English
往期目录
新闻公告
More
化学进展 2012, Vol. 24 Issue (07): 1309-1323 前一篇   后一篇

• 综述与评论 •

POMSS配位化合物

李昂1,2, 张春玲*1, 孙国恩1, 牟建新*3   

  1. 1. 吉林大学汽车材料教育部重点实验室 材料科学与工程学院 长春 130025;
    2. 北京化工大学 化工资源有效利用国家重点实验室 北京 100029;
    3. 吉林大学化学学院 长春 130022
  • 收稿日期:2011-10-01 修回日期:2011-12-01 出版日期:2012-07-24 发布日期:2012-06-30
  • 通讯作者: 张春玲, 牟建新 E-mail:clzhang@jlu.edu.cn; jianxin_mu@yahoo.com
  • 基金资助:

    国家自然科学基金项目(No.51003037)、吉林省科技厅项目(No.20100544)和长春市科技局国际合作项目(No.2010064)资助

下载PDF ( 737 ) 引用
导出 被引次数 ( 1 )

Synthesis and Application of POMSS

Li Ang1,2, Zhang Chunling1, Sun Guoen1, Mu Jianxin3   

  1. 1. Key Laboratory of Automobile Materials of Ministry of Education, College of Materials Science and Engineering, Jilin University, Changchun 130025, China;
    2. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
    3. College of Chemistry, Jilin University, Changchun 130022, China
  • Received:2011-10-01 Revised:2011-12-01 Online:2012-07-24 Published:2012-06-30
近20年来,聚倍半硅氧烷金属配合物(POMSS)的合成、物理和化学性质以及应用,取得了飞跃式的发展,是当前的研究热点之一。其所包含的配位元素的种类几乎遍布整个元素周期表,并被广泛地应用于催化剂领域和其他功能材料领域。本文根据配位元素的特点对POMSS配合物进行了分类,并对其合成方法、发展及应用情况做了简单总结,最后对POMSS未来的研究前景进行了展望。
关键词： POSS, POMSS, 分子模型, 催化剂, 功能材料
The synthesis strategies, physical and chemical properties, as well as applications of polyhedral oligometallasilsesquioxanes(POMSS) have taken a remarkable leap in recent 20 years. It is still one of the research focuses at present. A rich chemistry of POMSS has developed with elements throughout the periodic table, that used widely as catalysts or silica-supported catalyst models and some other functional materials. In this paper, the developments and applications of POMSS are summarized and reviewed, especially for the status quo of incompletely condensed polyhedral oligomeric silsesquioxanes coordination chemistry. Contents
1 Introduction
2 Preparation of POMSS
2.1 Synthesis of POSS ligands
2.2 Synthesis strategies of POMSS
3 Developments on POMSS
3.1 Part 1:group ⅠA & ⅡA metal derivatives
3.2 Part 2:group ⅢB transition metal derivatives
3.3 Part 3:other groups transition metal derivatives
3.4 Part 4:group ⅢA-Ⅴ[KG-*3]A metal derivative
4 Application of POMSS
4.1 Catalysts
4.2 Polymer hybrid nanocomposites
4.3 Optoelectronic functional materials
5 Outlook
Key words: POSS, POMSS, molecule models, catalysts, functional materials

中图分类号: 

