English
往期目录
新闻公告
More
化学进展 2011, Vol. 23 Issue (8): 1598-1610 前一篇   后一篇

• 综述与评论 •

可充镁电池电解液

赵青松, 努丽燕娜*, 郭永胜, 杨军, 王久林   

  1. 上海交通大学化学化工学院 上海 200240
  • 收稿日期:2010-11-01 修回日期:2011-03-01 出版日期:2011-08-24 发布日期:2011-07-25
  • 通讯作者: 努丽燕娜 E-mail:nlyn@sjtu.edu.cn
下载PDF ( 2074 ) 引用
导出 被引次数 ( 41 )

Electrolytes for Rechargeable Magnesium Batteries

Zhao Qingsong, Nuli Yanna*, Guo Yongsheng, Yang Jun, Wang Jiulin   

  1. School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
  • Received:2010-11-01 Revised:2011-03-01 Online:2011-08-24 Published:2011-07-25

由于金属镁具有能量密度较高、价格低、操作安全等优点,可充镁电池是在大负荷储能方面极具发展潜力的二次电池。本文综述了可充镁电池电解液的研究进展,其中包括溶于醚溶剂中的格氏试剂、Mg(BR2R′2)2(其中R、R′为烷基或芳基)、Mg(AX4-nRn′R′n″)2络合物(其中A=Al、B、Sb、P、As、Fe和Ta等,X =Cl、Br和F,R、R′为烷基或芳基,0<n<4,n′+n″= n)或氨基镁卤化物的有机溶液体系、可传导镁离子的熔盐体系和聚合物电解质体系;简述了各种体系的性能和特点,并对可充镁电池电解液的进一步研究和应用前景进行了展望。

关键词： 可充镁电池, 电解液, Mg(AX4-nRn′R′n″)2络合物, 熔盐, 聚合物电解质

Rechargeable magnesium batteries may be a potential candidate for heavy load application due to higher energy density, cheap raw material costs and easy to handle of magnesium. In this paper, the recent research advances on electrolytes for rechargeable magnesium batteries are reviewed, especially on ethereal solutions of Grignard reagents, Mg(BR2R′2)2 (R、R′ = alkyl or aryl groups), Mg(AX4-nRn′R′n″)2 complexes (A = Al, B, Sb, P, As, Fe and Ta, X = Cl, Br and F, R、R′ = alkyl or aryl groups, 0<n<4, n′+n″= n) or amidomagnesium halides, Mg ion conductive molten salts and polymeric electrolytes. The performances and characteristics of above three systems are presented, and further researches and developments are proposed.

Contents
1 Introduction
2 Ether-based organic electrolytes
2.1 Grignard reagents
2.2 Mg(BR2R′2)2
2.3 Mg(AX4-nRn′R′n″)2 complexes
2.4 Amidomagnesium halides
2.5 Others
3 Molten salts
3.1 Ionic liquids
3.2 High temperature molten salts
4 Polymeric electrolytes
5 Inorganic solid electrolytes
6 Conclusions and outlook

Key words: rechargeable magnesium batteries, electrolytes, Mg(AX4-nRn′R′n″)2 complexes, molten salts, polymeric electrolytes

中图分类号: 

()

