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化学进展 2011, Vol. 23 Issue (6): 1237-1250 前一篇   后一篇

• 综述与评论 •

有机-无机杂化介孔二氧化硅在环境保护中的应用

郭风, 朱桂茹*, 高从堦   

  1. 中国海洋大学化学化工学院海洋化学理论与工程技术教育部重点实验室 青岛266100
  • 收稿日期:2010-09-01 修回日期:2011-01-01 出版日期:2011-06-24 发布日期:2011-05-29
  • 作者简介:e-mail: zhugr@ouc.edu.cn
  • 基金资助:

    国家自然科学基金(No.20803068)资助

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导出 被引次数 ( 25 | 4 )

Organic-Inorganic Hybrid Mesoporous Silicas and Their Applications in Environmental Protection

Guo Feng, Zhu Guiru*, Gao Congjie   

  1. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China
  • Received:2010-09-01 Revised:2011-01-01 Online:2011-06-24 Published:2011-05-29

将有机基团通过后嫁接或共缩聚法引入到介孔二氧化硅的孔道表面或骨架中,根据有机基团在材料中的位置可得到表面结合型和桥键型两类功能化介孔材料。本文总结了有机-无机杂化介孔二氧化硅的分类及合成方法,重点介绍了该类材料作为吸附剂在环境保护中的应用,包括金属阳离子、含氧阴离子、有机污染物和气体的去除与回收。并展望了有机-无机杂化介孔二氧化硅的发展前景。

关键词： 有机-无机杂化介孔二氧化硅, 环境保护, 吸附, 金属阳离子, 含氧阴离子, 有机污染物

Mesoporous organic-inorganic hybrid materials have been obtained through the coupling of inorganic and organic components by template synthesis. The incorporation of functionalities onto material pore surfaces or into the frameworks can be achieved by post-synthesis grafting or co-condensation method. The classification and synthesis methods of hybrid mesoporous silica materials are reviewed. Besides, the applications of hybrid materials in environmental protection are highlighted, including removal and recovery of metal cations, oxyanions, organic pollutants and gases. The outlook of the organic-inorganic hybrid mesoporous silicas is provided.

Key words: organic-inorganic hybrid mesoporous silicas, environmental protection, adsorption, metal cations, oxyanions, organic pollutants

中图分类号: 