()
[1] Feher F J. J. Am. Chem. Soc., 1986, 108: 3850-3852
[2] Feher F J, Newman D A, Walzer J F. J. Am. Chem. Soc., 1989, 111: 1741-1748
[3] Feher F J, Weller K J. Organometallics, 1990, 9: 2638-2640
[4] Hanssen R W J M, van Santen R A, Abbenhuis H C L. Eur. J. Inorg. Chem., 2004, 4: 675-683
[5] Cordes D B, Lickiss P D, Rataboul F. Chem. Rev., 2010, 110: 2081-2173
[6] Abbenhuis H C L. Chem. Eur. J., 2000, 6: 25-32
[7] Feher F J, Budzichowski T A. Polyhedron, 1995, 14: 3239-3253
[8] Sprung M M, Guenther F O. J. Am. Chem. Soc., 1955, 77: 3990-3996
[9] Sprung M M, Guenther F O. J. Am. Chem. Soc., 1955, 77: 3996-4002
[10] Brown J F, Vogt L H. J. Am. Chem. Soc., 1965, 87: 4313-4317
[11] Brown J F. J. Am. Chem. Soc., 1965, 87: 4317-4324
[12] Voronkov M G, Lavrent'yev V I. Top. Curr. Chem., 1982, 102: 199-236
[13] Kudo T, Gordon M S. J. Am. Chem. Soc., 1998, 120: 11432-11438
[14] Kudo T, Gordon M S. J. Phys. Chem. A, 2000, 104: 4058-4063
[15] Jones R G, Wataru A, Chojnowski J. Silicon-Containing Polymers: The Science and Technology of Their Synthesis and Applications. The Netherlands: Kluwer Academic Publishers, 2000. 157-160
[16] Pescarmona P P, Maschmeyer T. Aust. J. Chem., 2001, 54: 583-596
[17] Feher F J, Budzichowski T A, Blanski R L, Weller K J, Ziller J W. Organometallics, 1991, 10: 2526-2528
[18] Lee D W, Kawakami Y. Polym. J., 2007, 39: 230-238
[19] Hoque A, Kakihana Y, Shinke S, Kawakami Y. Macromolecules, 2009, 42: 3309-3315
[20] Feher F J, Newman D A. J. Am. Chem. Soc., 1990, 112: 1931-1936
[21] Lorenz V, Edelmann F T. Adv. Organomet. Chem., 2005, 53: 101-153
[22] Annand J, Aspinall H C, Steiner A. Inorg. Chem., 1999, 38: 3941-3943
[23] Maxim N, Overweg A, Kooyman P J, van Wolput J H M C, Hanssen R W J M, van Santen R A, Abbenhuis H C L. J. Phys. Chem. B, 2002, 106: 2203-2209
[24] Lorenz V, Edelmann F T. Z. Anorg. Allg. Chem., 2004, 630: 1147-1157
[25] Lorenz V, Fischer A, Edelmann F T. Inorg. Chem. Commun., 2000, 3: 292-295
[26] Liu J C. J. Chem. Soc. Chem. Commun., 1996, 1109-1110
[27] Haddad T S, Lichtenhan J D. J. Inorg. Organomet. Polym., 1995, 5: 237-246
[28] Hanssen R W J M, Meetsma A, van Santen R A, Abbenhuis H C L. Inorg. Chem., 2001, 40: 4049-4052
[29] Lorenz V, Blaurock S, Edelmann F T. Z. Anorg. Allg. Chem., 2008, 634: 441-444
[30] Herrmann W A, Anwander R, Dufaud V, Scherer W. Angew. Chem., 1994, 106: 1338-1340; Angew. Chem. Int. Ed. Engl., 1994, 33: 1285-1286
[31] Lorenz V, Fischer A, Gieβmann S, Gilje J W, Gun'ko Y K, Jacob K, Edelmann F T. Coord. Chem. Rev., 2000, 206-207: 321-368
[32] Annand J, Aspinall H C J. Chem. Soc. Dalton Trans., 2000, 1867-1871
[33] Gun'ko Y K, Reilly R, Edelmann F T, Schmidt H G. Angew. Chem. Int. Ed., 2001, 40: 1279-1281
[34] Lorenz V, Fischer A, Edelmann F T. J. Organomet. Chem., 2002, 647: 245-249