[1] 师昌绪(Shi C X), 李恒德(Li H D), 王淀佐(Wang D Z), 李依依(Li Y Y), 左铁镛(Zuo T Y). 材料导报(Materials Review), 2001, 15: 5-6
[2] 彭成红(Peng C H), 朱敏(Zhu M). 电池(Battery), 2003, 33: 121-123
[3] 杨维谦(Yang W Q), 杨少华(Yang S H), 孙公权(Sun G Q), 辛勤(Xin Q). 化工进展(Chemical Industry and Engineering Process), 2008, 27(2): 214-217
[4] 袁华堂(Yuan H T), 吴峰(Wu F), 武绪丽(Wu X L), 李强(Li Q). 电池(Battery), 2002, 32(6): 14-17
[5] 沈健(Shen J), 彭博(Peng B), 陶占良(Tao Z L), 陈军(Chen J). 化学进展(Prog. Chem.), 2010, 22: 515-521
[6] 冯真真(Feng Z Z), 努丽燕娜(Nuli Y N), 王久林(Wang J L), 杨军(Yang J). 化学与物理电源系统(Chemical and Physical Power Sources), 2007, 1: 73-79
[7] Aurbach D, Lu Z, Schechter A, Gofer Y, Gizbar H, Turgemann R, Cohen Y, Moshkovich M, Levi E. Nature, 2000, 407: 724-727
[8] Aurbach D, Gofer Y, Lu Z, Schechter A, Chusid O, Gizbar H, Cohen Y, Ashkenazi V, Moshkovich M, Turgeman R, Levi E. J. Power Sources, 2001, 97/98: 28-32
[9] Lorentz P L, Emmenegger F. Electrochim. Acta, 1996, 41: 445-447
[10] Evans W V, Pearson R. J. Am. Chem. Soc., 1942, 64: 2865-2871
[11] 袁华堂(Yuan H T), 刘秀生(Liu X S), 曹建胜(Cao J S), 焦丽芳(Jiao L F), 赵明(Zhao M), 王永梅(Wang Y M). 电池(Battery Bimonthly), 2004, 34(2): 138-140
[12] 李吉刚(Li J G), 孙杰(Sun J), 王凤彦(Wang F Y). 化工进展(Chemical Industry and Engineering Progress), 2008, 27(2): 214-217
[13] Nelson J M, Evans W V. J. Am. Chem. Soc., 1917, 39: 82-83
[14] Genders J D, Pletcher D. J. Electroanal. Chem., 1986, 199: 93-100
[15] Liebenow C. J. Appl. Electrochem., 1997, 27: 221-225
[16] Lu Z, Schechter A, Moshkovich M, Aurbach D. J. Electroanal. Chem., 1999, 466: 203-217
[17] Aurbach D, Moshkovich M, Schechter A, Turgeman R. Electrochem. Solid-State Lett., 2000, 3: 31-34
[18] Ito S, Yamamoto O, Kanbara T, Matsuda H, US 6713213B2, 2004
[19] Guo Y S, Yang J, NuLi Y N, Wang J L. Electrochem. Commun., 2010, 12: 1671-1673
[20] Gregory T D, Hoffman R J, Winterton J. Electrochem. Soc., 1990, 137: 775-780
[21] Liebenow C, Yang Z, Lobitz P. Electrochem. Commun., 2000, 2: 641-645
[22] Aurbach D, Schechter A, Moshkovich M, Cohen Y. J. Electrochem. Soc., 2001, 148: A1004-A1014
[23] Aurbach D, Gizbar H, Schechter A, Chusid O, Gottlieb H E, Gofer Y, Goldberg I. J. Electrochem. Soc., 2002, 149: A115-A121
[24] Gizbar H, Vestfrid Y, Chusid O, Gofer Y, Gottlieb H E, Marks V, Aurbach D. Organometallics, 2004, 23: 3826-3831
[25] Vestfried Y, Chusid O, Gofer Y, Aped P, Aurbach D. Organometallics, 2007, 26: 3130-3137
[26] Viestfried Y, Levi M D, Gofer Y, Aurbach D. J. Electroanal. Chem., 2005, 576: 183-195
[27] Nakayama Y, Kudo Y, Oki H, Yamamoto K, Kitajima Y, Noda K. J. Electrochem. Soc., 2008, 155: A754-A759
[28] Gofer Y, Chusid O, Gizbar H, Viestfrid Y, Gottlieb H E, Marks V, Aurbach D. Electrochem. Solid. State Lett., 2006, 9: A257-A260
[29] Amir N, Vestfrid Y, Chusid O, Gofer Y, Aurbach D. J. Power Sources, 2007, 174: 1234-1240
[30] 冯真真(Feng Z Z). 上海交通大学博士论文(Doctoral Dissertation of Shanghai Jiao Tong University), 2008
