English
往期目录
新闻公告
More
化学进展 2011, Vol. 23 Issue (7): 1366-1371 前一篇   后一篇

• 放射化学专辑 •

从高放废液中去除锕系元素的TRPO 流程发展三十年

陈靖*, 王建晨   

  1. 清华大学核能与新能源技术研究院 北京 100084
  • 收稿日期:2010-10-01 修回日期:2011-03-01 出版日期:2011-07-24 发布日期:2012-03-15
  • 通讯作者: e-mail: jingxia@tsinghua.edu.cn E-mail:jingxia@tsinghua.edu.cn
下载PDF ( 1875 ) 引用
导出 被引次数 ( 16 | 7 )

Overview of 30 Years Research on TRPO Process for Actinides Partitioning from High Level Liquid Waste

Chen Jing*, Wang Jianchen   

  1. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China
  • Received:2010-10-01 Revised:2011-03-01 Online:2011-07-24 Published:2012-03-15

放射性废物,尤其是高放废物的妥善处理处置是各国政府和民众非常重视的一个问题,也是影响核能可持续发展的关键因素之一。高放废液是后处理Purex流程排放出来的废液,它集中了乏燃料中95%以上的放射性,其中α放射性核素的存在决定了需要将其处置在地质处置库中与生物圈隔离10万年以上。“分离-嬗变”方法处理高放废液可以有效缩减地质处置库与生物圈隔离的时限。TRPO具有良好的物性、辐照稳定性和对三价、四价和六价锕系元素良好的萃取选择性。基于此,我国提出了从高放废液中分离锕系元素的TRPO流程。多次热验证实验和中间规模冷台架实验结果证明TRPO流程处理我国生产堆高放废液,可完全实现高放废液的非α化。TRPO流程具有我国自主知识产权,在我国生产堆高放废液和动力堆高放废液处理中都具有良好的应有前景。

关键词： 高放废液, TRPO流程, 锕系元素, 分离

Safe treatment and disposal of radioactive waste, especially high level waste, are attracting much attention from governments of many countries and the public and becoming one of key factors affecting the sustainable development of nuclear energy. High level liquid waste (HLLW) is the raffinate from Purex process and contains more than 95% radioactivity of spent fuel. HLLW must be vitrified and disposed in the geological repository which should be isolated from biosphere for more than 100 000 years because of the α activity. “partitioning-transmutation” method for the treatment of HLLW can effectively reduce the isolation period of geological repository from biosphere. TRPO with good physico-chemical properties and irradiation stability has excellent extraction selectivity to tri-, tetra- and hexa-valent actinides. TRPO process for actinides removal from HLLW has been invented in China. Several times hot tests and the pilot test demonstrated that the HLLW could be conditioned into non-α waste after treatment by TRPO process. TRPO with self-owned intellectual property rights has a bright future in the treatment of defense HLLW and civil HLLW.

Contents
1 Significance of high level liquid waste partitioning
2 Composition of TRPO and its extraction properties
3 Principle TRPO process for actinides partitioning from high level liquid waste
4 Research and development of TRPO process
5 Future of TRPO process

Key words: high level liquid waste, TRPO process, actinides, partitioning

中图分类号: 

()


[1] Croff A C, Blomeke J O. Actinide Partitioning--Transmutation Program, Final Report. ORNL 5566, 1980

[2] Implications of Partitioning and Transmutation in Radioactive Waste Management. IAEA Technical Report Series No. 435, VIENNA, 2004

[3] Zhu Y J. An Extractant (TRPO) for the Removal and Recovery of Actinides from High Level Radioactive Liquid Waste. ISEC83, p9, Denver, Colorado, USA, 1983

[4] 朱永 NFDB2 (Zhu Y J), 焦荣洲(Jiao R Z), 郑华铃(Zheng H L), 王守忠(Wang S Z), 周顺利(Zhou S L), 杨大助(Yang D Z), 樊诗国(Fan S G), 刘秉仁(Liu B R), 陈树铭(Chen S M). 中国发明专利, CN85 1 05352, 1985

[5] 焦荣洲(Jiao R Z), 郑华铃(Zheng H L), 王守忠(Wang S Z), 周顺利(Zhou S L), 刘秉仁(Liu B R), 樊诗国(Fan S G), 陈树铭(Chen S M), 朱永 NFDB2 (Zhu Y J). 核科学与工程 (Chinese Journal of Nuclear Science and Engineering), 1985, 5(2): 147-153

[6] Zhu Y J, Jiao R Z. Nuclear Technology, 1994, 108 (3): 361-369

[7] Zhu Y J, Song C L. Recovery of Neptunium, Plutonium and Americium from Highly Active Waste by Trialkylphosphine Oxide Extraction. Transuranium Element Symposium 1990 (Eds. Morss L R, Fuger J). Washington D C: American Chemical Society, 1992, p318

