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化学进展 2011, Vol. 23 Issue (7): 1379-1385 前一篇   后一篇

• 放射化学专辑 •

氚化学与工艺

彭述明, 王和义*, 傅依备   

  1. 中国工程物理研究院 绵阳 621900
  • 收稿日期:2011-03-01 修回日期:2011-04-01 出版日期:2011-07-24 发布日期:2012-03-15
  • 通讯作者: e-mail: heyiwang@tom.com E-mail:heyiwang@tom.com
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Tritium Chemistry and Techniques

Peng Shuming, Wang Heyi*, Fu Yibei   

  1. China Academy of Engineering Physics, Mianyang 621900, China
  • Received:2011-03-01 Revised:2011-04-01 Online:2011-07-24 Published:2012-03-15

氚作为一种重要的资源,在国防科技和国民经济领域有着广泛的应用。伴随着国防科技发展需求的不断提高,中国工程物理研究院在氚化学与工艺研究方面取得了一定的成就,研究领域涉及到氚的整个生命周期,包括生产、分离、储存、应用及氚废物治理等。本文重点介绍了中国工程物理研究院近年来在金属氚化物、储氚材料、氢同位素分离技术、含氚重水提氚关键技术和ITER相关氚技术等方面的研究进展。

关键词： 氚化学, 氚工艺, 国防

As one of the most important resources, tritium is widely used in the scientific researches of national defense and national economy. To satisfy the development of national defense, China Academy of Engineering Physics (CAEP)has obtained great progress in the tritium chemistry and techniques, and the research fields are focused on the whole period of the tritium, including tritium production, isotopes separation, tritium storage, tritium application and tritium waste treatment, etc. Some of the recently progress in the fundamental research of CAEP are reviewed in this paper, which mainly introduces the physical and chemical property of metal tritide, tritium storage materials, hydrogen isotopes separation techniques, tritide heavy water treatment techniques and ITER related tritium techniques, and some directions for further researches have also been proposed.

Contents
1 Introduction
2 Metal tritide
2.1 Physical and chemical property of metal tritide
2.2 Helium behaviors in metal tritide
3 Tritium storage materials
3.1 La series metals
3.2 Zr series metals and alloys
3.3 Ti and Mg series alloys
4 Hydrogen isotopes separation techniques
4.1 Gas chromatograph(GC) technique
4.2 Cryogenic distil ion(CD) technique
5 Tritiated heavy water treatment techniques
5.1 Ensemble technique
5.2 Electrolyze technique
5.3 Catalysis exchange technique
5.4 Catalysis oxidation technique
5.5 Gas chromatograph(GC) technique
6 ITER related tritium techniques
6.1 Preparation and properties of tritium breeders
6.2 Techniques of tritium extraction in liquid LiPb cycle
6.3 Techniques of tritium safety
7 Summary

Key words: tritium chemistry, tritium technique, national defense

中图分类号: 

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[1] 杨通在, 汪小琳. 国防领域放射分析化学研究进展[J]. 化学进展, 2011, 23(7): 1520-1526.
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摘要

氚化学与工艺