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纤维素在离子液体中的降解转化

周理龙, 吴廷华*, 吴瑛*   

  1. 浙江师范大学物理化学研究所 金华 321004
  • 收稿日期:2011-10-01 修回日期:2012-01-01 出版日期:2012-08-24 发布日期:2012-08-06
  • 通讯作者: 吴廷华, 吴瑛 E-mail:thwu@zjnu.cn,yingwu@zjnu.cn
  • 基金资助:

    浙江省自然科学基金项目(No.LY12B03001)和浙江省科技厅计划项目(No. 2009C31084)资助

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Degradation and Conversion of Cellulose in Ionic Liquids

Zhou Lilong, Wu Tinghua, Wu Ying   

  1. Institute of Physical Chemistry,Zhejiang Normal University, Jinhua 321004, China
  • Received:2011-10-01 Revised:2012-01-01 Online:2012-08-24 Published:2012-08-06
随着社会对能源资源的需求越来越大,生物质资源得到了广泛的重视,世界上存储量最大的生物质资源--纤维素在新兴溶剂离子液体中的降解转化受到了越来越多的关注。本文简要介绍了近几年来纤维素在离子液体中的溶解、单糖(果糖、葡萄糖)在离子液体中脱水转化为5-HMF(5-羟甲基糠醛)和纤维素在离子液体中一步降解转化为5-HMF的研究。指出目前研究存在的缺点与不足,并提出了可能的解决方法。
关键词： 纤维素, 葡萄糖, 果糖, 离子液体, 5-HMF
As society’s requirement for resources increasing,biological resources attract widespread attentions. The degradation of cellulose, the most abundant biomass, in the emerging solvents--ionic liquids, becomes a hot topic in chemical research. Dissolving cellulose in ionic liquids is the first step of cellulose’s degradation. So at the beginning of this paper, the current research on dissolution of cellulose in ionic liquids is introduced. As the key step, monosaccharide (glucose and fructose) being converted into 5-HMF (5-hydroxymethyl furfural) in ionic liquids has been researched in recent years. Based on the representative works, it is found that developing an efficient catalyst to convert glucose to 5-HMF still has a long way to go. One-pot conversion of cellulose into 5-HMF in ionic liquids is the most important issue discussed in this article. The review introduces the latest research progress in degradation of cellulose in ionic liquids and the correlative mechanisms. At last, this article points out the shortcoming of the researches and puts forward some possible solutions. Contents 1 Introduction
2 Cellulose dissolves in ionic liquids
2.1 Survey of cellulose’s structure
2.2 Research of cellulose dissolving in ionic liquids
2.3 Mechanism of cellulose dissolving in ionic liquids
2.5 Influence factors of cellulose dissolving in ionic liquids.
3 Research of monosaccharide’s degradation into 5-HMF
3.1 Degradation of fructose to 5-HMF
3.2 Degradation of glucose to 5-HMF
3.3 Mechanism of degradation of glucose to 5-HMF
3.4 Summary
4 Degradation of cellulose in ionic liquids
4.1 Survey of ways to degradation of cellulose
4.2 Metal halides catalysts
4.3 Mineral acids and solid acids catalysts
4.4 Acid-functionalized ionic liquids catalysts
4.5 Summary
5 Conclusions and outlook
Key words: cellulose, glucose, fructose, ionic liquids, 5-HMF

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摘要

纤维素在离子液体中的降解转化