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化学进展 2011, Vol. 23 Issue (5): 880-892 前一篇   后一篇

• 综述与评论 •

贵金属纳米团簇的制备及在生物检测中的应用

杨群峰, 刘建云, 陈华萍, 王显祥, 黄乾明, 单志   

  1. 四川农业大学生命科学与理学院 雅安 625014
  • 收稿日期:2010-07-01 修回日期:2010-10-01 出版日期:2011-05-24 发布日期:2011-05-04
  • 基金资助:

    四川省教育厅重点科研项目(No.08ZA053)和四川农业大学科技创新基金项目(No.00731200)资助

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导出 被引次数 ( 24 | 2 )

Preparation of Noble Metallic Nanoclusters and Its Application in Biological Detection

Yang Qunfeng, Liu Jianyun, Chen Huaping, Wang Xianxiang, Huang Qianming, Shan Zhi   

  1. College of Life and Science, Sichuan Agricultural University, Ya'an 625014, China
  • Received:2010-07-01 Revised:2010-10-01 Online:2011-05-24 Published:2011-05-04

介绍了贵金属纳米团簇(noble metallic nanoclusters, NMNCs)的研究现状及其作为一种新型荧光标记纳米材料在生物检测中的重要作用。重点总结了贵金属纳米团簇的优异性质、三种常用的制备方法(模板法、单分子层保护法和蚀刻法)及其近年来在生物传感器、生物探针、细胞标记及成像等领域的应用进展。简要评述和展望了贵金属纳米团簇的发展方向和应用前景。

关键词： 贵金属纳米团簇(NMNCs), 荧光, 生物检测, 生物探针

As a new kind of fluorescent material,noble metallic nanoclusters (NMNCs) has recently received increasing attention due to its unique characteristics, which make it good candidate for biological application especially in the field of biological detection. This review first addresses the typical characteristics of NMNCs, and then summarizes the recent developments of preparation methods of NMNCs (i.e. template method, monolayer protected method and ligand etching method) and its applications in the area of biological sensors, biological probes, cell labeling and imaging. Finally, the trends and future perspectives in this research area are outlined.

Key words: noble metallic nanoclusters (NMNCs), fluorescence, biological detection, bioprobe

中图分类号: 

