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化学进展 2011, Vol. 23 Issue (0203): 449-462 前一篇   后一篇

• 综述与评论 •

单气室固体氧化物燃料电池关键材料与微堆系统

吕喆*, 魏波, 田彦婷, 王志红, 苏文辉   

  1. 哈尔滨工业大学物理系 凝聚态科学与技术研究中心 哈尔滨 150080
  • 收稿日期:2010-09-01 修回日期:2010-11-01 出版日期:2011-03-24 发布日期:2011-01-26
  • 通讯作者: e-mail:lvzhe@hit.edu.cn E-mail:lvzhe@hit.edu.cn
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Key Materials and Micro-Stack Systems of Single Chamber Solid Oxide Fuel Cells

Lü Zhe*, Wei Bo, Tian Yanting, Wang Zhihong, Su Wenhui   

  1. Center for the Condensed Matter Science and Technology, Department of Physics, Harbin Institute of Technology, Harbin 150080, China
  • Received:2010-09-01 Revised:2010-11-01 Online:2011-03-24 Published:2011-01-26

单气室固体氧化物燃料电池(SC-SOFC)是一种与传统的双气室结构燃料电池不同的新型燃料电池。SC-SOFC的阴极和阳极都暴露在单一气室中, 在工作时通入含有燃料和氧化剂的混合气体,利用阳极和阴极的选择催化作用实现发电。SC-SOFC具有结构简单、无需密封、易于进行堆叠等很多独特的优点。本文介绍了SC-SOFC近期的研究进展,内容包括工作原理的介绍、SC-SOFC的关键材料选择与研究现状、影响SC-SOFC运行的主要因素的讨论,以及微堆(电池组)系统结构设计和试验等。着重介绍了本课题组在SC-SOFC的研究工作,包括对复合阴极材料、Ni修饰氧化物阳极的研究,以及星型和阵列式等多种新型SC-SOFC微堆结构设计与实验等。最后,基于对其优缺点的分析,展望了SC-SOFC各种潜在的应用。

关键词： 单气室固体氧化物燃料电池, 关键材料, 微堆, 运行条件

Single chamber solid oxide fuel cell (SC-SOFC) is different from the conventional solid oxide fuel cell with dual gas chamber structure. Both cathode and anode of SC-SOFC are exposed to the only one gas chamber. Mixed gas containing fuel and oxidant is fed during operation and it can generate electric energy by the selectively catalytic activities of cathode and anode. SC-SOFC has many particular advatages, such as more simple structure, eliminating the need for sealing and easy stacking etc. In this paper, the recent research advances of SC-SOFC are reviewed, including brief introduction of operational principle of SC-SOFC, the selection of key materials for SC-SOFC, the discussion of main influencing factors on SC-SOFC, as well as the design and test of micro-stack (battery) system. The investigation results on SC-SOFC of our research group are highlighted, including composite cathode, oxide anode with Ni modification, and some novel designs for SC-SOFC micro stacks, such as star-type and array-type stacks, and so on. Finally, an outlook about the potential applications of SC-SOFC is given according to the analysis of its merits and drawbacks.

Key words: single chamber solid oxide fuel cells, key materials, micro-stacks, operating condition

中图分类号: 

