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化学进展 2012, Vol. 24 Issue (05): 769-775 前一篇   后一篇

• 综述与评论 •

含三唑-有机羧酸混合配体的配位聚合物

任红1*, 张萍2, 吴平1, 芦菲1   

  1. 1. 吉林化工学院 化学与制药工程学院 吉林 13202;
    2. 吉林大学 化学学院 长春 130012
  • 收稿日期:2011-09-01 修回日期:2011-12-01 出版日期:2012-05-24 发布日期:2012-04-10
  • 基金资助:
    国家自然科学基金项目(No.50573030)资助
下载PDF ( 1032 ) 引用
导出 被引次数 ( 3 | 1 )

Coordination Polymers Constructed from Triazole and Carboxylate Mixed Ligands

Ren Hong1*, Zhang Ping2, Wu Ping1, Lu Fei1   

  1. 1. School of Chemistry and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin 13202;
    2. Department of Chemistry, Jilin University, Changchun 130012, China
  • Received:2011-09-01 Revised:2011-12-01 Online:2012-05-24 Published:2012-04-10
配位聚合物由于具有丰富的拓扑结构,并在客体交换与分离、气体存储、手性拆分、选择性催化、分子识别、荧光和磁性等方面有潜在应用,已成为当前配位化学、材料化学和晶体工程学的热点研究领域之一。本文结合近年来本课题组的研究工作及国内外相关研究进展,概述了含三唑-有机羧酸混合配体的配位聚合物结构和性质,着重讨论了有机羧酸配体在构筑配合物结构中的作用,并对今后的研究和发展方向进行了展望。
关键词： 三唑, 脂肪类羧酸, 芳香类羧酸, 晶体结构
The research of coordination polymers remain an extremely active field of material chemistry, coordination chemistry and crystal engineering in recent years due to their various network topologies and their potential applications in many aspects such as guest exchange/separation, gas storage, chiral resolution, selective catalysis, molecular recognition, fluorescence and magnetism. This paper summarizes the recent advancement on the structure of coordination polymer containing triazolate-carboxylate mixed ligands, which focuses chiefly on the role of carboxylate ligand in the crystal structure. The future research and development of coordination polymer constructed from triazole and carboxylate are also prospcted.

Contents
1 Introduction
2 The M/trz layer pillared by carboxylate ligand to construct the 3D structure
2.1 The pillared-layer structure in the M/trz/aromatic carboxylate system
2.2 The pillared-layer structure in the M/trz/aliphatic carboxylate system
3 The network built by carboxylate ligand and M/trz through coordinative covalent bonding
3.1 The typical topological structure constructed by carboxylate ligand and M/trz
3.2 The novel topological structure constructed by carboxylate ligand and M/trz
4 The network built by carboxylate ligand and M/trz through weak intermolecular interactions
5 The properties of coordination polymers constructed from triazolate and carboxylate mixed ligands
6 Conclusion and outlook

Key words: triazole, aliphatic carboxylate, aromatic carboxylate, crystal structure

中图分类号: 

