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化学进展 2012, Vol. 24 Issue (05): 686-695 前一篇   后一篇

• 综述与评论 •

离子液体参与构建的胶束

赵学艳1*, 郑利强2, 曹桂荣1, 肖瑞杰1   

  1. 1. 防灾科技学院 三河 065201;
    2. 山东大学 胶体与界面化学教育部重点实验室 济南 250100
  • 收稿日期:2011-09-01 修回日期:2011-11-01 出版日期:2012-05-24 发布日期:2012-04-10
  • 基金资助:
    中国地震局教师科研基金项目(No.20110123)资助
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Micelles Based on Ionic Liquids

Zhao Xueyan1*, Zheng Liqiang2, Cao Guirong1, Xiao Ruijie1   

  1. 1. Institute of Disaster Prevention, Sanhe 065201, China;
    2. Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, China
  • Received:2011-09-01 Revised:2011-11-01 Online:2012-05-24 Published:2012-04-10
离子液体参与构建的有序组合体,以其独特的物理化学性质及在众多领域的应用潜能而引起广泛关注。本文结合我们的研究工作,对离子液体参与构建的胶束体系的主要研究成果进行了综述,重点介绍了传统表面活性剂在离子液体中胶束的形成、表面活性离子液体在水溶液中的聚集行为、离子液体作为添加剂对传统表面活性剂胶束的影响。在此基础上,归纳了部分体系胶束形成的机理和规律,并展望了离子液体构建的胶束体系研究和发展的方向。
关键词： 表面活性剂, 离子液体, 胶束
The ordered molecular aggregates based on ionic liquids (ILs) have attracted increasing interest due to their unique physicochemical properties and potential applications in various areas. Combining with our work, the recent progress in the micelle formation based on ILs is summarized. The aggregation of traditional surfactants in ILs, self-organization of surface-active ILs in aqueous solutions, as well as the effect of ILs on micelles formed by traditional surfactants are reviewed emphatically. Based on these studies, the mechanisms and regularities of micellization for some systems are proposed, and the trend for future research is prospected.

Contents
1 Introduction
2 ILs as solvents
2.1 Micelle formation of cationic surfactants in ILs
2.2 Micelle formation of anionic surfactants in ILs
2.3 Micelle formation of nonionic surfactants in ILs
2.4 Micelle formation of amphiphilic copolymers in ILs
3 ILs as surface-active agents
3.1 Micelle formation of common ILs in aqueous solution
3.2 Micelle formation of common ILs in non-aqueous solution
3.3 Micelle formation of functional ILs in aqueous solution
4 Effect of ILs on micelles formed by traditional surfactants
4.1 ILs as co-surfactants
4.2 ILs as salts
5 Prospects

Key words: surfactants, ionic liquids (ILs), micelles

中图分类号: 

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摘要

离子液体参与构建的胶束