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[1] Minh N Q. J. Am. Ceram. Soc., 1993, 76: 563-588
[2] Yano M, Tomita A, Sano M, Hibino T. Solid State Ion., 2007, 177: 3351-3359
[3] Eyraud C, Lenoir J, Gery M. Compt. Rend., 1961, 252:1599-1603
[4] Priestnall M, Kotzeva V, Fish D, Nilsson E. J. Power Sources, 2002, 106: 21-30
[5] Hibino T, Iwahara H. Chem. Lett., 1993, 22: 1131-1134
[6] Hibino T, Asano K, Iwahara H. Chem. Lett., 1993, 22: 485-488
[7] Riess I. J. Power Sources, 2008, 175: 325-337
[8] 王康(Wang K), 邵宗平(Shao Z P). 化学进展(Progress in Chemistry), 2007, 19: 267-275
[9] 魏波(Wei B), 吕喆(Lü Z), 黄喜强(Huang X Q), 刘志国(Liu Z G), 艾刚(Ai G), 苏文辉(Su W H). 电源技术(Chin. J. Power Sources), 2006, 30(3): 243-246
[10] 陈胜洲(Chen S Z), 董新法(Dong X F), 林维明(Lin W M). 电源技术(Chin. J. Power Sources), 2003, 27(2): 134-136
[11] Hibino T, Hashimoto A, Inoue T, Tokuno J, Yoshida S, Sano M. J. Electrochem. Soc., 2001, 148: A544-A549
[12] Asano K, Hibino T, Iwahara H. J. Electrochem. Soc., 1995, 142: 3241-3245
[13] Liu M L, Lü Z, Wei B, Huang X Q, Chen K F, Su W H. Electrochim. Acta, 2009, 54: 4726-4730
[14] Hibino T, Ushiki K, Kuwahara Y. Solid State Ionics, 1996, 91: 69-74
[15] Mordarski G, Suski L, Kolacz J, Ruggiero M. Pol. J. Chem., 2005, 79: 1063-1077
[16] Bay L, Horita T, Sakai N, Ishikawa M, Yamaji K, Yokokawa H. Solid State Ion., 1998, 113: 363-367
[17] Hibino T, Wang S Q, Kakimoto S, Sano M. Electrochem. Solid State Lett., 1999, 2: 317-319
[18] Hibino T, Wang S Q, Kakimoto S, Sano M. Electrochem. Solid State Lett., 1999, 2: 317-319
[19] Hibino T, Hashimoto A, Inoue T, Tokuno J, Yoshida S, Sano M. Science, 2000, 288: 2031-2033
[20] Jasinski P, Suzuki I, Dogan F, Anderson H U. Solid State Ion., 2004, 175: 35-38
[21] Shao Z P, Haile S M. Nature, 2004, 431: 170-173
[22] Suzuki T, Jasinski P, Petrovsky V, Anderson H U, Dogan F. J. Electrochem. Soc., 2004, 151: A1473-A1476
[23] Shao Z P, Mederos J, Chueh W C, Haile S M. J. Power Sources, 2006, 162: 589-596
[24] Lamas D G, Cabezas M D, Fabregas I O, de Reca N E W, Lascalea G E, Kodjaian A, Vidal M A, Amadeo N E, Larrondo S A. ECS Trans. 2007, 7: 961-970
[25] Liu M L, Lu Z, Wei B, Zhu R B, Huang X Q, Chen K F, Ai G, Su W H. J. Electrochem. Soc., 2007, 154: B588-B592
[26] Wei B, Lu Z, Huang X Q, Liu M L, Chen K F, Su W H. J. Power Sources, 2007, 167: 58-63
[27] Kuhn M, Napporn T W, Meunier M, Therriault D. Solid State Ion., 2010, 181: 332-337
[28] Ahn S J, Kim Y B, Moon J, Lee J H, Kim J. J. Power Sources, 2007, 171: 511-516
[29] Hibino T, Hashimoto A, Yano M, Suzuki M, Yoshida S, Sano M. J. Electrochem. Soc., 2002, 149: A133-A136
[30] Tomita A, Hirabayashi D, Hibino T, Nagao M, Sano M. Electrochem. Solid State Lett., 2005, 8: A63-A65
[31] Zhang C, Lin Y, Ran R, Shao Z. Int. J. Hydrogen Energ., 2010, 35: 8171-8176
[32] Demin A K, Gulbis F Y. Solid State Ion., 2000, 135: 451-456
[33] Zhan Z L, Barnett S A. Science, 2005, 308: 844-847
[34] Zhan Z L, Barnett S A. Solid State Ion., 2005, 176: 871-879
[35] Shao Z P, Haile S M, Ahn J, Ronney P D, Zhan Z L, Barnett S A. Nature, 2005, 435: 795-798
[36] Ye X F, Wang S R, Hu Q, Chen J Y, Wen T L, Wen Z Y. Solid State Ion., 2009, 180: 276-281
[37] Wang W, Su C, Wu Y Z, Ran R, Shao Z P. J. Power Sources, 2010, 195: 402-411
[38] Zhang C M, Zheng Y, Ran R, Shao Z P, Jin W Q, Xu N P, Ahn J M. J. Power Sources, 2008, 179: 640-648
