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化学进展 2010, Vol. 22 Issue (11): 2099-2105 前一篇   后一篇

• 综述与评论 •

CO2开关型溶剂、溶质及表面活性剂*

王九霞1,2   苏鑫1,2  Philip G. Jessop3   冯玉军1**   

  1. (1. 中国科学院成都有机研究所  成都  610041 ；2. 中国科学院研究生院  北京  100049；3.Department of Chemistry, Queen’s University, Kingston,Onttario K7L 3N6,Canada)

     
  • 收稿日期:2010-02-24 修回日期:2010-05-17 出版日期:2010-11-24 发布日期:2010-10-20
  • 通讯作者: 冯玉军 E-mail:yujun.feng@yahoo.com
  • 基金资助:

    四川省基础青年基金项目

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CO2 Switchable Solvents, Solutes and Surfactants: State of the Art

Wang Jiuxia1,2  Su Xin1,2   Philip G. Jessop3   Feng Yujun1**   

  1. (1.Chengdu Institute of Organic Chemistry,Chinese Academy of Sciences,Chengdu 610041,China;2. Graduate School of Chinese Academy of Sciences,Beijing 100049,China;3.Department of Chemistry, Queen’s University, Kingston,Onttario K7L 3N6,Canada)
  • Received:2010-02-24 Revised:2010-05-17 Online:2010-11-24 Published:2010-10-20
  • Contact: Feng Yujun E-mail:yujun.feng@yahoo.com

CO2诱导的开关型溶剂、溶质及表面活性剂是指在通入和排出CO2后，其溶液性质能发生可逆变化的新型溶剂、溶质及表面活性剂，是典型的环境刺激响应型智能化合物。本文综述了CO2诱导的开关型溶剂、溶质及表面活性剂的结构、性能及研究进展，并指出了这些开关型溶剂、溶质及表面活性剂的发展方向及应用前景等。

关键词： 开关型溶剂, 开关型溶质, 开关型表面活性剂, CO2开关, 环境刺激响应, 离子液体

CO2-induced switchable solvents, solutes and surfactants represent a novel family of smart compounds appeared recently. When bubbling and removing CO2, the properties of these compounds can be reversibly switchable. The progress on CO2 switchable solvents, solutes and surfactants were reviewed in this article, including their structures, properties and future development. The existing problems, the development prospect and potential applications of such switchable compounds were outlooked.

Contents
1 CO2 switchable solvents
1.1 Switchable polarity solvents
1.2 Switchable hydrophilicity solvents
2 CO2 switchable solutes
3 CO2 switchable surfactants
3.1 Conventional switchable surfactants
3.2 CO2 switchable surfactants
4 Conclusion and prospective

Key words: switchable solvents, switchable solutes, switchable surfactants, CO2 trigger, environmentally stimuli-responsive, ionic liquid

中图分类号: 

