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化学进展 2012, Vol. 24 Issue (01): 70-79 前一篇   后一篇

• 综述与评论 •

基于环糊精和偶氮化合物的光控可逆超分子体系

孙涛, 李月明, 辛飞飞, 李尚洋, 侯月会, 郝爱友*   

  1. 山东大学化学与化工学院 济南 250100
  • 收稿日期:2011-05-01 修回日期:2011-08-01 出版日期:2012-01-24 发布日期:2011-11-22
  • 基金资助:

    山东大学研究生自主创新基金项目(No.yzc09056)资助

下载PDF ( 2717 ) 引用
导出 被引次数 ( 36 | 3 )

A Photo-Switched Supramolecular System Based on Cyclodextrins and Azo Compounds

Sun Tao, Li Yueming, Xin Feifei, Li Shangyang, Hou Yuehui, Hao Aiyou*   

  1. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
  • Received:2011-05-01 Revised:2011-08-01 Online:2012-01-24 Published:2011-11-22

超分子化学是当前化学领域的研究热点之一。基于环糊精和偶氮化合物的光控超分子可逆体系是近几年在超分子化学基础上发展起来的活跃领域。二者的复合物具有的优秀光学性质使其在光敏型自组装、催化、分子机器设计和智能材料领域受到极大的关注。本文综述了基于环糊精和偶氮化合物的光控超分子可逆体系的研究进展。介绍了该体系的研究背景、优势与原理; 根据该体系控制组装体的不同进行了分类总结,包括囊泡、凝胶、轮烷、催化体系、分子触手等; 最后结合现阶段的研究情况,对其前景与发展方向进行了展望。

关键词： 光控可逆超分子体系, 光响应, 环糊精, 偶氮化合物, 可逆包结

Supramolecular chemistry is a hot research topic in current chemistry. The photo-switched supramolecular system based on cyclodextrins and azo compounds is a new area which has been developed in supramolecular chemistry recently. Their complexation with good optical properties attracted great interest in the fields of chemical self-assembly, catalysis, molecular machine design and smart materials. Here, the development of photo-switched supramolecular system based on cyclodextrins and azo compounds is reviewed. Firstly, the background and principle of the system are introduced. Then, the different aggregates controlled by the supramolecular system, including vesicles, gels, rotaxanes, catalytic systems and molecule hands, are emphatically described. At last, combined with current development of the system, the prospects are pointed out.

Contents
1 Introduction
2 A photo-switched supramolecular system based on cyclodextrin and azo compounds
2.1 Vesicle systems controlled by photo-switched supramolecular system
2.2 Gel systems controlled by photo-switched supramolecular system
2.3 Rotaxane systems controlled by photo-switched supramolecular system
2.4 Catalytic systems controlled by photo-switched supramolecular system
2.5 Molecular hand systems controlled by photo-switched supramolecular system
3 Prospects

Key words: photo-switched supramolecular system, photo-response, cyclodextrin, azo compounds, reversible inclusion

中图分类号: 

