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化学进展   后一篇

• 特约稿 •

分子识别与温度响应复合智能材料

谢锐, 杨眉, 程昌敬, 姜晶, 褚良银*   

  1. 四川大学化学工程学院 成都 610065
  • 收稿日期:2011-07-01 修回日期:2011-10-01 出版日期:2012-03-24 发布日期:2011-11-25
  • 通讯作者: 褚良银 E-mail:chuly@scu.edu.cn
  • 基金资助:

    国家杰出青年科学基金项目(No.20825622)、国家自然科学基金项目(No. 21076127,21036002,20806049,20990220)、国家重点基础研究发展计划(973)项目(No.2009CB623407)、教育部高等学校博士学科点专项科研基金项目(No.200806100038,200806101045)资助

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Molecular-Recognition and Thermo-Responsive Composite Smart Polymeric Materials

Xie Rui, Yang Mei, Cheng Changjing, Jiang Jing, Chu Liangyin*   

  1. School of Chemical Engineering, Sichuan University, Chengdu 610065, China
  • Received:2011-07-01 Revised:2011-10-01 Online:2012-03-24 Published:2011-11-25
研究和开发具有双重和多重刺激响应型智能高分子材料已成为一个重要的发展方向。本文详细地综述了我们近年来在基于聚(N-异丙基丙烯酰胺)(PNIPAM)和β-环糊精(β-CD)的复合智能线型高分子、复合智能微球和复合智能膜方面的研究进展。不同形式的复合智能材料均采用相同的反应机理制备。综述了制备工艺条件、共聚单体比例、接枝率、客体分子种类和浓度等因素对于不同形式复合智能材料的温度响应性和分子识别特性的影响规律,并对复合智能膜在亲合分离、控制释放和手性拆分等方面的应用进行了介绍。评述了分子识别与温度响应复合智能材料的研究意义和发展方向,并对其应用前景进行了展望。
关键词： 智能材料, 聚(N-异丙基丙烯酰胺), &beta, -环糊精, 线型高分子, 微球, 智能膜
Development of dual-stimuli-responsive and multi-stimuli-responsive smart polymeric materials becomes more and more important. The recent progresses in molecular-recognition and thermo-responsive composite smart linear polymers, smart microspheres and smart membranes based on poly(N-isopropylacrylamide) (PNIPAM) and β-cyclodextrin (β-CD) are reviewed in detail. The different kinds of smart materials are prepared by the same reaction mechanism, namely polymerization of N-isopropylacrylamide (NIPAM) with glycidyl methacrylate (GMA) into poly(N-isopropylacrylamide-co-glycidyl methacrylate) (PNG) polymer at first, followed by introduction of modified mono-6-deoxy-6-ethylenediamino-β-cyclodextrin (ECD) or mono-6-deoxy-6-hexanediamino-β-cyclodextrin (HCD) onto PNG polymer by virtue of reaction between primary amino groups and epoxy groups. The effects of preparation conditions, the molar ratio of NIPAM to GMA, grafting yields, the types and concentrations of guest molecules on the thermo-responsibility and molecular-recognition characteristics of different composite smart polymeric materials are discussed. Moreover, the applications of composite smart polymeric membranes in affinity separation, controlled release and chiral separation are also discussed. The significance and future of molecular-recognition and thermo-responsive composite polymeric materials are commented. Contents
1 Introduction
2 Molecular-recognition and thermo-responsive compo-site smart polymeric materials based on poly- (N-isopropylacrylamide) and β-cyclodextrin
2.1 Composite smart linear polymers
2.2 Composite smart microspheres
2.3 Composite smart membranes
3 Conclusions and Outlook
Key words: smart materials, poly(N-isopropylacrylamide), &beta, -cyclodextrin, linear polymers, microspheres, smart membranes

中图分类号: 