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[1] Potts K T. Chem. Rev., 1961, 61: 87—127
[2] Haasnoot J G. Coord. Chem. Rev., 2000, 200: 131—185
[3] Aromí G, Barrios L A, Roubeau O, Gamez P. Coord. Chem. Rev., 2011, 255: 485—546
[4] Hagrman P J, Bridges C, Greedan J E, Zubieta J. Dalton Trans., 1999, 2901—2903
[5] Hagrman D, Zubieta J. Chem. Comm., 1998, 2005—2006
[6] Hagrman P J, LaDuca R L, Koo H J, Rarig R, Haushalter R C, Whangbo M H, Zubieta J. Inorg. Chem., 2000, 39: 4311—4317
[7] Zhai Q G, Wu X Y, Chen S M, Zhao Z G, Lu C Z. Inorg. Chem., 2007, 46: 5046—5058
[8] Zhai Q G, Wu X Y, Chen S M, Chen L J, Lu C Z. Inorg. Chim. Acta, 2007, 360: 3484—3492
[9] Tian A X, Ying J, Peng J, Sha J Q, Su Z M, Pang H J, Zhang P P, Chen Y, Zhu M, Shen Y. Cryst. Growth Des., 2010, 10: 1104—1110
[10] Malaman B, Bagtache R, Abdmeziem K. Solid. State. Sci., 2010, 12: 1178—1182
[11] Müller-Buschbaum K, Mokaddem Y. Chem. Comm., 2006, 2060—2062
[12] Müller-Buschbaum K, Mokaddem Y. Solid. State. Sci., 2008, 10: 416—420
[13] Müller-Buschbaum K, Mokaddem Y, Hller C J. Z. Anorg. Allg. Chem., 2008, 634: 2973—2977
[14] Urakawa A, Beek W V, Monrabal-Capilla M, Galán-Mascarós J R, Palin L, Milanesio M. J. Phys. Chem. C, 2011, 115: 1323—1329
[15] Cadiau A, Martineau C, Leblanc M, Maisonneuve V, Hémon-Ribaud A, Taulelle F, Adil K. J. Mater. Chem., 2011, 21: 3949—3951
[16] Li D P, Zhou X H, Liang X Q, Li C H, Chen C, Liu J, You X Z. Cryst. Growth Des., 2010, 10: 2136—2145
[17] Zhai Q G, Zhang C C, Li S N, Jiang Y C, Hu M C. Inorg. Chem. Commun., 2011, 14: 1982—1985
[18] Ouellette W, Prosvirin A V, Chieffo V, Dunbar K R, Hudson B, Zubieta J. Inorg. Chem., 2006, 45: 9346—9366
[19] Ouellette W, Prosvirin A V, Valeich J, Dunbar K R, Zubieta J. Inorg. Chem., 2007, 46: 9067—9082
[20] Wei G, Shen Y F, Li Y R, Huang X C. Inorg. Chem., 2010, 49: 9191—9199
[21] Ouellette W, Galán-Mascarós J R, Dunbar K R, Zubieta J. Inorg. Chem., 2006, 45: 1909—1911
[22] Barea E, Diéguez A R, NavarroJ A R, D'Alfonso G, Sironi A. Dalton. Trans., 2008, 1825—1827
[23] Yin P X, Zhang J, Qin Y Y, Cheng J K, Zhao J L, Yao Y G. CrystEngComm, 2011, 13: 3536—3544
[24] Zhai Q G, Niu J P, Li S N, Jiang Y C, Hu M C, Batten S R. CrystEngComm, 2011, 13: 4508—4511
[25] Zhai Q G, Lu C Z, Chen S M, Xu X J, Yang W B. Cryst. Growth Des., 2006, 6: 1393—1398
[26] Mahata P, Prabu M, Natarajan S. Cryst. Growth Des., 2009, 9: 3683—3691
[27] Zhang J P, Lin Y Y, Huang X C, Chen X M. J. Am. Chem. Sco., 2005, 127: 5495—5506
[28] Li H L, Eddaoudi M, O'Keeffe M, Yaghi O M. Nature, 1999, 402: 276—279
[29] Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O'Keeffe M, Yaghi O M. Science, 2002, 295: 469—472
[30] Deng H X, Doonan C J, Furukawa H, Ferreira R B, Towne J, Knobler C B, Wang B, Yaghi O M. Science, 2010, 327: 836—850
