, 1333: 4168-4171
[71] Jiao L Y, Zhang L, Wang X R, Diankov G, Dai H J. Nature, 2009, 458(7240): 877-880
[72] Fan Y, Li J, Liu X, Wang L, Chen X, Sun S, Kawasaki A, Jiang W. Carbon, 2011, 49(4): 1439-1445
[73] Morelos Gómez A, Vega-Díaz S M, González V J, Tristán-López F, Cruz-Silva R, Fujisawa K, Muramatsu H, Hayashi T, Mi X, Shi Y, Sakamoto H, Khoerunnisa F, Kaneko K, Sumpter B G, Kim Y A, Meunier V, Endo M, Muñoz-Sandoval E, Terrones M. ACS Nano, 2012, 6(3): 2261-2272
[74] Kim K, Sussman A, Zettl A. ACS Nano, 2010, 4(3): 1362-1366
[75] Ma L, Wang J, Ding F. Angew. Chem., 2012, 124(5): 1187-1190
[76] Huang X, Yin Z, Wu S, Qi X, He Q, Zhang Q, Yan Q, Boey F, Zhang H. Small, 2011, 7(14): 1876-1902
[77] Stützel E U, Burghard M, Kern K, Traversi F, Nichele F, Sordan R. Small, 2010, 6(24): 2822-2825
[78] Johnson J L, Behnam A, Pearton S J, Ural A. Adv. Mater., 2010, 22(43): 4877-4880
[79] Chitara B, Panchakarla L S, Krupanidhi S B, Rao C N R. Adv. Mater., 2011, 23(45): 5419-5424
[80] Velten J A, Carretero-Gonzalez J, Castillo-Martinez E, Bykova J, Cook A, Baughman R, Zakhidov A. J. Phys. Chem. C, 2011, 115(50): 25125-25131
[81] Yu S, Zheng W. Nanoscale, 2010, 2(7): 1069-1082
[82] Chien S, Yang Y, Chen C O. Carbon, 2012, 50(2): 421-428
[83] Xiang H, Kan E, Wei S, Whangbo M, Yang J. Nano Lett., 2009, 9(12): 4025-4030
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石墨烯纳米带