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化学进展 2012, Vol. 24 Issue (05): 823-833 前一篇   后一篇

• 综述与评论 •

基于罗丹明染料的金属阳离子荧光探针

黎俊波, 胡启辉, 曾阳, 余响林, 潘志权*   

  1. 武汉工程大学 绿色化工过程教育部重点实验室 武汉 430073
  • 收稿日期:2011-09-01 修回日期:2011-12-01 出版日期:2012-05-24 发布日期:2012-04-10
  • 基金资助:
    国家自然科学基金项目(No.20901063)、武汉市科技局晨光计划项目(No.201050231049)和绿色化工过程教育部重点实验室项目(No.GCP201003)资助
下载PDF ( 1501 ) 引用
导出 被引次数 ( 43 | 5 )

Rhodamine-Based Fluorescent Probes for Cations

Li Junbo, Hu Qihui, Zeng Yang, Yu Xianglin, Pan Zhiquan   

  1. Key Laboratory for Green Chemical Process of Ministry of Education, Wuhan Institute of Technology, Wuhan 430073, China
  • Received:2011-09-01 Revised:2011-12-01 Online:2012-05-24 Published:2012-04-10
罗丹明是以氧杂蒽为母体的碱性呫吨染料,具有优良的光学性质,如延伸到可见光区的吸收及荧光、高的荧光量子产率及大的摩尔吸光系数等,使其成为制备荧光探针的理想生色团。本文综述了近年来用于检测金属阳离子的罗丹明类荧光探针的研究进展,特别是对基于螺酰胺环“关-开”机理、荧光共振能量转移(FRET)机理和光诱导电子转移(PET)机理的罗丹明类铜离子、汞离子、铁离子荧光探针进行了系统的阐述,包括结构特征、检测水平和应用范围。最后提出了这类荧光探针面临的问题与发展趋势。
关键词： 罗丹明, 荧光, 探针, 金属阳离子
As one kind of the xanthenes, rhodamine dyes have excellent photophysical properties, such as long absorption and emission wavelengths elongated to visible region, high fluorescence quantum yield, and large absorption coefficient, etc. Therefore, rhodamine-based dyes have become one of the perfect chromophores for making fluorescent probes. In the paper, the recent progress in the studies on rhodamine-based fluorescent probes for metal cations are reviewed. Especially systematically discuss about the rhodamine-based fluorescent probes for copper ion, mercury ion and iron ion that are based on the mechanism of screw amide ring “off-on”, the mechanism of fluorescence resonance energy transfer and the mechanism of photoinduced electron transfer. The structure, detecting level and applications are discussed in detail. Moreover, the problems and developing trends with this kind of fluorescent probe have also been discussed.

Contents
1 Introduction
2 Selective probes for copper ion
3 Selective probes for mercury ion
3.1 Probe with sulfur atoms coordination
3.2 Probe without sulfur atoms coordination
3.3 Probe with mercury ion induced chemical reactions
4 Selective probes for iron ion
5 Selective probes for other metal ions
6 Conclusions and outlook

Key words: rhodamine, fluorescence, probes, metal cations

中图分类号: 

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