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化学进展 2011, Vol. 23 Issue (0203): 336-348 前一篇   后一篇

所属专题： 锂离子电池

• 综述与评论 •

纳米薄膜锂离子电池电极材料

周永宁, 傅正文*   

  1. 复旦大学化学系激光化学研究所 上海市分子催化和功能材料重点实验室 上海 200433
  • 收稿日期:2010-09-01 修回日期:2010-11-01 出版日期:2011-03-24 发布日期:2011-01-26
  • 通讯作者: e-mail:zwfu@fudan.edu.cn E-mail:zwfu@fudan.edu.cn
  • 基金资助:

    上海科学技术委员会(No.08DZ2270500,09JC1401300)、国家自然科学基金项目(No.20773031)、国家重点基础研究发展计划(973)项目(No.2011CB933300)和国家高技术发展计划(863)项目(No.2007AA03Z322)资助

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Nanostructured Thin Film Electrode Materials for Lithium Ion Battery

Zhou Yongning, Fu Zhengwen*   

  1. Department of Chemistry & Laser Chemistry Institute, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University, Shanghai 200433, China
  • Received:2010-09-01 Revised:2010-11-01 Online:2011-03-24 Published:2011-01-26

本文总结了近年来纳米薄膜锂离子电池电极材料的研究情况,特别是本课题组在这方面的工作进展。我们从纳米颗粒和纳米结构两方面对各种纳米电极材料进行了分类和归纳,对于纳米颗粒组成的薄膜电极材料,除了对传统的锂-金属氧化物(LiMO2,LiMn2O4等)电极材料和聚阴离子型(LiFePO4等)电极材料薄膜化的研究做了介绍之外,着重介绍了一系列基于纳米效应的具有新型反应机理的正负极材料,包括二元金属化合物薄膜电极(MX)、含锂复合薄膜电极(M-LiX)以及多元复合薄膜电极(MXY,M1X-Y,M1X-M2Y)。这些新型电极材料及其反应机理的研究为锂离子电池的发展开辟了新的方向。对于纳米结构组成的薄膜电极材料,我们主要对三维结构的纳米丝电极和三维微网碳膜电极进行了介绍,指出这些三维纳米结构材料的研究将为未来三维微电池的开发奠定基础。

关键词： 锂离子电池, 纳米材料, 薄膜电极

This review summarizes the research in nanosized thin film electrode materials for ion batteries and our progress in this field. Nanosized thin film electrode materials are introduced by dividing into nanoparticle-materials and nanostructure-materials. For nanoparticle materials, besides introducing traditional thin film electrode materials like lithium-metal oxide (LiMO2, LiMn2O4, etc.) and lithium-metal polyanion (LiFePO4, etc.), we emphasize a series of novel thin film electrodes with new electrochemical reaction mechanisms based on nanometer-size effects, including binary metal compound (MX), composite materials contained lithium (M-LiX) and polynary composite system (MXY, M1X-Y, M1X-M2Y). The investigations of these new kinds of electrode materials will open new opportunity for the development of lithium ion battery. For nanostructured materials, we focuse on three-dimensional (3D) structured electrode and carbon micro-net films electrode. These studies lay the foundations for future 3D microbatteries.

Key words: lithium ion battery, nanostructured materials, thin film electrode

中图分类号: 

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纳米薄膜锂离子电池电极材料