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[1] 林章碧(Lin Z B), 苏星光(Su X G), 张家骅(Zhang J H), 金钦汉(Jin Q H). 分析化学(Chinese Journal of Analytical Chemistry), 2002, 2: 237-241
[2] Vosch T, Antoku Y, Hsiang J C, Richards C I, Gonzalez J I, Dickson R M. Proc. Natl. Acad. Sci. USA, 2007, 104: 12616-12621
[3] Somers R C, Bawendi M G, Nocera D G. Chem. Soc. Rev., 2007, 36: 579-591
[4] Liu W, Howarth M, Greytak A B, Zheng Y, Nocera D G, Ting A Y, Bawendi M G. J. Am. Chem. Soc., 2008, 130: 1274-1284
[5] Boeneman K, Delehanty J B, Susumu K, Stewart M H, Medintz I L. J. Am. Chem. Soc., 2010, 132: 5975-5977
[6] 刘建云(Liu J Y), 黄乾明(Huang Q M), 王显祥(Wang X X), 杨群峰(Yang Q F), 陈华萍(Chen H P). 化学进展(Progress in Chemistry), 2010, 22: 1068-1076
[7] Verberk R, Van Oijen A M, Orrit M. Phys. Rev. B, 2002, 66: art. no. 233202
[8] Derfus A M, Chan W C W, Bhatia S N. Nano Lett., 2004, 4: 11-18
[9] Zheng J, Zhang C, Dickson R M. Phys. Rev. Lett., 2004, 93: art. no. 077402
[10] Zheng J, Nicovich P R, Dickson R M. Annu. Rev. Phys. Chem., 2007, 58: 409-431
[11] Richards C I, Choi S, Hsiang J C, Antoku Y, Vosch T, Bongiorno A, Tzeng Y L, Dickson R M. J. Am. Chem. Soc., 2008, 130: 5038-5039
[12] Zheng J, Dickson R M. J. Am. Chem. Soc., 2002, 124: 13982-13983
[13] Triulzi R C, Micic M, Giordani S, Serry M, Chiou W A, Leblanc R M. Chem. Commun., 2006, 5068-5070
[14] Chen W, Tu X, Guo X. Chem. Commun., 2009, 1736-1738
[15] Lin S Y, Chen N T, Sum S P, Lo L W, Yang C S. Chem. Commun. (Camb), 2008, 4762-4764
[16] Yu J, Choi S, Richards C I, Antoku Y, Dickson R M. Photochem. Photobiol., 2008, 84: 1435-1439
[17] Guo W, Yuan J, Dong Q, Wang E. J. Am. Chem. Soc., 2010, 132: 932-934
[18] Chen S, Ingram R S, Hostetler M J, Pietron J J, Murray R W, Schaaff T G, Khoury J T, Alvarez M M, Whetten R L. Science, 1998, 280: 2098-2101
[19] Lee D, Donkers R L, Wang G, Harper A S, Murray R W. J. Am. Chem. Soc., 2004, 126: 6193-6199
[20] Crespo P, Litran R, Rojas T C, Multigner M, de la Fuente J M, Sanchez-Lopez J C, Garcia M A, Hernando A, Penades S, Fernandez A. Phys. Rev. Lett., 2004, 93: art. no. 087204
[21] Petty J T, Zheng J, Hud N V, Dickson R M. J. Am. Chem. Soc., 2004, 126: 5207-5212
[22] Lin C A J, Lee C H, Hsieh J T, Wang H H, Li J K, Shen J L, Chan W H, Yeh H I, W H Chang. J. Med. Biol. Eng., 2009, 6: 276-283
[23] Garcia-Martinez J C, Crooks R M. J. Am. Chem. Soc., 2004, 126: 16170-16178
[24] Zhang J G, Xu S Q, Kumacheva E. Adv. Mater., 2005, 17: 2336-2340
[25] Duan H, Nie S. J. Am. Chem. Soc., 2007, 129: 2412-2413
[26] Shang L, Dong S. Chem. Commun. (Camb), 2008, 1088-1090
[27] Shen Z, Duan H W, Frey H. Adv. Mater., 2007, 19: 349-352
[28] Braun E, Eichen Y, Sivan U, Ben-Yoseph G. Nature, 1998, 391: 775-778
[29] Yu J, Patel S A, Dickson R M. Angew. Chem. Int. Ed. Engl., 2007, 46: 2028-2030
[30] Neill P R O, Velazquez L R, Dunn D G, Gwinn E G, Fygenson D K. J. Phys. Chem. C, 2009, 113: 4229-4233
[31] Xie J, Zheng Y, Ying J Y. J. Am. Chem. Soc., 2009, 131: 888-889
[32] Linnert T, Mulvaney P, Henglein A, Weller H. J. Am. Chem. Soc., 1990, 112: 4657-4664
[33] Hatchett D W, Josowicz M, Janata J, Baer D R. Chem. Mater., 1999, 11: 2989-2994
[34] Wei H, Wang Z, Yang L, Tian S, Hou C, Lu Y. Analyst, 2010, 135: 1406-1410
[35] Yamane T, Davidson N. Biochimica et Biophysica Acta, 1962, 55: 609-621