[35] Lorenz V, Blaurock S, Hrib C G, Edelmann F T. Eur. J. Inorg. Chem., 2010, 18: 2605-2608
[36] Wu G M, Chen Y F, Xu D J, Liu J C, Sun W L, Shen Z Q. J. Organomet. Chem., 2009, 694: 1571-1574
[37] Ceyhan T, zda M A, Salih B, Erbil M K, Elmal A, zkaya A R, Bekaro lu . Eur. J. Inorg. Chem., 2008, 31: 4943-4950
[38] Feher F J, Gonzales S L, Ziller J W. Inorg. Chem., 1988, 27: 3440-3442
[39] Feher F J, Walzer J F. Inorg. Chem., 1990, 29: 1604-1611
[40] Feher F J, Budzichowski T A, Rahimian K, Ziller J W. J. Am. Chem. Soc., 1992, 114: 3859-3866
[41] Field L D, Lindall C M, Maschmeyer T, Masters A F. Aust. J. Chem., 1994, 47: 1127-1132
[42] Edelmann F T, Gieβmann S, Fischer A. J. Organomet. Chem., 2001, 620: 80-89
[43] Hay M T, Seurer B, Holmes D, Lee A. Macromolecules, 2010, 43: 2108-2110
[44] Duchateau R, Abbenhuis H C L, van Santen R A, Meetsma A, Thiele S K H, van Tol M F H. Organometallics, 1998, 17: 5663-5673
[45] Feher F J, Walzer J F, Blanski R L. J. Am. Chem. Soc., 1991, 113: 3618-3619
[46] Feher F J, Walzer J F. Inorg. Chem., 1991, 30: 1689-1694
[47] Feher F J, Blanski R L. J. Am. Chem. Soc., 1992, 114: 5886-5887
[48] Ohde C, Limberg C, Stsser R, Demeshko S. Inorg. Chem., 2010, 49: 2479-2485
[49] Fei Z F, Busse S, Edelmann F T. J. Chem. Soc. Dalton Trans., 2002, 2587-2589
[50] Belanzoni P, Rosi M, Gamellotti A. J. Mol. Struc. THEOCHEM, 2002, 579: 181-189
[51] Lorenz V, Blaurock S, Grls H, Edelmann F T. Organometallics, 2006, 25: 5922-5926
[52] García C, Gómez M, Gómez-Sal P, Hernández J M. Eur. J. Inorg. Chem., 2009, 29/30: 4401-4415
[53] Feher F J, Blanski R L. Makromol. Chem. Macromol. Symp., 1993, 66: 95-108
[54] Feher F J, Blanski R L. J. Chem. Soc. Chem. Commun., 1990, 1614-1616
[55] Feher F J, Tajima T L. J. Am. Chem. Soc., 1994, 116: 2145-2146
[56] Feher F J, Hwang T L, Schwab J J, Shaka A J, Ziller J W. Magn. Reson. Chem., 1997, 35: 730-734
[57] Blanc F, Chabanas M, Copéret C, Fenet B, Herdweck E. J. Organomet. Chem., 2005, 690: 5014-5026
[58] Blanc F, Copéret C, Thivolle-Cazat J, Basset J M, Lesage A, Emsley L, Sinha A, Schrock R R. Angew. Chem. Int. Ed., 2006, 45: 1216-1220
[59] Cho H M, Weissman H, Wilson S R, Moore J S. J. Am. Chem. Soc., 2006, 128: 14742-14743
[60] Budzichowski T A, Chacon S T, Chisholm M H, Feher F J, Streib W. J. Am. Chem. Soc., 1991, 113: 689-691
[61] Smet P, Devreese B, Verport F, Pauwels T, Svoboda I, Foro S, van Beeumen J, Verdonck L. Inorg. Chem., 1998, 37: 6583-6586
[62] Lorenz V, Blaurock S, Edelmann F T. Z. Anorg. Allg. Chem., 2008, 634: 2819-2824
[63] Riollet V, Quadrelli E A, Copéret C, Basset J M, Andersen R A, Khler K, Bttcher R M, Herdtweck E. Chem. Eur. J., 2005, 11: 7358-7365
[64] Chabanas M, Baudouin A, Copéret C, Basset J M, Lukens W, Lesage A, Hediger S, Emsley L. J. Am. Chem. Soc., 2003, 125: 492-504
