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化学进展 2012, Vol. Issue (9): 1646-1655 前一篇   后一篇

• 特约稿 •

金属-有机骨架材料用于废水处理

童敏曼, 赵旭东, 解丽婷, 刘大欢*, 阳庆元, 仲崇立*   

  1. 北京化工大学有机无机复合材料国家重点实验室 北京 100029
  • 收稿日期:2012-04-01 修回日期:2012-06-01 出版日期:2012-09-24 发布日期:2012-09-27
  • 通讯作者: 刘大欢, 仲崇立 E-mail:liudh@mail.buct.edu.cn; zhongcl@mail.buct.edu.cn
  • 基金资助:

    国家自然科学基金重点项目(No. 21136001)和国家自然科学基金委创新群体项目(No.21121064)资助

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Treatment of Waste Water Using Metal-Organic Frameworks

Tong Minman, Zhao Xudong, Xie Liting, Liu Dahuan, Yang Qingyuan, Zhong Chongli   

  1. State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2012-04-01 Revised:2012-06-01 Online:2012-09-24 Published:2012-09-27
废水中的各种有害物质常常具有生物毒性或致癌性,因此如何高效、节能地处理水体污染是一个亟待解决的重要问题。金属-有机骨架材料(metal-organic frameworks, MOFs)是一种新型纳米多孔材料,具有种类多样性、结构可设计性与可调控性、高比表面积及良好的热稳定性等优点,已成为当前化学、材料学科的一个研究热点, 在多个领域显示出潜在的应用前景,尤其是在分离方面。与气相分离相比,MOFs用于液相分离的研究较少。本文综述了近年来MOFs用于含有染料、药物、醇、芳香族化合物、重金属离子及其他离子的废水处理的研究进展,重点剖析了MOFs的孔结构、骨架电荷及功能性对分离效果的影响,并结合本课题组的研究工作,对这种新型多功能材料在水处理方面的前景和今后的研究重点作了展望。
关键词： 金属-有机骨架材料, 废水处理, 分离, 构效关系
Harmful compounds and heavy metal ions in waste water are often biologically toxic and/or carcinogenic. Thus, removal of these substances from waste water in an efficient way has drawn considerable social and scientific concern in recent years. Metal-organic frameworks (MOFs), commonly recognized as “soft” analogues of zeolites, is a new class of nanoporous materials with various topologies, adjustable pore size, controllable properties, large surface area, as well as acceptable thermal stability. MOFs have received much attention in the fields of chemistry and materials science and have shown potential applications with well performance compared to the traditional porous materials including zeolites and activated carbons, especially in separation. Though gas phase separation using MOFs has been extensively studied and reviewed, studies on liquid phase separation are scarce. This review introduces the research progress on waste water treatment using MOFs, in which different harmful substances such as organic dyes, pharmaceuticals, alcohols, aromatic compounds, heavy metal ions and inorganic ions are included. Detailed analysis of the effect of the pore structure, framework charge and functional group on separation is provided. In addition, future studies that should be focused in this field are proposed based on the existed works combined with the research results in our group. Contents 1 Introduction
2 Metal-organic frameworks for waste water treatment
2.1 Removal of organics
2.2 Removal of inorganics
3 Conclusions and outlook
Key words: metal-organic frameworks, waste water treatment, separation, structure-property relationship

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摘要

金属-有机骨架材料用于废水处理