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化学进展 2012, Vol. 24 Issue (01): 163-172 前一篇   后一篇

• 综述与评论 •

双相致密透氧膜

陈婷1, 赵海雷1,2*, 谢志翔1, 徐景璨1, 徐南生1, 李福燊1,2   

  1. 1. 北京科技大学材料科学与工程学院 北京 100083;
    2. 新能源材料与技术北京市重点实验室 北京 100083
  • 收稿日期:2011-05-01 修回日期:2011-06-01 出版日期:2012-01-24 发布日期:2011-11-22
  • 基金资助:

    国家自然科学基金项目(No.20973021),北京市自然科学基金项目(No.2102031)及国家高技术发展计划(863)项目(No.2006AA11A189)资助

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导出 被引次数 ( 19 | 2 )

Dense Dual-Phase Oxygen Permeation Membranes

Chen Ting1, Zhao Hailei1,2*, Xie Zhixiang1, Xu Jingcan1, Xu Nansheng1, Li Fushen1,2   

  1. 1. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;
    2. Beijing Key Laboratory of New Energy Materials and Technology, Beijing 100083, China
  • Received:2011-05-01 Revised:2011-06-01 Online:2012-01-24 Published:2011-11-22

混合导体透氧材料由于在高温下具有氧离子导电特性,在纯氧制备、膜反应器及富氧燃烧等方面显示出广阔的应用前景。单相混合导体材料用作透氧材料时存在稳定性不足、机械性能差等问题,限制了其在生产中的实际应用。在离子导体相中掺入电子导体相形成双相导体膜可以提高透氧材料在高温下和高氧浓度梯度下的工作稳定性和化学稳定性。本文详细论述了双相透氧材料的透氧机理和研究进展,包括氧离子导体/贵金属电子导体和氧离子导体/氧化物电子导体和氧离子导体/混合导体等的复合形式。重点分析了材料的组成、结构以及两相之间的化学相容性和混合比例对材料透氧率和工作稳定性的影响。介绍了双相材料在甲烷部分氧化制合成气(POM)膜反应过程及富氧燃烧中的应用,分析了目前有待解决的问题并提出了今后的研究方向。

关键词： 混合导体, 离子导体相, 电子导体相, 陶瓷膜, 氧分离

Mixed conducting membranes that exhibit oxygen ion conduction at elevated temperature are of significant interest due to their potential applications for oxygen production, partial oxidation of methane to syngas (POM), and oxygen-enriched combustion. Well-investigated single-phase conductors show some disadvantages, such as poor long-term stability and low mechanical strength, limiting their practical applications. The dual phase membrane made from ionic and electronic conducting phases could improve the performance of long-term stability and chemical stability at elevated temperature and high oxygen partial pressure gradient. In this paper, the oxygen permeation mechanism and the research progress in dual-phase membranes are reviewed, including ion-conducting phase/noble metal, ion-conducting phase/electron-conducting oxides, and ion-conducting phase/mixed conducting phase. The emphasis is focused on the effect of composition, lattice structure, and the chemical compatibility and mixing ratio of the two phases on the oxygen permeability and operation stability of the dual phase membrane. Their applications in POM and oxygen-enriched combustion are introduced. The present problems concerned with dual phase membrane are concluded and the main future research directions are proposed.

Contents
1 Introduction
2 Biocathode types
2.1 Aerobic biocathodes
2.2 Anaerobic biocathodes
3 Biofilm
4 Electrode materials
5 Separation
6 Biocathode applications
6.1 Dye decolouration
6.2 Biohydrogen production
6.3 Heavy metal removal
6.4 Denitrification of wastewater
6.5 Dechlorination of wastewater
7 Outlook

Key words: mixed conductor, ion-conducting phase, electron-conducting phase, ceramic membrane, oxygen separation

中图分类号: 