[36] Daune M, Dekker C A, Schachman H K. Biopolymers, 1966, 4: 51 - 76
[37] Eichhorn G L, Butzow J J, Clark P, Tarien E. Biopolymers, 1967, 5: 283-296
[38] Ritchie C M, Johnsen K R, Kiser J R, Antoku Y, Dickson R M, Petty J T. J. Phys. Chem. C, 2007, 111: 175-181
[39] Sengupta B, Ritchie C M, Buckman J G, Johnsen K R, Goodwin P M, Petty J T. J. Phys. Chem. C, 2008, 112: 18776-18782
[40] Antoku Y. Doctoral Dissertation of Georgia Institute of Technology, 2007
[41] Gwinn E G, O'Neill P R, Guerrero A J, Bouwmeester D, Fygenson D K. Adv. Mater., 2008, 20: 279-283
[42] Gibson D W, Beer M, Barrnett R J. Biochemistry, 1971, 10: 3669-3679
[43] Ackerson C J, Jadzinsky P D, Kornberg R D. J. Am. Chem. Soc., 2005, 127: 6550-6551
[44] Gentilini C, Evangelista F, Rudolf P, Franchi P, Lucarini M, Pasquato L. J. Am. Chem. Soc., 2008, 130: 15678-15682
[45] Branham M R, Douglas A D, Mills A J, Tracy J B, White P S, Murray R W. Langmuir, 2006, 22: 11376-11383
[46] Cha S H, Kim J U, Kim K H, Lee J C. Chem. Mater., 2007, 19: 6297-6303
[47] Hou W, Dasog M, Scott R W J. Langmuir, 2009, 25: 12954-12961
[48] Porta F, Krpetic Z, Prati L, Gaiassi A, Scari G. Langmuir, 2008, 24: 7061-7064
[49] Stefanescu D M, Glueck D S, Siegel R, Wasylishen R E. Langmuir, 2004, 20: 10379-10381
[50] Brust M, Walker M, Bethell D, Schiffrin D J, Whyman R. J. Chem. Soc. Chem. Commun., 1994, 801-802
[51] Jana N R, Peng X. J. Am. Chem. Soc., 2003, 125: 14280-14281
[52] Lin C A, Yang T Y, Lee C H, Huang S H, Sperling R A, Zanella M, Li J K, Shen J L, Wang H H, Yeh H I, Parak W J, Chang W H. ACS Nano, 2009, 3: 395-401
[53] Huang C C, Yang Z, Lee K H, Chang H T. Angew. Chem. Int. Ed. Engl., 2007, 46: 6824-6828
[54] Huang C C, Liao H Y, Shiang Y C, Lin Z H, Yanga Z, Chang H T. J. Mater. Chem., 2009, 19: 755-759
[55] Negishi Y, Nobusada K, Tsukuda T. J. Am. Chem. Soc., 2005, 127: 5261-5270
[56] Aryal S, Remant B K C, Dharmaraj N, Bhattarai N, Kim C H, Kim H Y. Spectrochim. Acta A, 2006, 63: 160-163
[57] Templeton A C, Cliffel D E, Murray R W. J. Am. Chem. Soc., 1999, 121: 7081-7089
[58] Wang G, Huang T, Murray R W, Menard L, Nuzzo R G. J. Am. Chem. Soc., 2005, 127: 812-813
[59] Wang G, Guo R, Kalyuzhny G, Choi J P, Murray R W. J. Phys. Chem. B, 2006, 110: 20282-20289
[60] Yang Y, Chen S. Nano Lett., 2003, 3: 75-79
[61] Negishi Y, Tsukuda T. Chem. Phys. Lett., 2004, 383: 161-165
[62] Donkers R L, Lee D, Murray R W. Langmuir, 2004, 20: 1945-1952
[63] Kim J, Lema K, Ukaigwe M, Lee D. Langmuir, 2007, 23: 7853-7858
[64] Devadas M S, Kwak K, Park J W, Choi J H, Jun C H, Sinn E, Ramakrishna G, Lee D. J. Phys. Chem. Lett., 2010, 1: 1497-1503
[65] Shichibu Y, Negishi Y, Tsunoyama H, Kanehara M, Teranishi T, Tsukuda T. Small, 2007, 3: 835-839
[66] Woehrle G H, Warner M G, Hutchison J E. J. Phys. Chem. B, 2002, 106: 9979-9981
[67] Shichibu Y, Negishi Y, Tsukuda T, Teranishi T. J. Am. Chem. Soc., 2005, 127: 13464-13465
[68] Zhu M, Aikens C M, Hollander F J, Schatz G C, Jin R. J. Am. Chem. Soc., 2008, 130: 5883-5885
[69] Zhu M, Lanni E, Garg N, Bier M E, Jin R. J. Am. Chem. Soc., 2008, 130: 1138-1139
[70] Wu Z, Suhan J, Jin R. J. Mater. Chem., 2009, 19: 622-626
[71] Wu Z, Lanni E, Chen W, Bier M E, Ly D, Jin R. J. Am. Chem. Soc., 2009, 131: 16672-16674
[72] Zhu M, Qian H, Jin R. J. Am. Chem. Soc., 2009, 131: 7220-7221
[73] Zhu M, Qian H, Jin R. J. Phys. Chem. Lett., 2010, 1: 1003-1007
