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化学进展 2011, Vol. 23 Issue (10): 2085-2094 前一篇   后一篇

• 综述与评论 •

有机微孔聚合物研究进展

徐叔军, 梁丽芸*, 李步怡, 罗亚莉, 刘承美, 谭必恩*   

  1. 华中科技大学化学与化工学院 材料化学与服役失效湖北省重点实验室 武汉 430074
  • 收稿日期:2011-01-01 修回日期:2011-04-01 出版日期:2011-10-24 发布日期:2011-09-15
  • 作者简介:e-mail:lly720@gmail.com; bien.tan@mail.hust.edu.cn
  • 基金资助:

    教育部新世纪优秀人才支持计划项目(NCET-10-0389)和国家自然科学基金项目(No.50973037)资助

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Research Progress on Microporous Organic Polymers

Xu Shujun, Liang Liyun*, Li Buyi, Luo Yali, Liu Chengmei, Tan Bien*   

  1. Hubei Key Laboratory of Materials Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
  • Received:2011-01-01 Revised:2011-04-01 Online:2011-10-24 Published:2011-09-15

有机微孔聚合物(MOPs)是一类新型的多孔材料,具有合成方法多样、化学和物理性质稳定、孔尺寸可调控、表面可修饰等优点。近年来,MOPs在物理吸附储存气体方面表现出巨大潜力,从而在储氢和温室气体封存方面成为研究的热点之一。本文首先介绍了MOPs的结构类型及特点,分别介绍了自具微孔聚合物、超交联聚合物、共价有机网络以及共轭微孔聚合物的最新进展,分析结构与性能间的关系,并对其在催化、分离和气体储存方面的应用做了简单总结。最后对MOPs未来的研究进行了展望。

关键词： 有机微孔聚合物, 储氢材料, 孔材料

Microporous organic polymers (MOPs) are a new type of porous materials, which have advantages with synthetic diversity, chemical and physical stability, pore size controllability, and pore surface modifiability. In recent years, MOPs have attracted an enormous attention in energy gas storage and greenhouse gas capture due to their great potential physisorptive gas storage. This paper describes the structure and characteristics of MOPs. The four different kinds of MOPs, such as polymers of intrinsic microporosity (PIMs), hyper-crosslinked polymers (HCPs), covalent organic frameworks (COFs) and conjugated microporous polymers (CMPs) are introduced respectively, including the recent research progress and the relationship between structures and properties. The applications of MOPs such as catalysis, separations and gas storage are discussed briefly. We also discuss the development of MOPs in future.

Contents
1 Introduction
2 Polymers of intrinsic microporosity
2.1 Insoluble PIMs
2.2 Soluble PIMs
3 Hyper-crosslinked polymers
4 Covalent organic frameworks
5 Conjugated microporous polymers
6 Prospects

Key words: microporous organic polymers, hydrogen storage materials, porous materials

中图分类号: 

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摘要

有机微孔聚合物研究进展