[65] Dragonetti C, Carlucci L, D'Alfonso G, Lucenti E, Macchi P, Roberto D, Sironi A, Ugo R. Organometallics, 2009, 28: 2668-2676
[66] Morán M, Casado C M, Cuadrado I, Losada J. Organometallics, 1993, 12: 4327-4333
[67] Marcolli C, Calzaferri G. Appl. Organometal. Chem., 1999, 13: 213-226
[68] Casado C M, Cuadrado I, Morado M, Alonso B, Barranco M, Losada J. Appl. Organomet. Chem., 1999, 13: 245-259
[69] Lorenz V, Fischer A, Edelmann F T. Z. Anorg. Allg. Chem., 2000, 626: 1728-1730
[70] Shapley P A, Bigham W S, Hay M T. Inorg. Chim. Acta, 2003, 345: 255-260
[71] Liu F, John K D, Scott B L, Baker R T, Ott K C, Tumas W. Angew. Chem. Int. Ed., 2000, 39: 3127-3130
[72] Liu J C, Wilson S R, Shapley J R, Feher F J. Inorg. Chem., 1990, 29: 5138-5139
[73] Feher F J, Soulivong D, Eklund A G, Wyndham K D. Chem. Commun., 1997, 1185-1186
[74] Braunstein P, Galsworthy J R, Hendan B J, Marsmann H C. J. Organomet. Chem., 1998, 551: 125-131
[75] Lucenti E, Feher F J, Ziller J W. Organometallics, 2007, 26: 75-82
[76] Rattay M, Fenske D, Jutzi P. Organometallics, 1998, 17: 2930-2932
[77] Lücke S, Stoppek-Langner K, Kuchinke J, Krebs B. J. Organomet. Chem., 1999, 584: 11-15
[78] Harrison P G, Hall C. J. Sol-Gel. Sci. Tech., 1998, 13: 391-396
[79] Chen K B, Chang Y P, Yang S H, Hsu C S. Thin Solid Films, 2006, 514: 103-109
[80] Yang X H, Froehlich J D, Chae H S, Li S, Mochizuki A, Jabbour G E. Adv. Funct. Mater., 2009, 19: 2623-2629
[81] Goodgame D M L, Kealey S, Lickiss P D, White A J P. J. Mol. Struct., 2008, 890: 232-239
[82] Mintcheva N, Tanabe M, Osakada K. Organometallics, 2007, 26: 1402-1410
[83] Tanabe M, Mutou K, Mintcheva N, Osakada K. Organometallics, 2008, 27: 519-523
[84] Abbenhuis H C L, Burrows A D, Kooijman H, Lutz M, Palmer M T, van Santena R A, Spek A L. Chem. Commun., 1998, 2627-2628
[85] Quadrelli E A, Davies J E, Johnson B F G, Feeder N. Chem. Commun., 2000, 1031-1032
[86] Mintcheva N, Tanabe M, Osakada K. Organometallics, 2006, 25: 3776-3783
[87] Mintcheva N, Tanabe M, Osakada K, Georgieva I, Mihailov T, Trendaflova N. J. Organomet. Chem., 2010, 695: 1738-1743
[88] Edelmann F T, Gieβmann S, Fischer A. Inorg. Chem. Commun., 2000, 3: 658-661
[89] Ceyhan T, Yüksek M, Ya lo lu H G, Salih B, Erbil M K, Elmal A, Bekaro lu . Dalton Trans., 2008, 2407-2413
[90] Schmid G, Pugin R, Malmb J O, Bovin J O. Eur. J. Inorg. Chem., 1998, 6: 813-817
[91] Abis L, Armelao L, Dell'Amico D B, Calderazzo F, Garbassi F, Merigo A, Quadrelli E A. J. Chem. Soc. Dalton Trans., 2001, 2704-2709
[92] Hanssen R W J M. Doctoral Dissertation of Eindhoven Technische Universiteit, 2003
[93] Duchateau R, van Meerendonk W J, Huijser S, Staal B B P, van Schilt M A, Gerritsen G, Meetsma A, Koning C E, Kemmere M F, Keurentjes J T F. Organometallics, 2007, 26: 4204-4211