[8] 梁俊福(Liang J F), 张伟(Zhang W), 焦荣洲(Jiao R Z), 朱永 NFDB2 (Zhu Y J). 核化学与放射化学(Journal of Nuclear and Radiochemistry), 1982, 4(3): 129-137

[9] 焦荣洲(Jiao R Z), 郑华铃(Zheng H L), 王守忠(Wang S Z), 周顺利(Zhou S L), 刘秉仁(Liu B R), 樊诗国(Fan S G), 陈树铭(Chen S M), 朱永 NFDB2 (Zhu Y J). 核化学与放射化学(Journal of Nuclear and Radiochemistry), 1985, 7(2): 65-71

[10] 朱永 NFDB2 (Zhu Y J), 宋崇立(Song C L), 徐景明(Xu J M), 杨大助(Yang D Z), 刘秉仁(Liu B R), 陈建锋(Chen J F).( Chinese Journal of Nuclear Science and Engineering) , 1989, 9(2): 141－150(中文期刊)

[11] 郑华铃(Zheng H L), 焦荣洲(Jiao R Z), 周顺利(Zhou S L), 王守忠(Wang S Z), 陈树铭(Chen S M), 刘秉仁(Liu B R), 樊诗国(Fan S G). 中国核科技报告(China Nuclear Science and Technology Report), CNIC-00124, 北京: 原子能出版社(Beijing: China Nuclear Science and Technology Report), 1987.12

[12] 张平(Zhang P), 梁俊福(Liang J F), 辛仁轩(Xin R X), 宋崇立(Song C L). 原子能科学技术(Atomic Energy Science and Technology), 2003, 37(1): 46-48

[13] 张平(Zhang P), 梁俊福(Liang J F), 辛仁轩(Xin R X), 宋崇立(Song C L). 清华大学学报(自然科学版)(Journal of Tsinghua University (Science and Technology)), 2000, 40(12): 55-58, 66

[14] 张平(Zhang P), 梁俊福(Liang J F), 辛仁轩(Xin R X), 宋崇立(Song C L). 原子能科学技术(Atomic Energy Science and Technology), 2001, 35(4): 337-343

[15] Zhang P, Song C L, Liang J F, Xin R X. Solvent Extraction and Ion Exchange, 2003, 21(1): 91-108

[16] 张平(Zhang P), 宋崇立(Song C L), 梁俊福(Liang J F), 辛仁轩(Xin R X). 原子能科学技术(Atomic Energy Science and Technology), 2003, 37(3): 237-241

[17] 张平(Zhang P), 梁俊福(Liang J F), 辛仁轩(Xin R X), 宋崇立(Song C L). 核科学与工程(Chinese Journal of Nuclear Science and Engineering), 2001, 21(3): 277-281

[18] 张平(Zhang P), 梁俊福(Liang J F), 辛仁轩(Xin R X), 宋崇立(Song C L). 核科学与工程(Chinese Journal of Nuclear Science and Engineering), 2004, 24(4): 335-340

[19] 辛仁轩(Xin R X), 梁俊福(Liang J F), 张 平(Zhang P), 宋崇立(Song C L). 光谱实验室(Chinese Journal of Spectrosopy Laboratory), 1999, 16(6): 638-641

[20] 朱永 NFDB2 (Zhu Y J ). 核化学与放射化学(Journal of Nuclear and Radio Chemistry), 1989, 11(4): 212-221, 254

[21] 朱永 NFDB2 (Zhu Y J). 清华大学学报(自然科学版)(Journal of Tsinghua University (Science and Technology)), 1992, 32(6): 1-12

[22] Glatz J P, Song C L, Koch L, Bokelund H, He X M. Hot Tests of the TRPO Process for the Removal of TRU Elements From HLLW. Proceedings of the Global95 Conference. Versailles, France, 10-14, Sept. 1995, vol. 1, pp. 548-555

[23] 宋崇立(Song C L), Glatz J P, Koch L, 何向明(He X M). 清华大学学报(自然科学版)(Journal of Tsinghua University (Science and Technology)), 1996, 36(6): 102-110

[24] Song C L, Glatz, J P, Koch L, Bocklund H, He X M. A Mathematical Model for the Extraction of Americium from HLW by 30% TRPO and its Experimental Verification. ISEC96, Melbourne, Mar. 19-23, 1996, Vol 2, p1355-1360

[25] 王建晨(Wang J C ), 宋崇立(Song C L), 刘秉仁(Liu B R). 核化学与放射化学(Journal of Nuclear and Radiochemistry), 1995, 17(3): 129-135

[26] Chen J, Wang J C, Song C L. Nuclear Science and Techniques, 1996, 7(3): 129-133

[27] Song C L, Wang J C, Jiao R Z. Hot Test of Total Partitioning Process for the Treatment of High Saline HLLW. in Global99: International Conference on Future Nuclear Systems, Proceedings, August 29-September 3, 1999, Jackson Hole, USA