[31] Feng Z Z, NuLi Y N, Wang J L, Yang J. J. Electrochem. Soc., 2006, 153: C689-C693
[32] 冯真真(Feng Z Z), 努丽燕娜(Nuli Y N), 杨军(Yang J). 电池工业(Battery Industry), 2007, 12: 235-240
[33] Aurbach D, Suresh G S, Levi E, Mitelman A, Mizrahi O, Chusid O, Brunelli M. Adv. Mater., 2007, 19: 4260-4267
[34] Mizrahi O, Amir N, Pollak E, Chusid O, Marks V, Gottlieb H, Larush L, Zinigrad E, Aurbach D. J. Electrochem. Soc., 2008, 155: A103-A109
[35] NuLi Y N, Yang J, Wang J L, Li Y. J. Phys. Chem. C, 2009, 113: 12594-12597
[36] NuLi Y N, Yang J, Li Y S, Wang J L. Chem. Commun., 2010, 46: 3794-3796
[37] 努丽燕娜(NuLi Y N), 杨军(Yang J), 郑育培(Zheng Y P). 无机材料学报(Journal of Inorganic Materials), 2011, 26 (2): 129-133
[38] Feng Z Z, Yang J, NuLi Y N, Wang J L, Wang X J, Wang Z X. Electrochem. Commun., 2008, 10: 1291-1294
[39] Feng Z Z, Yang J, NuLi Y N, Wang J L. J. Power Sources, 2008, 184: 604-609
[40] Li Y, NuLi Y N, Yang J, Yilinuer T, Wang J L. Chinese Science Bulletin, 2011, 56 (4/5): 386-390
[41] 李云(Li Y), 努丽燕娜(NuLi Y N), 杨军(Yang J), 伊丽奴尔·吐胡达洪(Yilinuer T), 王久林(Wang J L). 电源技术(Chinese Journal of Power Sources), 2010, 34 (10): 1031-1034
[42] Liang Y L, Feng R J, Yang S Q, Ma H, Liang J, Chen J. Adv. Mater., 2011, 23: 640-643
[43] 焦丽芳(Jiao L F), 袁华堂(Yuan H T), 李晓冬(Li X D), 王永梅(Wang Y M, 曹建胜(Cao J S), 高秀玲(Gao X L), 赵明(Zhao M). 化学通报(Chemistry Online), 2005, 9: 714-717
[44] Earle M J, Seddon K R. Pure Appl. Chem., 2000, 72(7): 1391-1398
[45] Prvulescu V I, Hardacre C. Chem. Rev., 2007, 107: 2615-2665
[46] Galiński M, Lewandowski A, Stepniak I, Electrochim. Acta 2006, 51: 5567-5580
[47] Lewandowski A, Swiderska-Mocek A, J. Power Sources 2009, 194: 601-609
[48] 杨立(Yang L), 房少华(Fang S H). 电源技术(Chinese Journal of Power Sources), 2010, 34(2): 101-105
[49] 杨立(Yang L), 房少华(Fang S H). 电源技术(Chinese Journal of Power Sources), 2010, 34(3): 218-222
[50] NuLi Y N, Yang J, Wang J L, Xu J Q, Wang P. Electrochem. Solid-State Lett., 2005, 8(11): C166-C169
[51] NuLi Y N, Yang J, Wu R. Electrochem. Commun., 2005, 7: 1110-1115
[52] NuLi Y N, Yang J, Wang P. Appl. Surf. Sci., 2006, 252: 8086-8090
[53] 努丽燕娜(NuLi Y N), 杜国栋(Du G D), 冯真真(Feng Z Z), 沈佳妮(Shen J N), 杨军(Yang J). 化学学报(Acta Chimica Sinica), 2008, 66: 175-180
[54] 王璞(Wang P), 上海交通大学硕士论文(Master's Dissertation of Shanghai Jiao Tong University), 2006
[55] Wang P, NuLi Y N, Yang J, Feng Z Z. Surf. Coat. Technol., 2006, 201: 3783-3787
[56] 努丽燕娜(NuLi Y N), 杨军(Yang J), 高鹏飞(Gao P F), 李云(Li Y), 王久林(Wang J L). 化学学报(Acta Chimica Sinica), 2010, 68: 948-954
[57] Kakibe T, Yoshimoto N, Egashira M, Morita M. Electrochem. Commun., 2010, 12: 1630-1633
[58] Cheek G T, O'Grady W E, Zein El Abedin S, Moustafa E M, Endres F. J. Electrochem. Soc., 2008, 155: D91-D95
[59] Yoshimoto N, Matsumoto M, Egashia M, Morita M. J. Power Sources, 2010, 195: 2096-2098
