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化学进展 2011, Vol. 23 Issue (8): 1692-1699 前一篇   后一篇

• 综述与评论 •

叠氮聚合物的合成

李光1,2, 白如科1*   

  1. 1. 中科院软物质化学重点实验室 中国科学技术大学高分子科学与工程系 合肥 230026;
    2. 聊城大学材料科学与工程学院 聊城 252059
  • 收稿日期:2010-11-01 修回日期:2011-01-01 出版日期:2011-08-24 发布日期:2011-07-25
  • 通讯作者: 白如科 E-mail:bairk@ustc.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.20674076)资助

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Synthesis of Azide Polymers

Li Guang1,2, Bai Ruke1*   

  1. 1. CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China;
    2. College of Materials Science and Engineering, Liaocheng University, Liaocheng 252059, China
  • Received:2010-11-01 Revised:2011-01-01 Online:2011-08-24 Published:2011-07-25

叠氮基团不仅是高含能基团和高反应性基团,而且也可以被转化为其他官能基团。叠氮聚合物可用作高能黏合剂、交联材料以及表面改性材料等,还可以作为合成功能高分子的前体,因此叠氮聚合物的合成研究引起了高分子科学家的广泛关注。到目前为止,叠氮聚合物的合成方法研究取得了新的进展,主要包括: 高分子化学改性法、环醚类叠氮单体阳离子开环聚合法和不饱和叠氮单体自由基聚合法。本文综述了近些年来叠氮聚合物的合成研究方面取得的主要成果和进展,其中包括本课题组的一些研究工作。

关键词： 叠氮聚合物, 高分子, 化学改性, 阳离子开环聚合, 活性自由基聚合, 合成

Azide groups are not only energetic and highly reactive groups, but also can be transformed into a variety of functional groups. With the development of the polymer science, azide polymers have been widely used as high energetic binders, cross-linking materials, materials for surface modification, and precursors of functional polymers. The synthesis of azide polymers has attracted great attention of polymer scientists. Until now, a number of synthetic methods for different azide polymers have been developed such as chemical modification of polymers, cationic ring-opening polymerization of cyclic ether azide monomers, and radical polymerization of unsaturated azide monomers. In this paper, the recent progresses on the synthesis of azide polymers, including the achievements of our research group, are summarized.

Contents
1 Introduction
2 Chemical modification of polymers
2.1 Azide polymers with ether chain as main chain
2.2 Azide polymers with carbon chain as main chain
3 Cationic ring-opening polymerization
4 Radical polymerization
4.1 Conventional radical polymerization
4.2 Living radical polymerization
5 Other synthesis methods
6 Outlook

Key words: azide polymers, polymers, chemical modification, cationic ring-opening polymerization, living radical polymerization, synthesis

中图分类号: 

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摘要

叠氮聚合物的合成