[31] Rao C N R, Natarajan S, Vaidhyanathan R. Angew. Chem. Int. Ed., 2004, 43: 1466—1496
[32] Hagrman P J, Hagrman D, Zubieta J. Angew. Chem. Int. Ed., 1999, 38: 2638—2684
[33] Ouellette W, Yu M H, O'Connor C J. Angew. Chem. Int. Ed., 2006, 45: 3497—3500
[34] Krber J, Bkouche-Waksman I, Pascard C, Thomann M, Kahn O. Inorg. Chim. Acta, 1995, 230: 159—163
[35] Mahmoudi G, Morsali A, Zhu L G. Z. Anorg. Allg. Chem., 2007, 633: 539—541
[36] Ouellette W, Hudson B S, Zubieta J. Inorg. Chem., 2007, 46: 4887—4904
[37] Chowdhhuri D S, Rana A, Bera M, Zangrando E, Dalai S. Polyhedron, 2009, 28: 2131—2136
[38] Park H, Moureau D M, Parise J B. Chem. Mater., 2006, 18: 525—531
[39] Park H, Britten J F, Mueller U, Lee J Y, Li J, Parise J B. Chem. Mater., 2007, 19: 1302—1308
[40] Qin J, Qin C, Wang C X, Li H, Cui L, Li T T, Wang X L. CrystEngComm, 2010, 12: 4071—4073
[41] Ren H, Song T Y, Xu J N, Jing S B, Yang Y, Zhang P, Zhang L R. Cryst. Growth. Des., 2009, 9: 105—112
[42] Ren H, Song T Y, Lou D W, Zhang L R, Chen Y L, Zhang P, Xu J N. Inorg. Chim. Acta, 2011, 373: 79—84
[43] Lu Y C, Li X R, Zhang Z H. Chinese J. Struct. Chem., 2007, 26: 15—20
[44] Ellsworth J M, Seward K L, Smith M D, Loye H C. Solid. State. Sci., 2008, 10: 267—282
[45] Yang E C, Liang Q Q, Wang P, Zhao X J. Inorg. Chem. Commun., 2009, 12: 211—213
[46] Hulvey Z, Falcao E H L, Eckert J, Cheetham A K. J. Mater. Chem., 2009, 19: 4307—4309
[47] Yang Q, Chen S P, Gao S L. Inorg. Chem. Commun., 2009, 12: 1224—1226
[48] Zhai Q G, Li S N, Ji W J. Inorg. Chem. Commun., 2010, 13: 891—894
[49] Wang X L, Qin C, Lan Y Q, Shao K Z, Su Z M, Wang E B. Chem. Commun., 2009, 410—412
[50] Zhai Q G, Lu C Z, Wu X Y, Batten S R. Cryst. Growth. Des., 2007, 7: 2332—2342
[51] Chen Y L, Wang L, Zhang L R, Zhang D J, Jing X M, Fan Y, Ren H, Jiang J H, Zhang P, Xu J N. Inorg. Chim. Acta, 2010, 363: 3874—3879
[52] Chen Y L, Fan Y, Zhang D J, Huang L L, Jiang J H, Zhang P, Xu J N. Inorg. Chem. Commun., 2011, 14: 343—346
[53] Luo F, Che Y X, Zheng J M. CrystEngComm, 2009, 11: 1097—1102
[54] Yao J C, Mei X L, Jiang K, Li Y G, Ma L F. Inorg. Chem. Commun., 2009, 12: 941—944
[55] Liu Z Y, Wang X G, Yang E C, Zhao X J. Z. Anorg. Allg. Chem., 2008, 634: 1807—1811
[56] Liang Q Q, Liu Z Y, Yang E C, Zhao X J. Z. Anorg. Allg. Chem., 2009, 635: 2653—2659
[57] Song Z, Gao H Z, Li G H, Yu Y, Shi Z, Feng S H. CrystEngComm, 2009, 11: 1579—1584
[58] Zhang Z L, Shen G L, Cheng Y, Ding Y B, Yin Y G, Li D. CrystEngComm, 2010, 12: 1171—1174
[59] Yang E C, Liu Z Y, Shi X J, Liang Q Q, Zhao X J. Inorg. Chem., 2010, 49: 7969—7975
[60] Dinc M, Dailly A, Liu Y, Brown C M, Neumann D A, Long J R. J. Am. Chem. Soc., 2006, 128: 16876—16883
[61] Cheng L, Wang J Q, Gou S H. Inorg. Chem. Commun., 2011, 14: 261—264
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