[28] Wang J C, Song C L. Solvent Extraction and Ion Exchange, 2001, 19(2): 231-242

[29] 韩宾兵(Han B B), 吴秋林(Wu Q L), 曹冬华(Cao D H), 宋崇立(Song C L). 核科学与工程(Journal of Tsinghua University(Science and Technology)), 1997, 17(3): 285-288

[30] 陈靖(Chen J), 吴秋林(Wu Q L), 徐世平(Xu S P), 马荣林(Ma R L), 邰德荣(Tai D R), 宋崇立(Song C L). 清华大学学报(自然科学版)(Journal of Tsinghua University(Science and Technology)), 2000, 40(6): 91-94

[31] 马荣林(Ma R L ), 陈 靖(Chen J), 徐世平(Xu S P), 吴秋林(Wu Q L), 邰德荣(Tai D R), 宋崇立(Song C L). 原子能科学技术(Atomic Energy Science and Technolgy), 2000, 34(1): 54-58

[32] 王悦云(Wang Y Y), 吴秋林(Wu Q L). 核科学与工程(Chinese Journal of Nuclear Science and Engineering), 2003, 23(1): 68-72

[33] Duan W H, Wang J C, Zhou X Z, Chen J. Solvent Extraction and Ion Exchange, 2008, 26(6): 783-796

[34] Chen J, Wang J C, Jing S. A Pilot Test of Partitioning for the Simulated Highly Saline High Level Waste. Proceedings of GLOBAL 2007. Boise, USA, Sep. 9-13, 2007. pp. 1831-1835
[1] 张沐雅, 刘嘉琪, 陈旺, 王利强, 陈杰, 梁毅. 蛋白质凝聚作用在神经退行性疾病中的作用机制研究[J]. 化学进展, 2022, 34(7): 1619-1625.
[2] 尹晓庆, 陈玮豪, 邓博苑, 张佳路, 刘婉琪, 彭开铭. 超润湿膜在乳化液破乳中的应用及作用机制[J]. 化学进展, 2022, 34(3): 580-592.
[3] 闫保有, 李旭飞, 黄维秋, 王鑫雅, 张镇, 朱兵. 氨/醛基金属有机骨架材料合成及其在吸附分离中的应用[J]. 化学进展, 2022, 34(11): 2417-2431.
[4] 吴明明, 林凯歌, 阿依登古丽·木合亚提, 陈诚. 超浸润光热材料的构筑及其多功能应用研究[J]. 化学进展, 2022, 34(10): 2302-2315.
[5] 罗贤升, 邓汉林, 赵江颖, 李志华, 柴春鹏, 黄木华. 多孔氮化石墨烯(C2N)的合成及应用[J]. 化学进展, 2021, 33(3): 355-367.
[6] 王德超, 辛洋洋, 李晓倩, 姚东东, 郑亚萍. 多孔液体在气体捕集与分离领域的应用[J]. 化学进展, 2021, 33(10): 1874-1886.
[7] 李波, 马利建, 罗宁, 李首建, 陈云明, 张劲松. 固相萃取分离铀[J]. 化学进展, 2020, 32(9): 1316-1333.
[8] 黄炎, 刘国东, 张学记. 新型冠状病毒(COVID-19)的检测和诊断[J]. 化学进展, 2020, 32(9): 1241-1251.
[9] 高凤凤, 杨言言, 杜晓, 郝晓刚, 官国清, 汤兵. 电控离子(交换)膜分离技术——从ESIX到ESIPM[J]. 化学进展, 2020, 32(9): 1344-1351.
[10] 徐国华, 成凯, 王晨, 李从刚. 生物凝聚态物质的多层次结构表征[J]. 化学进展, 2020, 32(8): 1231-1239.
[11] 汪润田, 柳春丽, 陈振斌. 印迹复合膜[J]. 化学进展, 2020, 32(7): 989-1002.
[12] 李孝建, 张海军, 李赛赛, 张 俊, 贾全利, 张少伟. 超亲水疏油材料的制备及其油水分离性能[J]. 化学进展, 2020, 32(6): 851-860.
[13] 刘阳, 张新波, 赵樱灿. 二维MoS2纳米材料及其复合物在水处理中的应用[J]. 化学进展, 2020, 32(5): 642-655.
[14] 王贺礼, 朱美华, 梁丽, 吴婷, 张飞, 陈祥树. SSZ-13分子筛膜的制备方法及其气体分离[J]. 化学进展, 2020, 32(4): 423-433.
[15] 刘耀阳, 刘志斌, 赵闯, 周羽, 高杨, 何辉. 锕系元素分离研究:不对称双酰胺荚醚的萃取化学及应用[J]. 化学进展, 2020, 32(2/3): 219-229.