[94] Jones M D, Keir C G, Johnson A L, Mahon M F. Polyhedron, 2010, 29: 312-316
[95] Feher F J, Budzichowski T A, Weller K J. J. Am. Chem. Soc., 1989, 111: 7288-7289
[96] Duchateau R, Harmsen R J, Abbenhuis H C L, van Santen R A, Meetsma A, Thiele S K H, Kranenburg M. Chem. Eur. J., 1999, 5: 3130-3135
[97] Skowronska-Ptasinska M D, Duchateau R, van Santen R A, Yap G P A. Eur. J. Inorg. Chem., 2001, 1: 133-137
[98] Skowronska-Ptasinska M D, Duchateau R, van Santen R A, Yap G P A. Organometallics, 2001, 20: 3519-3530
[99] Edelmann F T, Gun'ko Y K, Giessmann S, Olbrich F, Jacob K. Inorg. Chem., 1999, 38: 210-211
[100] Feher F J, Budzichowski T A, Ziller J W. Inorg. Chem., 1997, 36: 4082-4086
[101] Gerritsen G, Duchateau R, van Santen R A, Yap G P A. Organometallics, 2003, 22: 100-110
[102] Lorenz V, Fischer A, Jacob K, Edelmann F T. Inorg. Chem. Commun., 2003, 6: 795-798
[103] Feher F J, Rahimian K, Budzichowski T A, Ziller J W. Organometallics, 1995, 14: 3920-3926
[104] Gun'ko Y K, Nagy L, Bruser W, Lorenz V, Fischer A, Gieβmann S, Edelmann F T, Jacob K, Vértes A. Monatsh. Chem., 1999, 130: 45-54
[105] Duchateau R, Dijkstra T W, Severn J R, van Santen R A, Korobkov I V. Dalton Trans., 2004, 2677-2682
[106] Hendan B J, Marsmann H C. Appl. Organometal. Chem., 1999, 13: 287-294
[107] Clark J C, Saengkerdsub S, Eldridge G T, Campana C, Barnes C E. J. Organomet. Chem., 2006, 691: 3213-3222
[108] Feher F J, Budzichowski T A. Organometallics, 1991, 10: 812-815
[109] Budzichowski T A. Doctoral Dissertation of University of California, 1991
[110] Chabanas M, Quadrelli E A, Fenet B, Copéret C, Thivolle-Cazat J, Basset J M, Lesage A, Emsley L. Angew. Chem. Int. Ed., 2001, 40: 4493-4496
[111] Feher F J, Weller K J, Ziller J W. J. Am. Chem. Soc., 1992, 114: 9686-9688
[112] Chabanas M, Quadrelli E A, Fent B, Copéret C, Thivolle-Cazat J, Basset J M, Lesage A, Emsley L. Angew. Chem. Int. Ed., 2001, 40: 4493-4496
[113] Fraile J M, García J I, Mayoral J A, Vispe E. J. Catal., 2005, 233: 90-99
[114] Duchateau R, Cremer U, Harmsen R J, Mohamud S I, Abbenhuis H C L, van Santen R A, Meetsma A, Thiele S K H, van Tol M F H, Kranenburg M. Organometallics, 1999, 18: 5447-5459
[115] Duchateau R, Abbenhuis H C L, van Santen R A, Thiele S K H, van Tol M F H. Organometallics, 1998, 17: 5222-5224
[116] Pérez Y, Quintanilla D P, Fajardo M, Sierra I, Del Hierro I. J. Mol. Catal. A-Chemical, 2007, 271: 227-237
[117] Thomas J M, Sankar G, Klunduk M C, Attfield M P, Maschmeyer T, Johnson B F G, Bell R G. J. Phys. Chem. B, 1999, 103: 8809-8813
[118] Maschmeyer T, Klunduk M C, Martin C M, Shephard D S, Thomas J M, Johnson B F G. Chem. Commun., 1997, 1847-1848
[119] Quadrelli E A, Basset J M. Coord. Chem. Rev., 2010, 254: 707-728