[74] Tracy J B, Kalyuzhny G, Crowe M C, Balasubramanian R, Choi J P, Murray R W. J. Am. Chem. Soc., 2007, 129: 6706-6707
[75] Huang C C, Chen C T, Shiang Y C, Lin Z H, Chang H T. Anal. Chem., 2009, 81: 875-882
[76] Kawasaki H, Yamamoto H, Fujimori H, Arakawa R, Inadab M, Iwasakia Y. Chem. Commun., 2010, 46: 3759-3761
[77] Edinger K, Golzhauser A, Demota K, Woll C, Grunze M. Langmuir, 1993, 9: 4-8
[78] Schaaff T, Whetten R. J. Phys. Chem. B, 1999, 103: 9394-9396
[79] Warner M G, Reed S M, Hutchison J E. Chem. Mater., 2000, 12: 3316-3320
[80] Woehrle G H, Hutchison J E. Inorg. Chem., 2005, 44: 6149-6158
[81] Jin R, Egusa S, Scherer N F. J. Am. Chem. Soc., 2004, 126: 9900-9901
[82] Woehrle G H, Brown L O, Hutchison J E. J. Am. Chem. Soc., 2005, 127: 2172-2183
[83] Tsunoyama H, Nickut P, Negishi Y, Al-Shamery K, Matsumoto Y, Tsukuda T. J. Phys. Chem. C, 2007, 111: 4153-4158
[84] Muhammed M A, Ramesh S, Sinha S S, Pal S K, Pradeep T. Nano Res., 2008, 1: 333-340
[85] Muhammed M A, Verma P K, Pal S K, Kumar R C, Paul S, Omkumar R V, Pradeep T. Chemistry, 2009, 15: 10110-10120
[86] Shibu E S, Radha B, Verma P K, Bhyrappa P, Kulkarni G U, Pal S K, Pradeep T. ACS Appl. Mater. Interfaces, 2009, 1: 2199-2210
[87] Zhou R J, Shi M M, Chen X Q, Wang M, Chen H Z. Chem. Eur. J., 2009, 15: 4944-4951
[88] Rao T, Pradeep T. Angew. Chem. Int. Ed., 2010, 49: 3925-3929
[89] Gazit V, Ben-Abraham R, Coleman R, Weizman A, Katz Y. Amino Acids, 2004, 26: 163-168
[90] Wang W, Rusin O, Xu X, Kim K K, Escobedo J O, Fakayode S O, Fletcher K A, Lowry M, Schowalter C M, Lawrence C M, Fronczek F R, Warner I M, Strongin R M. J. Am. Chem. Soc., 2005, 127: 15949-15958
[91] Shang L, Dong S. Biosens. Bioelectron., 2009, 24: 1569-1573
[92] Shang L, Qin C, Wang T, Wang M, Wang L, Dong S. J. Phys. Chem. C, 2007, 111: 13414-13417
[93] Tanaka F, Mase N, Barbas C F. Chem. Commun., 2004, 1762-1763
[94] Huang C C, Chiang C K, Lin Z H, Lee K H, Chang H T. Anal. Chem., 2008, 80: 1497-1504
[95] Sun X L, Cui W, Haller C, Chaikof E L. Chem. Bio. Chem., 2004, 5: 1593-1596
[96] Babu P, Sinha S, Surolia A. Bioconjug. Chem., 2007, 18: 146-151
[97] Yu J, Choi S, Dickson R M. Angew. Chem. Int. Ed., 2009, 48: 318-320
[98] Horky M, Kotala V, Anton M, Wesierska-Gadek J. Ann. N. Y. Acad. Sci., 2002, 973: 258-264
[99] Lin C A J, Lee C H, Hsieh J T, Yu W C, Yang H Z, Li J K, Sperling R, Wang H H, Yeh H I, Parak W J, Chang W H. Proc. SPIE-Int. Soc. Opt. Eng., 2010, 7575: 7575061-7575069
[100] Retnakumari A, Setua S, Menon D, Ravindran P, Muhammed H, Pradeep T, Nair S, Koyakutty M. Nanotechnology, 2009, 21: art. no. 055103
[101] Antoku Y, Hotta J, Mizuno H, Dickson R M, Hofkens J, Vosch T. Photochem. Photobiol. Sci., 2010, 9: 716-721
[102] Frangioni J V. Curr. Opin. Chem. Biol., 2003, 7: 626-634
[103] Xing Y, Rao J H. Cancer Biomarkers, 2008, 4: 307-319
[104] Zheng Y, Gao S, Ying J Y. Adv. Mater., 2007, 19: 376-380
[105] Schipper M L, Iyer G, Koh A L, Cheng Z, Ebenstein Y, Aharoni A, Keren S, Bentolila L A, Li J Q, Rao J H, Chen X Y, Banin U, Wu A M, Sinclair R, Weiss S, Gambhir S S. Small, 2009, 5: 126-134
[106] Wu X, He X X, Wang K M, Xie C, Zhou B, Qing Z H. Nanoscale, 2010, 2: 2244-2249
[107] Yeh H C, Sharma J, Han J J, Martinez J S, Werner J H. Nano Lett., 2010, 10: 3106-3110
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