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化学进展 2011, Vol. 23 Issue (8): 1665-1682 前一篇   后一篇

• 综述与评论 •

含磷杯芳烃及其配合物的合成与应用

刘智成, 王红*, 杨睿, 李玮*   

  1. 昆明理工大学理学院应用化学系 昆明 650093
  • 收稿日期:2010-10-01 修回日期:2010-12-01 出版日期:2011-08-24 发布日期:2011-07-25
  • 通讯作者: 王红, 李玮 E-mail:hong4w2002@hotmail.com; lwg3@163.com
  • 基金资助:

    昆明理工大学创新基金项目(No.2010BA043)、昆明理工大学分析测试基金项目(No.2010282)和国家大学生创新性实验计划项目(No.101067410)资助

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Synthesis and Application of Phosphorous-Containing Calixarenes and Their Complexes

Liu Zhicheng, Wang Hong*, Yang Rui, Li Wei*   

  1. Department of Applied Chemistry, School of Sciences, Kunming University of Science and Technology, Kunming 650093, China
  • Received:2010-10-01 Revised:2010-12-01 Online:2011-08-24 Published:2011-07-25

含磷杯芳烃作为一类特殊杯芳烃主体分子,可以通过不同的方式与众多的客体分子作用,形成主体-客体配合物。无论是母体含磷杯芳烃或其配合物都在分子识别、自组装、生物酶模拟、药物设计、化学传感器和金属催化剂的开发等方面显示出广阔的应用潜力。本文综述了近十年来含磷杯芳烃及其配合物的研究进展。对一些新型含磷杯芳烃及其配合物的合成方法与应用作了重点介绍,并展望了研究和发展方向。

关键词： 杯芳烃, 磷, 超分子化学, 配合物, 合成, 应用

As a class of particular host molecules, phosphorous-containing calixarenes, can form host-guest complexes with numerous guest molecules by different ways. Either the calixarenes or their complexes, show extensive application potential in many fields, such as molecular recognition, self-assembly, mimic of biological enzyme, drug design, chemsensor and metal catalyst exploitation. In this article, research progress during past decade on phosphorous-containing calixarenes and their complexes is reviewed, with focuses on synthetic methods as well as applications of novel phosphorous-containing calixarenes and their complexes. The research trend is also prospected.

Contents
1 Introduction
2 Synthesis of phosphorous-containing calixarenes and their complexes
2.1 Calix[4]arenes and their complexes
2.2 Calix[5]arenes and their complexes
2.3 Calix[6]arenes and their complexes
2.4 Other higher order calixarenes and their complexes
2.5 Resorcinarenes and their complexes
2.6 Biscalixarenes and their complexes
3 Applications of phosphorous-containing calixarenes and their complexes
3.1 Mimic and inhibition of enzyme
3.2 Drug design
3.3 Molecular recognition
3.4 Self-assembly
4 Conclusion and prospective

Key words: calixarene, phosphorous, supramolecular chemistry, complexes, synthesis, application

中图分类号: 

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