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[1] Pedersen C J. Angew. Chem. Int. Ed. Engl., 1988, 27: 1021-1027
[2] Cram D J. Angew. Chem. Int. Ed. Engl., 1988, 27: 1009-1020
[3] Lehn J M. Angew. Chem. Int. Ed. Engl., 1988, 27: 89-112
[4] 孙涛(Sun T), 张华承(Zhang H C), 李月明(Li Y M), 辛飞飞(Xin F F), 孔丽(Kong L), 郝爱友(Hao A Y). 化学进展(Progress in Chemistry), 2010, 22(11): 2156-2164
[5] 童林荟(Tong L H). 环糊精化学--基础与应用(Cyclodextrin Chemistry--Foundation and Application). 北京: 科学出版社(Beijing: Science Press), 2001. 10-20
[6] 金征宇(Jin Z Y), 徐学明(Xu X M), 陈寒青(Chen H Q), 李学红(Li X H). 环糊精化学(Cyclodextrins Chemistry). 北京: 化学工业出版社(Beijing: Chemical Industry Press), 2009
[7] Uekama K, Hirayama F, Irie T. Chem. Rev., 1998, 98: 2045-2076
[8] Sun T, Zhang H, Yan H, Li J, Cheng G, Hao A, Qiao H, Xin F. Supramol. Chem., 2011, 23(5): 351-364
[9] 郭明雨(Guo M Y), 江明(Jiang M). 化学进展(Progress in Chemistry), 2007, 19(4): 557-566
[10] Yu Y L, Nakano M, Ikeda T. Nature, 2003, 425(6954): 145-145
[11] Yamada M, Kondo M, Mamiya J I, Yu Y, Kinoshita M, Barrett C J, Ikeda T. Angew. Chem. Int. Ed., 2008, 47(27): 4986-4988
[12] Natansohn A, Rochon P. Chem. Rev., 2002, 102(11): 4139-4175
[13] Gibbons W M, Shannon P J, Sun S T, Swetlin B J. Nature, 1991, 351(6321): 49-50
[14] Breslow R, Dong S D. Chem. Rev., 1998, 98: 1997-2012
[15] Dugave C, Demange L. Chem. Rev., 2003, 103: 2475-2532
[16] Service R F. Science, 2005, 309: 95-95
[17] Pileni M P. Nature Mater., 2003, 2(5): 145-150
[18] Song A, Jia X, Teng M, Hao J. Chem. Eur. J., 2007, 13(17): 496-501
[19] Zhang X, Wang C. Chem. Soc. Rev., 2011, 40(1)j: 94-101
[20] Zou J, Tao F, Jiang M. Langmuir, 2007, 23: 12791-12794
[21] Wang Y, Ma N, Wang Z, Zhang X. Angew. Chem. Int. Ed., 2007, 46: 2823-2826
[22] Zou J, Guan B, Liao X, Jiang M, Tao F. Macromolecules, 2009, 42: 7465-7473
[23] Jin Q, Liu G, Liu X, Ji J. Soft Matter, 2010, 6: 5589-5595
[24] 卢国冬(Lu G D), 燕青芝(Yan Q Z), 宿新泰(Su X T), 刘中清(Liu Z Q), 葛昌纯(Ge C C). 化学进展(Progress in Chemistry), 2007, 19(4): 485-493
[25] Takashima Y, Nakayama T, Miyauchi M, Kawaguchi Y, Yamaguchi H, Harada A. Chem. Lett., 2004, 33(7): 890-891
[26] Tomatsu I, Hashidzume A, Harada A. J. Am. Chem. Soc., 2006, 128: 2226-2227
[27] Tomatsu I, Hashidzume A, Harada A. Macromolecules, 2005, 38: 5223-5227
[28] Liao X, Chen G, Liu X, Chen W, Chen F, Jiang M. Angew. Chem., 2010, 122: 4511-4515
[29] Zhao Y, Stoddart J F. Langmuir, 2009, 25(15): 8442-8446
[30] Tamesue S, Takashima Y, Yamaguchi H, Shinkai S, Harada A. Angew. Chem. Int. Ed., 2010, 49: 7461-7464
[31] 翟春熙(Zhai C X), 黄飞鹤(Huang F H ). 中国科学B辑: 化学(Sci. China Ser. B), 2009, 39(4): 315-328
[32] Murakami H, Kawabuchi A, Kotoo K, Kunitake M, Nakashima N. J. Am. Chem. Soc., 1997, 119: 7605-7606
[33] Tomatsu I, Hashidzume A, Harada A. Angew. Chem., 2006, 118: 4721-4724
[34] Wang Q, Ma X, Qu D, Tian H. Chem. Eur. J., 2006, 12: 1088-1096
[35] Ma X, Wang Q, Qu D, Xu Y, Ji F, Tian H. Adv. Funct. Mater., 2007, 17: 829-837
[36] Zhu L, Ma X, Ji F, Wang Q, Tian H. Chem. Eur. J., 2007, 13: 9216-9222
[37] Fujimoto T, Nakamura A, Inoue Y, Sakataa Y, Kaneda T. Tetrahedron Lett., 2001, 42: 7987-7989
[38] Inoue Y, Kuad P, Okumura Y, Takashima Y, Yamaguchi H, Harada A. J. Am. Chem. Soc., 2007, 129: 6396-6397
[39] Li S, Taura D, Hashidzume A, Harada A. Chem. Asian J., 2010, 5: 2281-2289
[40] Ueno A, Takahashi K, Osa T J C S. Chem. Commun., 1980, 837-838
[41] Ueno A, Takahashi K, Osa T J C S. Chem. Commun., 1981, 94-96
[42] Lee W, Ueno A. Macromol. Rapid Commun., 2001, 22: 448-450
[43] Banerjee I A, Yu L, Matsui H. J. Am. Chem. Soc., 2003, 125: 9542-9543
[44] Wang Z, Li Z, Liu Z. J. Phys. Chem. C, 2009, 113(10): 3899-3902
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