[60] Venkata Narayanan N S, Ashok Raj B V, Sampath S. Electrochem. Commun., 2009, 11: 2027-2031
[61] Venkata Narayanan N S, Ashok Raj B V, Sampath S. J. Power Sources, 2010, 195: 4356-4364
[62] Kisza A, Ka Dz＇ mierczak J, Brressen B, Haarberg G M, Tunold R. J. Appl. Electrochem., 1995, 25: 940-946
[63] Kisza A, Kazmierczak J, Brressen B, Haarberg G M, Tunold R. J. Electrochem. Soc., 1997, 144: 1646-1651
[64] Martínez A M, Brresen B, Haarberg G M, Castrillejo Y, Tunold R. J. Electrochem. Soc., 2004, 151: C508-C513
[65] Brressen B, Haarberg G M, Tunold R. Electrochim. Acta, 1997, 42: 1613-1622
[66] Castrillejo Y, Martínez A M, Pardo R, Haarberg G M. Electrochim. Acta, 1997, 42: 1869-1876
[67] Meyer W H. Adv. Mater., 1998, 10: 439-448
[68] Agrawal R C, Pandey G P. J. Phys. D: Appl. Phys., 2008, 41: art. no. 223001
[69] 肖立新(Xiao L X), 郭炳焜(Guo B K), 李新海(Li X H). 电池(Battery Bimonthly), 2003, 33(2): 110-113
[70] Yang L L, Farrington G C, Chiodelli G. Solid State Ionic, 1986, 18/19: 291-294
[71] Yang L L, McGhie A R, Farrington G C. J. Electrochem. Soc., 1986, 133: 1380-1385
[72] Patrick A, Glasse M, Latham R, Linford R. Solid State Ionics, 1988, 18/19: 1063-1067
[73] Cherng J Y, Munshi M Z A, Owens B B, Smyrl W H. Solid State Ionics, 1988, 28/30: 857-861
[74] Jaipal Reddy M, Chu P P. Solid State Ionics, 2002, 149: 115-123
[75] Jaipal Reddy M, Chu P P. J. Power Sources, 2002, 109: 340-346
[76] Liebenow C, Reiche A, Lobitz P. Electrochim. Acta, 1998, 43: 2375-2378
[77] Liebenow C. Electrochim. Acta, 1998, 43: 1253-1256
[78] Liebenow C. Solid State Ionics, 2000, 136/137: 1211-1214
[79] Acosta J L, Morales E. Electrochim. Acta, 1998, 43: 791-797
[80] Girish Kumar G, Munichandraiah N. J. Electroanal. Chem., 2000, 495: 42-50
[81] Girish Kumar G, Munichandraiah N. Electrochim. Acta, 1999, 44: 2663-2666
[82] Girish Kumar G, Munichandraiah N. Solid State Ionics, 2000, 128: 203-210
[83] Girish Kumar G, Munichandraiah N. J. Power Sources, 2000, 91: 157-160
[84] Girish Kumar G, Munichandraiah N. J. Power Sources, 2001, 102: 46-54
[85] Girish Kumar G, Munichandraiah N. Electrochim. Acta, 2002, 47: 1013-1022
[86] Perera K, Dissanayake M A K L, Bandaranayake P W S K. Mater. Res. Bull., 2004, 39: 1745-1751
[87] Lauenstein , Tegenfeldt J. J. Phys. Chem. B, 1998, 102: 6702-6709
[88] Sheha E, El-Mansy M K. J. Power Sources, 2008, 185: 1509-1513
[89] Chusid O, Gofer Y, Gizbar H, Vestfrid Y, Levi E, Aurbach D, Riech I. Adv. Mater., 2003, 15: 627-630
[90] Aravindan V, Karthikaselvi G, Vickraman P, Naganandhini S P. J. Appl. Polym. Sci., 2009, 112: 3024-3029
[91] Saito M, Ikuta H, Uchimoto Y, Wakihara M. Yokoyama S, Yabe T, Yamamoto M. J. Electrochem. Soc., 2003, 150: A477-A483
[92] Saito M, Ikuta H, Uchimoto Y, Wakihara M, Yokoyama S, Yabe T, Yamamotoc MJ. Electrochem. Soc., 2003, 150: A726-A731
[93] Saito M, Ikuta H, Uchimoto Y, Wakihara M, Yokoyama S, Yabe T, Yamamoto M. J. Phys. Che.  B, 2003, 107: 11608-11614
