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化学进展 2012, Vol. 24 Issue (07): 1252-1261 前一篇   后一篇

• 综述与评论 •

分子筛在加氢脱硫催化剂深度脱硫方面的应用

尹海亮1, 周同娜2, 柴永明3, 柳云骐3, 刘晨光*3   

  1. 1. 中国石油大学(华东)重质油国家实验室 科学技术研究院 东营 257061;
    2. 东营市环境保护局 东营 257300;
    3. 中国石油大学(华东)重质油国家实验室 青岛 266555
  • 收稿日期:2011-10-01 修回日期:2011-12-01 出版日期:2012-07-24 发布日期:2012-06-30
  • 通讯作者: 刘晨光 E-mail:liucg@upc.edu.cn
  • 基金资助:

    国家重点基础研究发展计划(973)项目(No. 2010CB226905)资助

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Application of Zeolites in Hydrodesulfurization Catalysts for Deep Desulfurization

Yin Hailiang1, Zhou Tongna2, Chai Yongming3, Liu Yunqi3, Liu Chenguang3   

  1. 1. State Key Laboratory of Heavy Oil Processing, Academy of Science & Technology, China University of Petroleum(East China), Dongying 257061, China;
    2. Environmental Protection Agency of Dongying, Dongying 257300, China;
    3. State Key Laboratory of Heavy Oil Processing, China University of Petroleum(East China), Qingdao 266555, China
  • Received:2011-10-01 Revised:2011-12-01 Online:2012-07-24 Published:2012-06-30
本文综述了分子筛对加氢脱硫催化剂深度脱硫性能的影响,对分子筛基加氢脱硫催化剂上涉及含硫大分子4,6-二甲基二苯并噻吩(4,6-DMDBT)加氢脱硫反应的研究进展作了总结。主要介绍了微孔分子筛、介孔分子筛、微介孔复合分子筛和纳米分子筛在加氢脱硫催化剂针对4,6-DMDBT加氢脱硫反应方面的应用进展。简要介绍了分子筛基加氢脱硫催化剂上4,6-DMDBT加氢脱硫反应的反应途径、反应机理及抑制过度裂化反应的措施。最后展望了该研究领域的发展前景。
The recent progress in the application of zeolites in hydrodesulfurization catalysts for the deep desulfurization is reviewed in this paper, including microporous zeolite, mesoporous zeolite, micro-mesoporous zeolite and nano-zeolite. The reaction pathways and mechanisms of the hydrodesulfurization of 4,6-DMDBT and the measures to inhibit the overcracking reactions of desulfurization products over hydrodesulfurization catalysts containing zeolites are described briefly. Finally, challenges and prospects for further development of this field are presented. Contents
1 Introduction
2 The application of zeolites in hydrodesulfurization catalysts for the deep desulfurization
2.1 The application of microporous zeolites
2.2 The application of mesoporous zeolites
2.3 The application of micro-mesoporous zeolites
2.4 The application of nano-zeolites
3 The new reaction pathways of the hydrodesulfurization of 4,6-DMDBT over hydrodesulfurization catalysts containing zeolites
4 The new reaction mechanisms of hydrodesulfurization of 4,6-DMDBT over hydrodesulfurization catalysts containing zeolites
4.1 Isomerization reaction mechanism
4.2 Transalkylation reaction mechanism
4.3 Cracking reaction mechanism
4.4 Other reaction mechanism
5 The measures to inhibit the overcracking reactions of desulfurization products
6 Summary and perspective
Key words: zeolite, 4,6-DMDBT, hydrodesulfurization

中图分类号: 

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