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[1] Zeng P Y, Ran R, Chen Z H, Gu H X, Shao Z P, Liu S M. AIChE J., 2007, 53: 3116-3124
[2] Martynczuk J, Liang F, Arnold M,Šepelák V, Feldhoff A. Chem. Mater., 2009, 21: 1586-1594
[3] Yaremchenko A A, Kharton V V, Valente A A, Snijkers F M M, Cooymans J F C, Luyten J J, Marques F M B. J. Membr. Sci., 2008, 319: 141-148
[4] Harada M, Domen K, Hara M, Tatsumi T. Chem. Lett., 2006, 35: 968-969
[5] Gu X H, Jin W Q, Chen C L, Xu N P, Shi J, Ma Y H. AIChE J., 2002, 48: 2051-2060
[6] Li Y, Zhao H L, Xu N S, Shen Y N, Lu X G, Ding W Z, Li F S. J. Membr. Sci., 2010, 362: 460-470
[7] Shao Z P, Yang W S, Cong Y, Dong H, Tong J H, Xiong G X. J. Membr. Sci., 2000, 172: 177-188
[8] Teraoka Y, Zhang H M, Furukawa S, Yamazoe N. Chem. Lett., 1985, 14: 1743-1746
[9] Pei S, Kleefisch M S, Kobylinski T P, Faber J, Udovich C A, Zhang-McCoy V, Dabrowski B, Balachandran U, Mieville R L, Poeppel R B. Catal. Lett., 1995, 30: 201-212
[10] Kruidhof H, Bouwmeester H J M, Doom R H E v, Burggraaf A J. Solid State Ionics, 1993, 63/65: 816-822
[11] Yaremchenko A A, Kharton V V, Avdeev M, Shaula A L, Marques F M B. Solid State Ionics, 2007, 178: 1205-1217
[12] Kharton V V, Kovalevsky A V, Viskup A P, Figueiredo F M, Yaremchenko A A, Naumovich E N, Marques F M B. J. Eur. Ceram. Soc., 2001, 21: 1763-1767
[13] Chen C S, Liu W, Xie S, Zhang G G, Liu H, Meng G Y, Peng D K. Adv. Mater., 2000, 12: 1132-1134
[14] 金万勤(Jin W Q), 徐南平(Xu N P). 化工进展(Chemical Industry and Engineering Progress), 2006, 25(10): 1143-1151
[15] 邵宗平(Shao Z P), 熊国兴(Xiong G X). 化学进展(Progress in Chemistry), 1999, 11(1): 30-40
[16] 佟建华(Tong J H), 杨维慎(Yang W S). 膜科学与技术(Membrane Science and Technology), 2003, 23 (1): 34-42
[17] 邵宗平(Shao Z P), 熊国兴(Xiong G X), 杨维慎(Yang W S). 无机材料学报(Journal of Inorganic Materials), 2001, 16(1): 23-31
[18] Kobayashi K, Nishioka M, Sato K, Inoue T, Hamakawa S, Tsunoda T. J. Solid State Electrochem, 2006, 10: 629-634
[19] Wagner C, Schottky W. Z. Physik. Chem. B, 1930, 11: 25
[20] Ge L, Shao Z P, Zhang K, Ran R, Costa J C D, Liu S M. AIChE J., 2009, 55: 2603-2613
[21] Zhu X F, Wang H H, Cong Y, Yang W S. Catal. Lett., 2006, 111: 179-185
[22] Van Doorn R H E, Bouwmeester H J M, Burggraaf A J. Solid State Ionics, 1998, 111: 263-272
[23] 朱雪峰(Zhu X F), 杨维慎(Yang W S). 催化学报(Chinese Journal of Catalysis), 2009, 30(8): 801-816
[24] Mazanec T J, Cable T L, Frye J G. Solid State Ionics, 1992, 53/56: 111-118
[25] Chen C S, Boukamp B A, Bouwmeester H J M, Cao G Z, Kruidhof H, Winnubst A J A, Burggraaf A J. Solid State Ionics, 1995, 76: 23-28
[26] Wu Z L, Liu M L. Solid State Ionics, 1996, 93: 65-84
[27] Chen C S, Kruidhof H, Bouwmeester H J M, Verweij H, Burggraaf A J. Solid State Ionics, 1996, 86/88: 569-572
[28] Joshi A V, Kulkarni S, Nachlas J, Diamond J, Weber N, Virkar A V. J. Mater. Sci., 1990, 25: 1237-1245
[29] Kruidhof H, Bouwmeester H J M, Vries K J de, Gellings P J, Burggraaf A J. Solid State Ionics, 1992, 50: 181-186
[30] Chen C S, Burggraaf A J. Appl. Electrochem., 1999, 29: 355-360
[31] Kobayashi K, Tsunoda T. Solid State Ionics, 2004, 175: 405-408
[32] Tilley R J D. J. Solid State Chem., 1982, 41: 233-243
[33] Takahashi T, Esaka T, Iwahara H. J. Solid State Chem., 1976, 16: 317-323
[34] Lee T H, Yang Y L, Jacobson A J. Solid State Ionics, 2000, 134: 331-339
[35] Wu K, Xie S, Jiang G S, Liu W, Chen C S. J. Membr. Sci., 2001, 188: 189-193
[36] Zeng Y. Doctoral Dissertation of University of Cincinnati, 1998
