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化学进展 2012, Vol. 24 Issue (04): 483-491 前一篇   后一篇

• 综述与评论 •

离子液体介导制备5-羟甲基糠醛

胡磊, 孙勇, 林鹿   

  1. 厦门大学能源研究院 厦门 361005
  • 收稿日期:2011-08-01 修回日期:2011-10-01 出版日期:2012-04-24 发布日期:2012-02-08
  • 基金资助:

    国家重点基础研究发展计划(973)项目(No.2010CB732201)、国家自然科学基金项目(No.21106121);中央高校基本业务费专项资金项目(No.2010121077)资助

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Ionic Liquids-Mediated Formation of 5-Hydroxymethylfurfural

Hu Lei, Sun Yong, Lin Lu   

  1. School of Energy Research, Xiamen University, Xiamen 361005, China
  • Received:2011-08-01 Revised:2011-10-01 Online:2012-04-24 Published:2012-02-08
5-羟甲基糠醛(5-HMF)被认为是一种非常重要的平台化合物。利用离子液体介导制备5-HMF的研究已经引起了人们越来越广泛的重视,并取得了较为理想的研究成果。本文对离子液体介导制备5-HMF的研究成果进行了系统的归纳和总结,着重介绍了离子液体作为反应溶剂和催化剂在5-HMF制备过程中的应用以及离子液体介导制备5-HMF的形成机理和影响因素,并对离子液体介导制备5-HMF的研究前景进行了展望,以期为5-HMF的进一步研究提供思路和参考。
关键词： 5-羟甲基糠醛, 离子液体, 生物质, 反应溶剂, 催化剂, 形成机理, 影响因素
5-Hydroxymethylfurfural (5-HMF) is considered as a very important biomass-based platform compound that can be used to synthesize a broad range of liquid fuels and chemicals, which are mainly derived from fossil resources so far. The study of the production of 5-HMF in the presence of ionic liquids has increasingly attracted more attention. In this review, the recent achievements of ionic liquids-mediated formation of 5-HMF are systematically summarized, including applications of ionic liquids as reaction solvents and catalysts in the production of 5-HMF, influence factors and formation mechanisms in the ionic liquids-mediated formation of 5-HMF. The future research trends of ionic liquids-mediated formation of 5-HMF are suggested.
Contents
1 Introduction
2 Production of 5-HMF using ionic liquids as reaction solvents
2.1 Fructose as feedstock
2.2 Glucose as feedstock
2.3 Sucrose as feedstock
2.4 Cellulose, starch and inulin as feedstock
3 Production of 5-HMF using ionic liquids as catalysts
3.1 Ionic liquids as base catalysts
3.2 Ionic liquids as acid catalysts
4 Mechanisms of ionic liquids-mediated formation of 5-HMF
5 Influence factors of ionic liquids-mediated formation of 5-HMF
5.1 Reaction temperature
5.2 Heating method
5.3 Reaction time
5.4 Catalyst loading
5.5 Substrate loading
5.6 Water content
5.7 Co-solvent
5.8 Extraction method
6 Conclusions and perspectives
Key words: 5-hydroxymethylfurfural, ionic liquids, biomass, reaction solvents, catalysts, formation mechanisms, influence factors

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摘要

离子液体介导制备5-羟甲基糠醛