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[1] 陈莉(Chen L). 智能高分子材料(Intelligent Polymer Materials). 北京:化学工业出版社(Beijing: Chemical Industry Press), 2004. 5-9
[2] Liu L, Wang W, Ju X J, Xie R, Chu L Y. Soft Matt., 2010, 6(16): 3759-3763
[3] Wang J Y, Jin Y, Xie R, Liu J Y, Ju X J, Meng T, Chu L Y. J. Colloid Interf. Sci., 2011, 353(1): 61-68
[4] Liu L, Yang J P, Ju X J, Xie R, Liu Y M, Wang W, Zhang J J, Niu C H, Chu L Y. Soft Matt., 2011, 7(10): 4821-4827
[5] Wei J, Ju X J, Xie R, Mou C L, Lin X, Chu L Y. J. Colloid Interf. Sci., 2011, 357(1): 101-108
[6] Anastasiadis S H, Lygeraki M I, Athanassiou A, Farsari M, Pisignano D. J. Adhes. Sci. Technol., 2008, 22(15): 1853-1868
[7] Liu G Q, Zhao X P. J. Macromol. Sci. Pure Appl. Chem., 2006, A43(2): 345-354
[8] Yoon S G, Kim I Y, Kim S I, Kim S J. Polym. Inter., 2005, 54(8): 1169-1174
[9] 朱小丽(Zhu X L), 谢锐(Xie R), 杨眉(Yang M), 褚良银(Chu L Y). 化工进展(Chemical Industry and Engineering Process), 2008, 27(6): 917-921
[10] Zhang S B, Chu L Y, Xu D, Zhang J, Ju X J, Xie R. Polym. Adv. Technol., 2008, 19(8): 937-743
[11] 戴亚妮(Dai Y N), 李平(Li P), 王爱勤(Wang A Q). 化学进展(Progress in Chemistry), 2007, 19(2/3): 362-369
[12] Dimitrova I, Trzebickab B, Muller A H E, Dworakb A, Tsvetanov C B. Prog. Polym. Sci., 2007, 32(11): 1275-1343
[13] Wang W, Liu L, Ju X J, Zerrouki D, Xie R, Yang L, Chu L Y. ChemPhysChem, 2009, 10(14): 2405-2409
[14] Yang W C, Xie R, Pang X Q, Ju X J, Chu L Y. J. Membrane Sci., 2008, 321(2): 324-330
[15] Wu H G, Ju X J, Xie R, Liu Y M, Deng J G, Niu C H, Chu L Y. Polym. Adv. Technol., 2011, 22(9): 1389-1394
[16] Pi S W, Ju X J, Wu H G, Xie R, Chu L Y. J. Colloid Interf. Sci., 2010, 349(2): 512-518
[17] 陈永朝(Chen Y C), 谢锐(Xie R), 李鹏飞(Li P F), 巨晓洁(Ju X J), 褚良银(Chu L Y). 化工学报(J. Chem. Ind. Eng. (China)), 2010, 61(7): 1866-1872
[18] Zhang J, Xie R, Zhang S B, Cheng C J, Ju X J, Chu L Y. Polymer, 2009, 50(11): 2516-2525
[19] 汪伟(Wang W), 李鹏飞(Li P F), 谢锐(Xie R), 巨晓洁(Ju X J), 杨眉(Yang M), 褚良银(Chu L Y). 高分子材料科学与工程(Polym. Mater. Sci. Eng.), 2009, 25(12):145-148
[20] Ju X J, Liu L, Xie R, Niu C H, Chu L Y. Polymer, 2009, 50(3): 922-929
[21] 褚良银(Chu L Y), 谢锐(Xie R), 巨晓洁(Ju X J). 化工进展(Chemical Industry and Engineering Process), 2011, 30(1):167-171
[22] 童林荟(Tong L H). 环糊精化学:基础与应用(Cyclodextrin Chemistry: Infrastructure and Application). 北京:科学出版社 (Beijing: Science Press), 2001. 10-14
[23] 刘育(Liu Y), 尤长城(You C C), 张衡益(Zhang H Y). 超分子化学--合成受体的分子识别与组装(Supramolecular Chemistry: Molecular Recognition and Assembly of Synthetic Receptors). 天津: 南开大学出版社(Tianjin: Nankai University Press), 2001. 166-171
[24] Koopmans C, Ritter H. J. Am. Chem. Soc., 2007, 129(12), 3502-3503
[25] Wang H D, Chu L Y, Yu X Q, Xie R, Yang M, Xu D, Zhang J, Hu L. Ind. Eng. Chem. Res., 2007, 46, 1511-1518
[26] Liu Y Y, Fan X D. Polymer, 2002, 43(18): 4997-5003
[27] Liu Y Y, Fan X D, Hu H, Tang Z H. Macromol. Biosci., 2004, 4(8): 729-736
[28] Zhang J T, Xue Y N, Gao F Z, Huang S W, Zhuo R X. J. Appl. Polym. Sci., 2008, 108(5): 3031-3037
[29] Yang M, Chu L Y, Xie R, Wang C. Macromol. Chem. Phys., 2008, 209(2): 204-211
[30] Liu Y Y, Fan X D, Gao L. Macromol. Biosci., 2003, 3(12): 715-719
[31] Liu Y Y, Fan X D, Zhao Y B. J. Polym. Sci. Part A: Polym. Chem., 2005, 43(16): 3516-3524
[32] 马光辉(Ma G H), 苏志国(Su Z G). 高分子微球材料(Polymer Microspheres Materials). 北京: 化学工业出版社(Beijing: Chemical Industry Press), 2005
[33] Liu Y Y, Yu Y, Wei T, Sun L, Fan X D. Macromol. Biosci., 2009, 9(5): 525-534
[34] 姜晶(Jiang J), 谢锐(Xie R), 巨晓洁(Ju X J), 程昌敬(Cheng C J), 褚良银(Chu L Y). 化工进展(Chemical Industry and Engineering Process), 2009, 28(10):1771-1776
[35] 程昌敬(Cheng C J). 四川大学博士学位论文(Doctoral Dissertation of Sichuan University), 2005
[36] 陈利(Chen L), 褚良银(Chu L Y). 过滤与分离(Journal of Filtration & Separation), 2007, 17(3): 1-3, 48
[37] 谢锐(Xie R), 褚良银(Chu L Y). 膜科学与技术(Membrane Science and Technology), 2007, 27(4): 1-7
[38] Xie R, Zhang S B, Wang H D, Yang M, Li P F, Zhu X L, Chu L Y. J. Membrane Sci., 2009, 326(2): 618-626
[39] Yanagioka M, Kurita H, Yamaguchi T, Nakao S. Ind. Eng. Chem. Res., 2003, 42(2): 380-385
[40] Yang M, Xie R, Wang J Y, Ju X J, Yang L, Chu L Y. J. Membrane Sci., 2010, 355(1/2): 142-150
[41] Yang M, Chu L Y, Wang H D, Xie R, Song H, Niu C H. Adv. Funct. Mater., 2008, 18(4): 652-663
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