[37] Kim J, Lin Y S. J. Membr. Sci., 2000, 167: 123-133
[38] Zhu X F, Yang W S. AIChE J., 2008, 54: 665-672
[39] 孙帆(Sun F), 郑勇(Zheng Y), 高小龙(Gao X L), 王秋红(Wang Q H). 金属功能材料(Metallic Functional Materials), 2010, 17: 75-80
[40] Wang B, Zhan M C, Zhu D C, Liu W, Chen C S. J. Solid State Electrochem., 2006, 10: 625-628
[41] Kharton V V, Kovalevsky A V, Viskup A P, Figueiredo F M, Yaremchenko A A, Naumovich E N, Marques F M B. J. Electrochem. Soc., 2000, 147: 2814-2821
[42] Kharton V V, Kovalevsky A V, Viskup A P, Shaula A L, Figueiredo F M, Naumovich E N, Marques F M B. Solid State Ionics, 2003, 160: 247-258
[43] Yi J X, Zuo Y B, Liu W, Winnubst L, Chen C S. J. Membr. Sci., 2006, 280: 849-855
[44] Wang B, Yi J X, Winnubst L, Chen C S. J. Membr. Sci., 2006, 286: 22-25
[45] Li W, Tian T F, Shi F Y, Wang Y S, Chen C S. Ind. Eng. Chem. Res., 2009, 48: 5789-5793
[46] 吴修胜(Wu X S). 安徽建筑(Anhui Architecture), 2008, 6: 152-153
[47] 韩敏芳(Han M F), 李震(Li Z), 杜晓佳(Du X J), 陈鑫(Chen X). 稀有金属材料与工程(Rare Metal Materials and Engineering), 2009, z2: 708-711
[48] Takamura H, Koshino Y, Kamegawa A, Okada M. Solid State Ionics, 2006, 177: 2185-2189
[49] Kagomiya I, Iijima T, Takamura H. J. Membr. Sci., 2006, 286: 180-184
[50] Shaula A L, Kharton V V, Marques F M B. J. Eur. Ceram. Soc., 2004, 24: 2631-2639
[51] Wang H H, Yang W S, Cong Y, Zhu X F, Lin Y S. J. Membr. Sci., 2003, 224: 107-115
[52] Zhang K, Ge L, Ran R, Shao Z P, Liu S M. Acta Mater., 2008, 56: 4876-4889
[53] Taskin A A, Lavrov A N, Ando Y. Prog. Solid State Chem., 2007, 35: 481-490
[54] Choi M B, Jeon S Y, Hwang H J, Park J Y, Song S J. Solid State Ionics, 2010, 181: 1680-1684
[55] Chen T, Zhao H L, Xu N S, Li Y, Lu X G, Ding W Z, Li F S. J. Membr. Sci., 2011, 370: 158-165
[56] Shen Y S, Liu M, Taylor D, Bolagopal S, Joshi A, Krist K. Proc. 2nd Int. Symp. On Ionic and Mixed Conducting Ceramics, 94-12, T. A. NJ; The Electrochemical Society, 1994, 574-595
[57] 胡捷(Hu J), 贾庆超(Jia Q C), 范玉山(Fan Y S), 郭益群(Guo Y Q), 胡行(Hu X). 天然气化工(Natural Gas Chemical Industry), 2006, 31(3): 61-66
[58] Dong H, Shao Z P, Xiong G X, Tong J H, Sheng S S, Yang W S. Catal. Today, 2001, 67: 3-13
[59] Zhu X F, Li Q M, He Y F, Cong Y, Yang W S. J. Membr. Sci., 2010, 360: 454-460
[60] Zhu X F, Li Q M, Cong Y, Yang W S. Catal. Commun., 2008, 10: 309-312
[61] Takamura H, Sugai H, Watanabe M, Kasahara T, Kamegawa A, Okada M. J. Electroceram., 2006, 17: 741-748
[62] Kneer R, Toporov D, Förster M, Christ D, Broeckmann C, Pfaff E, Zwick M, Modigell S, Engels M. Energy Environ. Sci., 2010, 3: 198-207
[63] Cheng Y, Zhao H, Teng D, Li F, Lu X, Ding W. J. Membr. Sci., 2008, 322: 484-490
[64] Martynczuk J, Efimov K, Robben L, Feldhoff A. J. Membr. Sci., 2009, 344: 62-70
[65] Luo H X, Efimov K, Jiang H Q, Feldhoff A, Wang H H, Caro J. Angew. Chem. Int. Ed., 2011, 50: 759-763
[66] Watanabe K, Yuasa M, Kida T, Shimanoe K, Teraoka Y, Yamazoe N. Chem. Mater., 2008, 20: 6965-6973
[67] Watanabe K, Yuasa M, Kida T, Teraoka Y, Yamazoe N, Shimanoe K. Adv. Mater., 2010, 22: 2367-2370
[68] Leo A, Liu S M, Costa J D. J. Membr. Sci., 2009, 340: 148-153
[69] 周健儿(Zhou J E), 朱志刚(Zhu Z G), 梁健(Liang J), 马光华(Ma G H), 顾幸勇(Gu X Y). 中国陶瓷工业(China Ceramic Industry), 2001, 8: 41-45
[70] Mondal P, Klein A, Jaegermann W, Hahn H. Solid State Ionics, 1999, 118: 331-339
[71] Wu Z T, Dong X L, Jin W Q, Fan Y Q, Xu N P. J. Membr. Sci., 2007, 291: 172-179tional Materials), 2010, 17: 75-80