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[1] Jessop P G, Stanley R R, Brown R A, Eckert C A, Liotta C L, Ngo T, Pollet P. Green Chem., 2003, 5: 123—128
[2] Tai C C, Pitts J, Main A D, Linehan J C, Munshi P, Jessop P G. Inorg. Chem., 2002, 41: 1606—1614
[3] Jessop P G, Subramaniam B. Chem. Rev., 2007, 107: 2666—2694
[4] Jessop P G, Ikariya T, Noyori R. Nature, 1994, 368: 231—233
[5] Li C J, Jessop P G. Green Chem., 2004, 6: 51—51
[6] Jessop P G, Heldebrant D J, Li X W, Eckert C A, Liotta C L. Nature, 2005, 436: 1102—1102
[7] Phan L, Chiu D, Heldebrant D J, Huttenhower H, John E, Li X, Pollet P, Wang R, Eckert C A, Liotta C L, Jessop P G. Ind. Eng. Chem. Res., 2008, 47: 539—545
[8] Heldebrant D J, Jessop P G, Thomas C A, Eckert C A, Liotta C L. J. Org. Chem., 2005, 70: 5335—5338
[9] Yamada T, Lukac P J, George M, Weiss R G. Chem. Mater., 2007, 19: 967—969
[10] Phan L, Andreatta J R, Horvey L K, Edie C F, Luco A L, Mirchandi A, Darensbourg D J, Jessop P G. J. Org. Chem., 2008, 73: 127—132
[11] Li W J, Zhang Z F, Han B X, Hu S Q, Song J L, Xie Y, Zhou X. Green Chem., 2008, 10: 1142—1145
[12] Jessop P G, Phan L, Carrier A, Robinson S, Dürr C J, Harjani J R. Green Chem., 2010, 12: 809—814
[13] Phan L, Brown H, White J, Hodgson A, Jessop P G. Green Chem., 2009, 11: 53—59
[14] Andanson J M, Jutz F, Baiker A. J. Phys. Chem. B, 2009, 113: 10249—10254
[15] Planeta J, Karásek P, Roth M. J. Phys. Chem. B, 2007, 111: 7620—7625
[16] Yave W, Car A, Peinemann K V. J. Membr. Sci., 2010, 350: 124—129
[17] Jessop P G, Stanley R R, Brown R A, Eckert C A, Liotta C L, Ngo T T, Pollet P. Green Chem., 2003, 5: 123—128
[18] Zhang F, Xu Q, Zhang H, Zhang Z W. J. Phys. Chem. C, 2009, 113: 18531—18535
[19] Blasucci V M, Husain Z A, Fadhel A Z, Donaldson M E, Vyhmeister E, Pollet P, Liotta C L, Eckert C A. J. Phys. Chem. A, 2010, 114: 3932—3938
[20] Wang X G, Yang H M, Feng B, Hou Z H, Hu Y, Qiao Y X, Li H, Zhao X G. Catal. Lett., 2009, 132: 34—40
[21] Heldebrant D J, Witt H N, Walsh S M, Ellis T, Rauscher J, Jessop P G. Green Chem., 2006, 8: 807—815
[22] Scurto A M, Leitner W. Chem. Commun., 2006, 45: 3681—3683
[23] Heldebrant D J, Jessop P G. J. Am. Chem. Soc., 2003, 125: 5600—5601
[24] Phan L, Jessop P G. Green Chem., 2009, 11: 307—308
[25] Desset S L, Cole-Hamilton D J. Angew. Chem. Int. Ed., 2009, 48: 1472—1474
[26] 解战峰(Xie Z F), 冯玉军(Feng Y J). 化学进展(Progress in Chemistry), 2009, 21: 1164—1170
[27] Jawitz J M, Annable M D, Rao P S C, Rhue R D. Environ. Sci. Health A, 2001, 36(8): 1437—1450
[28] Hashim M A, Kulanda I J, Hassan R S. J. Chem. Technol. Biot., 1992, 54: 207—214
[29] Ying G G. Environ. Int., 2006, 32: 417—431
[30] Klijn J E, Stuart M C A, Scarzello M, Wagenaar A, Engerberts J B F N. J. Phys. Chem. B, 2006, 110: 21694—21700
[31] Johnsson M, Wagenaar A J, Engberts B F N. J. Am. Chem. Soc., 2003, 125: 757—760
[32] Asokan A, Cho M J. Bioconjugate Chem., 2004, 15: 1166—1173
[33] Han S K, Bae Y H. Colloids Surf. A: Physicochem. Eng. Aspects, 2003, 214: 49—59
[34] Brazdova B, Rong N, Samoshin V V, Guo X. Chem. Commun., 2008, 39: 4774—4776
[35] 李英杰(Li Y J), 田森林(Tian S L), 宁平(Ning P). 应用化工(Applied Chemical Industry), 2008, 37(4): 438—441
[36] Gallardo B S, Hwa M J, Abbott N L. Langmuir, 1995, 11: 4209—4212
[37] Kakizaw Y, Sakai H, Nishiyama K, Abe M, Shoji H, Kondo Y, Yoshino N. Langmuir, 1996, 12: 921—924
[38] Saj I T, Hoshino K, Aoyaguz S. J. Am. Chem. Soc., 1985, 107: 6865—6868
[39] Aydogan N, Abbott N. Langmuir, 2001, 17: 5703—5706
[40] Kang H C, Lee B M, Yoon J, Yoon M. J. Colloid Interface Sci., 2000, 231: 255—264
[41] Eastoe J, Dominguez M S, Wyatt P, Beeby A, Heenan R. Langmuir, 2002, 18: 7837—7844
[42] Liu Y X, Jessop P G, Cunningham M, Eckert C A, Liotta C L. Science, 2006, 313: 958—960
[43] Poteau S, Argillier J F, Langevin D, Pincet F, Perez E. Energy Fuels, 2005, 19: 1337—1341
[44] Acevedo S, Borges B, Quintero F, Piscitelly V, Gutierrez L. Energy Fuels, 2005, 19: 1948—1953
[45] Vinci D, Donaldson M, Hallett J P, John E A, Pollet P, Tomas C A, Grilly J D, Jessop P G, Liotta C L, Eckert C A. Chem. Commun., 2007, 1427—1429
[46] Wang L, Qiao W H, Cao C, Li Z. Colloids Surf. A: Physicochem. Eng. Aspects, 2008, 320: 271—274
[47] 秦勇(Qin Y), 纪俊玲(Ji J L), 么士平(Yao S P). 日用化学工业(China Surfactant Detergent & Cosmetics), 2009, 39(2): 89—92
[48] 秦勇(Qin Y), 纪俊玲(Ji J L), 汪媛(Wang Y). 日用化学工业(China Surfactant Detergent & Cosmetics), 2008, 39(9): 15—18
[49] 秦勇(Qin Y), 纪俊玲(Ji J L), 汪媛(Wang Y), 丁璇(Ding X). 日用化学品科学(Detergent & Cosmetics), 2009, 32(11): 18—22
[50] 秦勇(Qin Y), 纪俊玲(Ji J L), 葛海华(Ge H H). 日用化学工业(China Surfactant Detergent & Cosmetics), 2009, 39(6): 386—389
[51] Zhou K J, Li J F, Lu Y, Zhang G, Xie Z, Wu C. Macromolecules, 2009, 42: 7146—7154
[52] Ochiai B, Yokota K, Fujii A, Nagai D, Endo T. Macromolecules, 2008, 41: 1229—1236
[53] Yu T, Yamada T, Gaviola G C, Weiss R G. Chem. Mater., 2008, 20: 5337—5344
[54] Yamada T, Lukac P J, Yu T, Weiss R G. Chem. Mater., 2007, 19: 4761—4768
[55] Hartmann L, Bedard M, Brner H G, Mhwald H, Sukhorukov G B, Antonietti M. Soft Matter, 2008, 4: 534—539
[56] Muoz D M, Portugal A F, Lozano A E, de la Campa J G, de Abajo J. Energy Environ. Sci., 2009, 2: 883—891
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