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自修复高分子材料

李思超, 韩朋, 许华平*   

  1. 清华大学化学系 有机光电子与分子工程教育部重点实验室 北京 100084
  • 收稿日期:2011-09-01 修回日期:2011-11-01 出版日期:2012-07-24 发布日期:2012-06-30
  • 通讯作者: 许华平 E-mail:xuhuaping@tsinghua.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.20904028,21074066)资助

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导出 被引次数 ( 29 )

Self-Healing Polymeric Materials

Li Sichao, Han Peng, Xu Huaping   

  1. Key Lab of Organic Optoelectronic and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, China
  • Received:2011-09-01 Revised:2011-11-01 Online:2012-07-24 Published:2012-06-30
高分子材料制造和使用过程中,经常由于内部的微裂纹和局部损伤,而导致性能下降,影响使用寿命。自修复高分子材料模仿生物体损伤愈合的原理,自行发现裂纹并通过一定机理自行愈合,是一种有着广泛应用需求的高分子智能材料,包括含修复剂型和不含修复剂型两类。它的特点在于自动化、精准化。本文旨在结合近年来最新的研究成果,介绍并归纳多种典型的自修复体系,总结各种优化手段,并针对已发展的自修复材料存在的局限性,对其研究前景进行合理的展望。
关键词： 自修复, 高分子材料, 仿生, 超分子作用
In the process of manufacture and usage, the mechanical properties of polymeric materials will decrease due to internal micro-cracks or partial injuries, thus shortening the lifetime of the material. By imitating the principles of organism wound healing, the self-healing polymeric materials, which are able to discover and repair cracks automatically, have been developed through different mechanisms. Because of its rapid and precise response to the formation of micro-cracks inside, self-healing polymeric materials have shown great potential as novel smart materials in some severe conditions. The review tries to summarize recent progress in this field, and to introduce a variety of typical self-healing systems along with optimization methods. Rational design on fabrication of self-healing polymeric materials is also outlooked. Contents
1 Introduction
2 Self-healing polymeric materials with repair agents
2.1 Microcapsule-based systems
2.2 Microvascular network systems
3 Self-healing polymeric materials without repair agents
3.1 Reversible covalent reactions
3.2 Supramolecular interactions
4 Conclusion and outlook
Key words: self-healing, polymeric materials, biomimics, supramolecular interactions

中图分类号: 

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摘要

自修复高分子材料