[40] Wang B, Zhan M C, Zhu D C, Liu W, Chen C S. J. Solid State Electrochem., 2006, 10: 625-628

[41] Kharton V V, Kovalevsky A V, Viskup A P, Figueiredo F M, Yaremchenko A A, Naumovich E N, Marques F M B. J. Electrochem. Soc., 2000, 147: 2814-2821

[42] Kharton V V, Kovalevsky A V, Viskup A P, Shaula A L, Figueiredo F M, Naumovich E N, Marques F M B. Solid State Ionics, 2003, 160: 247-258

[43] Yi J X, Zuo Y B, Liu W, Winnubst L, Chen C S. J. Membr. Sci., 2006, 280: 849-855

[44] Wang B, Yi J X, Winnubst L, Chen C S. J. Membr. Sci., 2006, 286: 22-25

[45] Li W, Tian T F, Shi F Y, Wang Y S, Chen C S. Ind. Eng. Chem. Res., 2009, 48: 5789-5793

[46] 吴修胜(Wu X S). 安徽建筑(Anhui Architecture), 2008, 6: 152-153

[47] 韩敏芳(Han M F), 李震(Li Z), 杜晓佳(Du X J), 陈鑫(Chen X). 稀有金属材料与工程(Rare Metal Materials and Engineering), 2009, z2: 708-711