[39] Zhang C M, Sun L L, Ran R, Shao Z P. Electrochem. Commun., 2009, 11: 1563-1566
[40] 艾刚(Ai G), 吕喆(Lü Z), 魏波(Wei B), 黄喜强(Huang X Q), 陈孔发(Chen K F), 苏文辉(Su W H). 催化学报(Chin. J. Catal.), 2006, 27: 885-889
[41] 吕喆(Lü Z), 艾刚(Ai G), 魏波(Wei B), 陈孔发(Chen K F), 黄喜强(Huang X Q), 朱瑞滨(Zhu R B), 诸葛淑媛(Zhuge S Y), 苏文辉(Su W H). CN 1832240, 2006
[42] Kellogg I D, Koylu U O, Petrovsky V, Dogan F. Int. J. Hydrogen Energy, 2009, 34: 5138-5143
[43] Jacques-Bedard X, Napporn T W, Roberge R, Meunier M. J. Power Sources, 2006, 153: 108-113
[44] Buergler B E, Ochsner M, Vuillemin S, Gauckler L J. J. Power Sources, 2007, 171: 310-320
[45] Tao S W, Irvine J T S. Nat. Mater., 2003, 2: 320-323
[46] 郑尧(Zheng Y), 周嵬(Zhou W), 冉然(Ran R), 邵宗平(Shao Z P). 化学进展(Progress in Chemistry), 2008, 20: 413-421
[47] Atkinson A, Barnett S, Gorte R J, Irvine J T S, McEvoy A J, Mogensen M. Nat. Mater., 2004, 3: 17-27
[48] Huang Y H, Dass R I, Xing Z L, Goodenough J B. Science, 2006, 312: 254-257
[49] Zhu X B, Zhe L, Bo W, Chen K F, Liu M L, Huang X Q, Su W H. J. Power Sources, 2010, 195: 1793-1798
[50] Zhu X B, Lu Z, Wei B, Zhang Y H, Liu M L, Huang X Q, Su W H. J. Electrochem. Soc., 2010, 157: B691-B696
[51] Zhu X B, Lu Z, Wei B, Zhang Y H, Huang X Q, Su W H. Int. J. Hydrogen Energy, 2010, 35: 6897-6904
[52] Zhu X B, Lu Z, Wei B, Huang X Q, Su W H. J. Electrochem. Soc., 2010, 157(5): B691-B696
[53] Hibino T, Wang S Q, Kakimoto S, Sano M. Solid State Ion., 2000, 127: 89-98
[54] Zhang C M, Zheng Y, Lin Y, Ran R, Shao Z P, Farrusseng D. J. Power Sources, 2009, 191: 225-232
[55] Hibino T, Hashimoto A, Inoue T, Tokuno J, Yoshida S, Sano M. J. Electrochem. Soc., 2000, 147: 2888-2892
[56] Song H S, Min J H, Kim J, Moon J. J. Power Sources, 2009, 191: 269-274
[57] Shao Z P, Kwak C, Haile S M. Solid State Ionics, 2004, 175: 39-46
[58] Pinol S. J. Fuel Cell Sci. Technol., 2006, 3: 434-437
[59] Suzuki T, Jasinski P, Anderson H U, Dogan F. J. Electrochem. Soc., 2004, 151: A1678-A1682
[60] Gaudillere C, Olivier L, Vernoux P, Zhang C M, Shao Z P, Farrusseng D. J. Power Sources, 2010, 195: 4758-4764
[61] Morel B, Roberge R, Savoie S, Napporn T W, Meunier M. Appl. Catal. A-Gen., 2007, 323: 181-187
[62] Asano K, Iwahara H. J. Electrochem. Soc., 1997, 144: 3125-3130
[63] Buergler B E, Siegrist M E, Gauckler L J. Solid State Ion., 2005, 176: 1717-1722
[64] Jasinski P, Suzuki T, Byars Z, Dogan F, Anderson H U. in Solid Oxide Fuel Cells Ⅷ(Eds. Singhal S C, Dokiya M). Pennington: Electrochemical Society Inc., 2003, 1101-1108
[65] Suzuki T, Jasinski P, Petrovsky V, Anderson H U, Dogan F. J. Electrochem. Soc., 2005, 152: A527-A531
[66] Akhtar N, Decent S P, Loghin D, Kendall K. J. Power Sources, 2009, 193: 39-48
[67] Zong W Z, Zhu Y F. Acta Phys. -Chim. Sin., 2010, 26: 827-832
[68] 温廷琏(Wen T L), 聂怀文(Nie H W), 王绍荣(Wang S R). 第十二届中国固态离子学学术会议论文集(Proceedings of 12th Chinese Conference of Solid State Ionics), 苏州(Suzhou) 2004, A01
[69] Tomita A, Teranishi S, Nagao M, Hibino T, Sano M. J. Electrochem. Soc., 2006, 153: A956-A960
[70] Asahara S, Michiba D, Hibino M, Yao T. Electrochem. Solid State Lett., 2005, 8: A449-A451
[71] Jacquens J, Farrusseng D, Georges S, Viricelle J P, Gaudillere C, Corbel G, Lacorre P. Fuel Cells, 2010, 10: 433-439
[72] Iwahara H. Ionics, 1998, 4: 409-414
