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• 综述与评论 •

有机微纳米材料的设计策略、加工及应用

杨柳1, 雷霆2, 裴坚*1,2, 刘晨江* 1   

  1. 1. 石油天然气精细化工教育部&自治区重点实验室 乌鲁木齐绿色催化与合成技术重点实验室 新疆大学化学与化工学院 乌鲁木齐830046;
    2. 北京大学化学与分子工程学院 北京 100871
  • 收稿日期:2012-05-01 修回日期:2012-06-01 出版日期:2012-12-24 发布日期:2012-12-11
  • 通讯作者: 裴坚, 刘晨江 E-mail:pxylcj@126.com;jianpei@pku.edu.cn
  • 基金资助:

    国家自然科学基金项目 (No. 21162025,20862016,20662009) 和乌鲁木齐市科技计划项目 (No.H101133001) 资助

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Design Strategy , Processing and Applications of Organic Micro- and Nano-Materials

Yang Liu1, Lei Ting2, Pei Jian*1,2, Liu Chenjiang* 1   

  1. 1. Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, Urumqi Key Laboratory of Green Catalysis and Synthesis Technology, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China;
    2. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
  • Received:2012-05-01 Revised:2012-06-01 Online:2012-12-24 Published:2012-12-11
有机微纳米材料是一类新型的材料体系,具备了传统体相有机材料诸多特点,同时由于尺寸效应表现出独特的物理化学特性,因而在最近几年引起了广泛的关注。相比传统的无机微纳米材料体系,有机微纳米材料构筑单元选择广泛、可调控性强、加工成本低以及易于大规模加工,目前已被应用在有机场效应晶体管、有机光伏太阳能电池等方面。本文总结了有机微纳米材料的加工方法,利用超分子化学的概念探讨了有机微纳米材料的分子设计思路,以及有机微纳米材料的生长机理,并介绍了其相关应用。
关键词： 有机微纳米材料, 有机场效应晶体管, 有机光伏太阳能电池, 超分子化学
Organic micro- and nano-materials is a kind of novel material system, possessing a good many features of traditional bulk organic materials, and exhibiting unique physicochemical characteristics due to size effect. Thus they have attracted more and more attentions in recent years. In comparison with traditional inorganic micro- and nano-materials, organic micro- and nano-materials possesses some merits such as unlimited choice of building blocks, low-cost, ease for large-area fabrication, and they have been applied in organic field-effect transistors, organic photovoltaic solar cells and so on. In this paper, we summarizes recent development of organic micro- and nano-materials. Using the concept of supramolecular chemistry, we discusses molecule design strategy and growth mechanism of organic micro- and nano-materials, and their applications. Contents
1 Introduction
2 Molecular design strategy and synthesis
2.1 π-π interaction
2.2 S-S interaction
2.3 Donor-acceptor interaction
2.4 Hydrophobic interaction
2.5 Hydrogen-bonding interaction
3 Controlled growth and growth mechanism of organic micro- and nano-materials
3.1 Internal factors of the organic micro- and nano-materials growth
3.2 External actors of the organic micro- and nano-materials growth
4 The applications of organic micro- and nano-materials
4.1 Organic field-effect transistors
4.2 Organic photovoltaic solar cells
5 Conclusion and Outlook
Key words: organic micro- and nano-materials, organic field-effect transistors, organic photovoltaic solar cells, supramolecular chemistry

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