[94] Morita M, Yoshimoto N, Yakushiji S, Ishikawa M. Electrochem. Solid-State Lett., 2001, 4(11): A177-A179
[95] Yoshimoto N, Tomonaga Y, Ishikawa M, Morita M. Electrochim. Acta, 2001, 46: 1195-1200
[96] Yoshimoto N, Yakushiji S, Ishikawa M, Morita M. Solid State Ionics, 2002, 152/153: 259-266
[97] Yoshimoto N, Yakushiji S, Ishikawa M, Morita M. Electrochim. Acta, 2003, 48: 2317-2322
[98] Morita M, Shirai T, Yoshimoto N, Ishikawa M. J. Power Sources, 2005, 139: 351-355
[99] Oh J S, Ko J M, Kim D W. Electrochim. Acta, 2004, 50: 903-906
[100] Pandey G P, Hashmi S A. J. Power Sources, 2009, 187: 627-634
[101] Pandey G P, Agrawal R C, Hashmi S A. J. Power Sources, 2009, 190: 563-572
[102] Kushwaha S S S, Mishra J. Current Science, 2005, 88: 1159-1161
[103] 俞文海(Yu W H), 朱斌(Zhu B), 王大志(Wang D Z). 材料科学进展 (Material Science Progress), 1988, 2: 72-77
[104] 朱斌(Zhu B), 薛立新(Xue L X), 王大志(Wang D Z), 俞文海(Yu W H). 无机材料学报(J. Inorg. Mater. ), 1987, 2(2): 176-182
[105] 朱斌(Zhu B), 陈茂春(Chen M C), 陈世红(Chen S H), 俞文海(Yu W H). 中国科学技术大学学报(Journal of China University of Science and Technology), 1989, 19: 393-398
[106] 袁望治(Yuan W Z), 劳令耳(Lao L E), 黄英才(Huang Y C). 贵州工学院学报(Journal of Guizhou University of Technology), 1996, 25: 86-91
[107] 朱斌(Zhu B), 王文楼(Wang W L), 陈茂春(Chen M C), 刘皖育(Liu W Y), 林枫凉(Lin F L), 俞文海(Yu W H). 无机材料学报(J. Inorg. Mater. ), 1991, 6: 213-218
[108] Imanaka N, Okazaki Y, Adachi G. Chem. Lett. 1999, 939-940
[109] Imanaka N, Okazaki Y, Adachi G. J. Mater. Chem., 2000, 10: 1431-1435
[110] Imanaka N, Okazaki Y, Adachi G. Electrochem. Solid-State Lett., 2000: 3: 327-329
[111] Imanaka N, Okazaki Y, Adachi G. Ionics, 2001, 7: 440-446
[1] 张旭, 张蕾, 黄善恩, 柴之芳, 石伟群. 盐包合材料在高温熔盐体系中的合成及其潜在应用[J]. 化学进展, 2022, 34(9): 1947-1956.
[2] 王许敏, 李书萍, 何仁杰, 余创, 谢佳, 程时杰. 准固相转化机制硫正极[J]. 化学进展, 2022, 34(4): 909-925.
[3] 黄祺, 邢震宇. 锂硒电池研究进展[J]. 化学进展, 2022, 34(11): 2517-2539.
[4] 陈龙, 黄少博, 邱景义, 张浩, 曹高萍. 聚合物固态锂电池电解质/负极界面[J]. 化学进展, 2021, 33(8): 1378-1389.
[5] 李文涛, 钟海, 麦耀华. 锂二次电池中的原位聚合电解质[J]. 化学进展, 2021, 33(6): 988-997.
[6] 黄国勇, 董曦, 杜建委, 孙晓华, 李勃天, 叶海木. 锂离子电池高压电解液[J]. 化学进展, 2021, 33(5): 855-867.
[7] 杨琪, 邓南平, 程博闻, 康卫民. 锂电池中的凝胶聚合物电解质[J]. 化学进展, 2021, 33(12): 2270-2282.
[8] 穆德颖, 刘铸, 金珊, 刘元龙, 田爽, 戴长松. 废旧锂离子电池正极材料及电解液的全过程回收及再利用[J]. 化学进展, 2020, 32(7): 950-965.
[9] 徐昌藩, 房鑫, 湛菁, 陈佳希, 梁风. 金属-二氧化碳电池的发展:机理及关键材料[J]. 化学进展, 2020, 32(6): 836-850.
[10] 陈嘉苗, 熊靖雯, 籍少敏, 霍延平, 赵经纬, 梁亮. 锂电池用全固态聚合物电解质[J]. 化学进展, 2020, 32(4): 481-496.
[11] 汪靖伦, 冉琴, 韩冲宇, 唐子龙, 陈启多, 秦雪英. 锂离子电池有机硅功能电解液[J]. 化学进展, 2020, 32(4): 467-480.
[12] 刘燕晨, 黄斌, 邵奕嘉, 沈牧原, 杜丽, 廖世军. 钾离子电池及其最新研究进展[J]. 化学进展, 2019, 31(9): 1329-1340.
[13] 蒋志敏, 王莉, 沈旻, 陈慧闯, 马国强, 何向明. 锂离子电池正极界面修饰用电解液添加剂[J]. 化学进展, 2019, 31(5): 699-713.
[14] 赵云, 亢玉琼, 金玉红, 王莉, 田光宇, 何向明. 锂离子电池硅基负极及其相关材料[J]. 化学进展, 2019, 31(4): 613-630.
[15] 黄路露, 孙凯玲, 刘明瑞, 李静, 廖世军. 非水系锂空气电池碳基正极材料[J]. 化学进展, 2019, 31(10): 1406-1416.
阅读次数
全文


摘要

可充镁电池电解液