[48] Takamura H, Koshino Y, Kamegawa A, Okada M. Solid State Ionics, 2006, 177: 2185-2189

[49] Kagomiya I, Iijima T, Takamura H. J. Membr. Sci., 2006, 286: 180-184

[50] Shaula A L, Kharton V V, Marques F M B. J. Eur. Ceram. Soc., 2004, 24: 2631-2639

[51] Wang H H, Yang W S, Cong Y, Zhu X F, Lin Y S. J. Membr. Sci., 2003, 224: 107-115

[52] Zhang K, Ge L, Ran R, Shao Z P, Liu S M. Acta Mater., 2008, 56: 4876-4889

[53] Taskin A A, Lavrov A N, Ando Y. Prog. Solid State Chem., 2007, 35: 481-490

[54] Choi M B, Jeon S Y, Hwang H J, Park J Y, Song S J. Solid State Ionics, 2010, 181: 1680-1684

[55] Chen T, Zhao H L, Xu N S, Li Y, Lu X G, Ding W Z, Li F S. J. Membr. Sci., 2011, 370: 158-165

[56] Shen Y S, Liu M, Taylor D, Bolagopal S, Joshi A, Krist K. Proc. 2nd Int. Symp. On Ionic and Mixed Conducting Ceramics, 94-12, T. A. NJ; The Electrochemical Society, 1994, 574-595

[57] 胡捷(Hu J), 贾庆超(Jia Q C), 范玉山(Fan Y S), 郭益群(Guo Y Q), 胡行(Hu X). 天然气化工(Natural Gas Chemical Industry), 2006, 31(3): 61-66

[58] Dong H, Shao Z P, Xiong G X, Tong J H, Sheng S S, Yang W S. Catal. Today, 2001, 67: 3-13

[59] Zhu X F, Li Q M, He Y F, Cong Y, Yang W S. J. Membr. Sci., 2010, 360: 454-460

[60] Zhu X F, Li Q M, Cong Y, Yang W S. Catal. Commun., 2008, 10: 309-312

[61] Takamura H, Sugai H, Watanabe M, Kasahara T, Kamegawa A, Okada M. J. Electroceram., 2006, 17: 741-748

[62] Kneer R, Toporov D, Förster M, Christ D, Broeckmann C, Pfaff E, Zwick M, Modigell S, Engels M. Energy Environ. Sci., 2010, 3: 198-207

[63] Cheng Y, Zhao H, Teng D, Li F, Lu X, Ding W. J. Membr. Sci., 2008, 322: 484-490

[64] Martynczuk J, Efimov K, Robben L, Feldhoff A. J. Membr. Sci., 2009, 344: 62-70

[65] Luo H X, Efimov K, Jiang H Q, Feldhoff A, Wang H H, Caro J. Angew. Chem. Int. Ed., 2011, 50: 759-763

[66] Watanabe K, Yuasa M, Kida T, Shimanoe K, Teraoka Y, Yamazoe N. Chem. Mater., 2008, 20: 6965-6973

[67] Watanabe K, Yuasa M, Kida T, Teraoka Y, Yamazoe N, Shimanoe K. Adv. Mater., 2010, 22: 2367-2370

[68] Leo A, Liu S M, Costa J D. J. Membr. Sci., 2009, 340: 148-153

[69] 周健儿(Zhou J E), 朱志刚(Zhu Z G), 梁健(Liang J), 马光华(Ma G H), 顾幸勇(Gu X Y). 中国陶瓷工业(China Ceramic Industry), 2001, 8: 41-45

[70] Mondal P, Klein A, Jaegermann W, Hahn H. Solid State Ionics, 1999, 118: 331-339

[71] Wu Z T, Dong X L, Jin W Q, Fan Y Q, Xu N P. J. Membr. Sci., 2007, 291: 172-179
[1] 邵宗平,熊国兴. 混合导体透氧膜及其在甲烷部分氧化制合成气反应中的应用[J]. 化学进展, 1999, 11(01): 30-.
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双相致密透氧膜