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干胶法合成分子筛

杨娜1, 岳明波1,2, 王一萌1*   

  1. 1. 华东师范大学化学系 上海市绿色化学与化工过程绿色化重点实验室 上海 20006;
    2. 曲阜师范大学化学与化工学院 曲阜 273165
  • 收稿日期:2011-07-01 修回日期:2011-09-01 出版日期:2012-03-24 发布日期:2011-11-25
  • 通讯作者: 王一萌 E-mail:ymwang@chem.ecnu.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.20890124,21003083)和中国博士后科学基金项目(No.201004700766)资助

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Synthesis of Zeolites by Dry Gel Conversion

Yang Na1, Yue Mingbo1,2, Wang Yimeng1*   

  1. 1. Shanghai Key Lab of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 20006;
    2. School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China
  • Received:2011-07-01 Revised:2011-09-01 Online:2012-03-24 Published:2011-11-25
相对于传统的水热合成法,干胶法(dry gel conversion,DGC)合成分子筛具有产量高、废液量少等优势。本文综述了近十年来DGC合成分子筛的研究进展。以水为线索,总结了外加水和固有水(指原料干胶所含的水)在DGC中对分子筛的生长、晶相的转换与物化性质的影响,论述了在DGC条件下分子筛的生长过程和晶化机理,介绍了DGC在介孔-微孔复合分子筛、分子筛膜、单块材料等新型分子筛材料合成中的一些实例。
关键词： 干胶法(DGC), 分子筛, 合成机理, 水
Compared with traditional hydrothermal synthesis (HTS), dry gel conversion (DGC) synthesis of zeolites has the advantages of high yield, less waste, less usage of templates,etc. Firstly, this review summarized the developments in last decade and pivoted on the role of water. In typical DGC synthesis, the gel powder keeps intact with the liquid including liquid water. However, water could also be the vapor or those adsorbed/absorbed in gel powders. Therefore, both the water added and those included in gel powder may affect the nucleation, and growth of zeolite, phase selectivity and transformation, and the properties of obtained zeolite. It is believed that water has been the prerequisite for the transformation of zeolite from initial gel. And the required amount of water differs by structural properties of zeolite. Apart from water, other factors have been seen as contributing roles as well in the synthesis condition. Secondly, the difference between HTS and DGC is discussed. Thirdly, this review provided some insights into the formation mechanism of zeolite in DGC process, where nanoparticles and semi-crystalline intermediates play the role. Finally, this review illustrated the applications of DGC in the synthesis of hierarchical zeolite, zeolite film, zeolite monolith and others. Some advices about DGC used in the synthesis of these relatively new materials are concluded. Contents
1 Introduction
2 Definition of DGC
3 Factors in crystallization by DGC
3.1 Role of water
3.2 Other factors
4 Differences between HTS and DGC
5 Crystal growth and zeolite synthesis mechanism
6 Applications in fabrication of zeolite-like materials
6.1 Synthesis of hierarchical zeolite
6.2 Synthesis of zeolite monolith and other zeolite-like materials
7 Outlook
Key words: dry gel conversion (DGC), zeolite, synthetic mechanism, water

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摘要

干胶法合成分子筛