[120] Hay M T, Geib S J, Pettner D A. Polyhedron, 2009, 28: 2183-2186
[121] Hay M T, Geib S J. Acta Crystallogr. Sect. E-Struct., 2007, 63: M445-M446
[122] Aresta M, Fragale C, Quaranta E, Tommasi I. J. Chem. Soc. Chem. Commun., 1992, 315-317
[123] Cho H M, Weissman H, Wilson S R, Moore J S. J. Am. Chem. Soc., 2006, 128: 14742-14743
[124] Maxim N, Magusin P C M M, Kooyman P J, van Wolput J H M C, van Santen R A, Abbenhuis H C L. Chem. Mater., 2001, 13: 2958-2964
[125] Maxim N, Abbenhuis H C L, Stobbelaar P J, Mojet B L, van Santen R A. Phys. Chem. Chem. Phys., 1999, 1: 4473-4477
[126] Maxim N, Overweg A, Kooyman P J, Nagy A, van Santen R A, Abbenhuis H C L. J. Mater. Chem., 2002, 12: 3792-3798
[127] Wada K, Mitsudo T. Catal. Surv. Asia, 2005, 9: 229-241
[128] Bürgy H, Calzaferri G, Herren D, Zhdanov A. CHIMIA, 1991, 45: 3-8
[129] Duchateau R. Chem. Rev., 2002, 102: 3525-3542
[130] Guzman J, Gates B C. Dalton Trans., 2003, 3303-3318
[131] Fina A, Abbenhuis H C L, Tabuani D, Frache A, Camino G. Polym. Degrad. Stabil., 2006, 91: 1064-1070
[132] Fina A, Abbenhuis H C L, Tabuani D, Camino G. Polym. Degrad. Stabil., 2006, 91: 2275-2281
[133] Carniato F, Fina A, Tabuani D, Boccaleri E. Nanotechnology, 2008, 19: art. no. 475701
[134] Song X Y, Geng H P, Li Q F. Polymer, 2006, 47: 3049-3056
[135] 潘其维(Pan Q W), 范星河(Fan X H), 陈小芳(Chen X F), 周其凤(Zhou Q F). 化学进展(Progress in Chemistry), 2006, 18(5): 616-621
[136] Murfee H J, Thoms T P S, Greaves J, Hong B. Inorg. Chem., 2000, 39: 5209-5217
[1] 李佳烨, 张鹏, 潘原. 在大电流密度电催化二氧化碳还原反应中的单原子催化剂[J]. 化学进展, 2023, 35(4): 643-654.
[2] 邵月文, 李清扬, 董欣怡, 范梦娇, 张丽君, 胡勋. 多相双功能催化剂催化乙酰丙酸制备γ-戊内酯[J]. 化学进展, 2023, 35(4): 593-605.
[3] 徐怡雪, 李诗诗, 马晓双, 刘小金, 丁建军, 王育乔. 表界面调制增强铋基催化剂的光生载流子分离和传输[J]. 化学进展, 2023, 35(4): 509-518.
[4] 杨越, 续可, 马雪璐. 金属氧化物中氧空位缺陷的催化作用机制[J]. 化学进展, 2023, 35(4): 543-559.
[5] 叶淳懿, 杨洋, 邬学贤, 丁萍, 骆静利, 符显珠. 钯铜纳米电催化剂的制备方法及应用[J]. 化学进展, 2022, 34(9): 1896-1910.
[6] 王乐壹, 李牛. 从铜离子、酸中心与铝分布的关系分析不同模板剂制备Cu-SSZ-13的NH3-SCR性能[J]. 化学进展, 2022, 34(8): 1688-1705.
[7] 杨启悦, 吴巧妹, 邱佳容, 曾宪海, 唐兴, 张良清. 生物基平台化合物催化转化制备糠醇[J]. 化学进展, 2022, 34(8): 1748-1759.
[8] 贾斌, 刘晓磊, 刘志明. 贵金属催化剂上氢气选择性催化还原NOx[J]. 化学进展, 2022, 34(8): 1678-1687.
[9] 张明珏, 凡长坡, 王龙, 吴雪静, 周瑜, 王军. 以双氧水或氧气为氧化剂的苯羟基化制苯酚的催化反应机理[J]. 化学进展, 2022, 34(5): 1026-1041.
[10] 乔瑶雨, 张学辉, 赵晓竹, 李超, 何乃普. 石墨烯/金属-有机框架复合材料制备及其应用[J]. 化学进展, 2022, 34(5): 1181-1190.
[11] 刘洋洋, 赵子刚, 孙浩, 孟祥辉, 邵光杰, 王振波. 后处理技术提升燃料电池催化剂稳定性[J]. 化学进展, 2022, 34(4): 973-982.
[12] 沈树进, 韩成, 王兵, 王应德. 过渡金属单原子电催化剂还原CO2制CO[J]. 化学进展, 2022, 34(3): 533-546.
[13] 楚弘宇, 王天予, 王崇臣. MOFs基材料高级氧化除菌[J]. 化学进展, 2022, 34(12): 2700-2714.
[14] 景远聚, 康淳, 林延欣, 高杰, 王新波. MXene基单原子催化剂的制备及其在电催化中的应用[J]. 化学进展, 2022, 34(11): 2373-2385.
[15] 孟鹏飞, 张笑容, 廖世军, 邓怡杰. 金属/非金属元素掺杂提升原子级分散碳基催化剂的氧还原性能[J]. 化学进展, 2022, 34(10): 2190-2201.
阅读次数
全文


摘要

POMSS配位化合物