[73] Fabbri E, D'Epifanio A, Sanna S, di Bartolomeo E, Balestrino G, Licoccia S, Traversa E. Energy Environ. Sci., 2010, 3: 618-621
[74] Napporn T W, Morin F, Meunier M. Electrochem. Solid State Lett., 2004, 7: A60-A62
[75] Suzuki T, Jasinski P, Anderson H U, Dogan F. Electrochem. Solid State Lett., 2004, 7: A391-A393
[76] Nagao M, Yano M, Okamoto K, Tomita A, Uchiyama Y, Uchiyama N, Hibino T. Fuel Cells, 2008, 8: 322-329
[77] Wei B, Lu Z, Huang X Q, Liu M L, Jia D C, Su W H. Electrochem. Commun., 2009, 11: 347-350.
[78] Liu M L, Lu Z, Wei B, Huang X Q, Chen K F, Su W H. Fuel Cells, 2009, 9: 717-721
[79] Liu M L, Lu Z, Wei B, Huang X Q, Zhang Y H, Su W H. J. Power Sources, 2010, 195: 4247-4251
[80] Akhtar N, Decent S P, Kendall K. Int. J. Hydrogen Energy, 2009, 34: 7807-7810
[81] Stefan I C, Jacobson C P, Visco S J, de Jonghe L C. Electrochem. Solid State Lett., 2004, 7(7): A198-A200
[82] Jacques-Bedard X, Napporn T W, Roberge R, Meunier M. J. Electrochem. Soc., 2007, 154(3): B305-B309
[83] Napporn T W, Jacques-Bedard X, Morin F, Meunier M. J. Electrochem. Soc., 2004, 151(12): A2088-A2094
[84] Morel B, Roberge R, Savoie S, Napporn T W, Meunier M. Electrochem. Solid State Lett., 2007, 10(2): B31-B33
[85] Morel B, Roberge R, Savoie S, Napporn T W, Meuniera M. J. Power Sources, 2009, 186(1): 89-95
[86] Hibino T, Tsunekawa H, Tanimoto S, Sano M. J. Electrochem. Soc., 2000, 147(4): 1338-1343
[87] Kuhn M, Napporn T W. Energies, 2010, 3(1): 57-134
[88] Yano M, Kawai T, Okamoto K, Nagao M, Sano M, Tomita A, Hibino T. J. Electrochem. Soc., 2007, 154(8): B865-B870
[89] Yano M, Nagaoa M, Okamoto K, Inoa A T, Uchiyarna Y, Uchiyama N, Hibino T. Electrochem. Solid State Lett., 2008, 11: B29-B33
[90] Buergler B E, Grundy A N. Ganuckler L J. J. Electrochem. Soc., 2006, 153: A1378-A1385
[91] Jou S, Wu T H. J. Phys. Chem. Solids, 2008, 69: 2804-2812
[92] Ahn S J, Lee J H, Kim J, Moon J. Electrochem. Solid State Lett., 2006, 9: A228-A231
[93] Fasinski P. Microelectron. Int., 2008, 25: 42-48
[94] Kim H C, Lee H W, Kim S M, Song H S, Lee J H, Kim J S, Son J W, Ahn S J. KR724119-B1, 2008.
[95] Wang Z H, Lü Z, Wei B, Huang X Q, Chen K F, Liu M L, Pan WP, Su W H. Electrochem. Solid State Lett., 2010, 13(3): B14-B16
[96] 王景锋(Wang J F). 哈尔滨工业大学硕士论文(Master Dissertation of Harbin Institute of Technology). 2008, 35-37
[97] Hibino T, Ushiki K, Sato T, Kuwahara Y. Solid State Ion., 1995, 81: 1-3
[98] Hibino T, Hashimoto A, Suzuki M, Yano M, Yoshida S, Sano M. J. Electrochem. Soc., 2002, 149(2): A195-A200
[99] Ahn S, Kim Y, Moon J, Lee J, Kim J. J. Power Sources, 2007, 171: 551-516
[100] Ahn S, Kim Y, Moon J, Lee J, Kim J. J. Electroceram., 2006, 17: 689-693
[101] Kuhn M, Napporn T, Meunier M, Therriault D, Vengallatore S. J. Power Sources, 2008, 177: 148-153
[102] Kim H, Choi S, Kim J, Lee H, Song H, Lee J. J. Mater. Pro. Tech., 2010, 210: 1243-1248
[103] 王志红(Wang Z H). 哈尔滨工业大学硕士论文(Master Dissertation of Harbin Institute of Technology). 2009, 38-39
[104] Liu M L, Lü Z, Wei B, Huang X Q, Chen K, Su W H. J. Electrochem. Soc., 2009, 156: B1253-B1256
[105] Liu M L, Lü Z, Wei B, Huang X Q, Zhang Y H, and Su W H. Solid State Ion., 2010, 181: 939-942
[106] Akhtar N, Decent S P, Kendall K. J. Power Sources, 2010, 195: 7818-7824
[107] 赵新兵(Zhao X B), 朱铁军(Zhu T J), 韩敏芳(Han M F), 刘洪权(Liu H Q). CN 101237061, 2008
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