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化学进展 2010, Vol. 22 Issue (0203): 322-330 前一篇   后一篇

• 综述与评论 •

多孔分子筛材料的合成*

王义1;李旭光2;薛志元1;李全芝2**   

  1. （1. 复旦大学分析测试中心  上海  200433； 2. 复旦大学化学系   上海  200433）
  • 收稿日期:2009-04-21 修回日期:2009-08-06 出版日期:2010-03-24 发布日期:2010-03-18
  • 通讯作者: 李全芝 E-mail:qzli@fudan.edu.cn
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Synthesis of Porous Molecular Sieves

Wang Yi1;  Li Xuguang2;  Xue Zhiyuan1;  Li Quanzhi2**   

  1. （1. Center of Analysis and Measurement, Fudan University, Shanghai 200433, China; 2. Department of Chemistry, Fudan University, Shanghai 200433, China）
  • Received:2009-04-21 Revised:2009-08-06 Online:2010-03-24 Published:2010-03-18
  • Contact: Li Quanzhi E-mail:qzli@fudan.edu.cn

综述了近年来微孔、介孔分子筛的改进以及多级孔复合分子筛材料的合成研究进展，包括各类分子筛的结构特点、制备方法、改性合成以及应用前景等；并分析了各种合成方法及合成的材料的优点，指出了存在的问题，探讨了分子筛类材料的发展前景。

关键词： 多孔分子筛, 微孔分子筛, 介孔分子筛, 复合分子筛, 多级孔分子筛

Porous molecular sieves, as a kind of important inorganic materials, have been greatly concerned by researchers. The development of the research, such as structure, methods of preparation, improvement, applications and so on are reviewed, which based on the different porous molecular sieves, involving improved microporous molecular sieves, improved mesoporous molecular sieves and hierarchical-porous composite molecular sieves. The strongpoints and deficiencies of porous materials synthesized by different methods are analyzed. The prospects for porous molecular sieves are expected.

Contents
1 Introduction
2 Microporous molecular sieves
2.1 Creating mesopores in zeolite crystals by post treatment method
2.2 Synthesizing mesoporous zeolites by confined space method
3 Mesoporous molecular sieves
3.1 Enhancing hydrothermal stability and catalytic activity of mesoporous molecular sieves by modifying their frameworks
3.2 Mesoporous molecular sieves whose pore walls contain secondary structural units of zeolites
4 Micro-mesoporous molecular sieve composites
4.1 Hydrothermal synthesis
4.2 Physical synthesis
5 Micro-microporous molecular sieve composites
6 Molecular sieves with macropores
7 Conclusion and prospects

Key words: porous molecular sieves, microporous molecular sieves, mesoporous molecular sieves, composite molecular sieves, hierarchical molecular sieves

中图分类号: 

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摘要

多孔分子筛材料的合成*