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[1] Kresge C T, Leonowicz M E, Roth W J, Vartuli J C, Beck J S. Nature, 1992, 359:710-712
[2] Beck J S, Vartuli J C, Roth W J, Leonowicz M E, Kresge C T, Schmitt K D, Chu C T W, Olson D H, Sheppard E W, McCullen S B, Higgins J B, Schlenker J L. J. Am. Chem. Soc., 1992, 114:10834-10843
[3] Soler-Illia G J A A, Sanchez C, Lebeau B, Patarin J. Chem. Rev., 2002, 102:4093-4138
[4] Jaroniec C P, Kruk M, Jaroniec M, Sayari A. J. Phys. Chem. B., 1998, 102:5503-5510
[5] Lim M H, Stein A. Chem. Mater., 1999, 11: 3285-3295
[6] Burkett S L, Sims S D, Mann S. Chem. Commun., 1996, (11):1367-1368
[7] 刘健(Liu J),杨启华(Yang Q H),张磊(Zhang L), 郭亚军(Guo Y J). 化学进展(Progress in Chemistry), 2005, 17(5):809-817
[8] Inagaki S, Guan S, Fukushima Y, Ohsuna T, Terasaki O. J. Am. Chem. Soc., 1999, 121:9611-9614
[9] Asefa T, MacLachlan M J, Coombs N, Ozin G A. Nature, 1999, 402:867-871
[10] Melde B J, Holland B T, Banford C F, Stein A. Chem. Mater., 1999, 11:3302-3308
[11] Kuroki M, Asefa T, Whitnal W, Kruk M, Yoshina-Ishii C, Jaroniec M, Ozin G A. J. Am. Chem. Soc., 2002, 124:13886-13895
[12] Corriu R J P, Mehdi A, Reyé C, Thieuleux C. Chem. Commun., 2002, (13):1382-1383
[13] Hatton B, Landskron K, Whitnall W, Perovic D, Ozin G A. Acc. Chem. Res., 2005, 38:305-312
[14] Bonifacio L D, Lotsch B V, Ozin G A. Comprehensive Nanoscience and Technology, 2011, 5:69-125
[15] 杨启华(Yang Q H),刘健(Liu J),钟华(Zhong H), 王培远(Wang P Y). 无机材料学报(Journal of Inorganic Materials), 2009, 24(4):641-649
[16] Zhu G, Yang Q, Jiang D, Yang J, Zhang L, Li C. J. Chromatogr. A, 2006, 1103:257-264
[17] Zhu G, Jiang D, Yang Q, Yang J, Li C. J. Chromatogr. A, 2007, 1149:219-227
[18] Feng X, Fryxell G E, Wang L Q, Kim A Y, Liu J, Kemner K M. Science, 1997, 276:923-926
[19] Pérez-Quintanilla D, del Hierro I, Fajardo M, Sierra I. J. Mater. Chem., 2006, 16:1757-1764
[20] Antochshuk V, Olkhovyk O, Jaroniec M, Park I S, Ryoo R. Langmuir, 2003, 19:3031-3034
[21] Pérez-Quintanilla D, Sánchez A, del Hierro I, Fajardo M, Sierra I. J. Colloid Interface Sci., 2007, 313:551-562
[22] Pérez-Quintanilla D, Sánchez A, del Hierro I, Fajardo M, Sierra I. J. Sep. Sci., 2007, 30:1556-1567
[23] Nam K H, Tavlarides L L. Chem. Mater., 2005, 17:1597-1604
[24] Kang T, Park Y, Yi J. Ind. Eng. Chem. Res., 2004, 43:1478-1484
[25] Lam K F, Yeung K L, McKay G. Langmuir, 2006, 22:9632-9641
[26] Xue X, Li F. Micropor. Mesopor. Mat., 2008, 116:116-122
[27] Liu D, Lei J H, Guo L P, Du X D, Zeng K. Micropor. Mesopor. Mat., 2009, 117:67-74
[28] Lam K F, Fong C M, Yeung K L. Gold Bull., 2007, 40:192-198
[29] Yang H, Xu R, Xue X, Li F, Li G. J. Hazard. Mater., 2008, 152:690-698
[30] Aguado J, Arsuaga J M, Arencibia A, Lindo M, Gascón V. J. Hazard. Mater., 2009, 163:213-221
[31] Olkhovyk O, Jaroniec M. J. Am. Chem. Soc., 2005, 127:60-61
[32] Liu J, Yang J, Yang Q, Wang G, Li Y. Adv. Funct. Mater., 2005, 15:1297-1302
[33] Zhang L, Zhang W, Shi J, Hua Z, Li Y, Yan J. Chem. Commun., 2003, (2):210-211
[34] Teng M, Wang H, Li F, Zhang B. J. Colloid Interface Sci., 2010, doi: 10.1016/j.jcis.2010.11.008
[35] Benitez M, Das D, Ferreira R, Pischel U, García H. Chem. Mater., 2006, 18:5597-5603
[36] Lam K F, Yeung K L, McKay G. Micropor. Mesopor. Mat., 2007, 100:191-201
[37] Kang T, Park Y, Choi K, Lee J S, Yi J. J. Mater. Chem., 2004, 14:1043-1049
[38] Mureseanu M, Reiso A, Stefanescu I, David E, Parvulescu V, Renard G, Hulea V. Chemosphere., 2008, 73:1499-1504
[39] Jamali M R, Assadi Y, Shemirani F, Hosseini M R M, Kozani R R, Masteri-Farahani M, Salavati-Niasari M. Anal. Chim. Acta, 2006, 579:68-73
[40] Olkhovyk O, Jaroniec M. Ind. Eng. Chem. Res., 2007, 46:1745-1751
[41] Lin Y, Fiskum S K, Yantasee W, Wu H, Mattigod S V, Vorpagel E, Fryxell G E, Raymond K N, Xu J. Environ. Sci. Technol., 2005, 39:1332-1337
[42] Yoshitake H, Koiso E, Horie H, Yoshimura H. Micropor. Mesopor. Mat., 2005, 85:183-194
[43] Alothman Z A, Apblett A W. J. Hazard. Mater., 2010, 182:581-590
[44] Jamali M R, Assadi Y, Shemirani F, Salavati-Niasari M. Talanta., 2007, 71:1524-1529
[45] Corriu R J P, Mehdi A, Reyé C, Thieuleux C. Chem. Mater., 2004, 16:159-166
[46] Silva L C C, Santos L B O, Abate G, Cosentino I C, Fantini M C A, Masini J C, Matos J R. Micropor. Mesopor. Mat., 2008, 110:250-259
[47] Mureseanu M, Reiss A, Cioatera N, Trandafir I, Hulea V. J. Hazard. Mater., 2010, 182:197-203
[48] Chandra D, Das S K, Bhaumik A. Micropor. Mesopor. Mat., 2010, 128:34-40
[49] Huang X, Wang Y, Liao X, Shi B. J. Hazard. Mater., 2010, 183:793-798
[50] Huang X, Liao X, Shi B. J. Hazard. Mater., 2010, 173:33-39
[51] Jeong E Y, Ansari M B, Mo Y H, Park S E. J. Hazard. Mater., 2010, doi: 10.1016/j.jhazmat.2010.10.047
[52] Sangvanich T, Sukwarotwat V, Wiacek R J, Grudzien R M, Fryxell G E, Addleman R S, Timchalk C, Yantasee W. J. Hazard. Mater., 2010, 182:225-231
[53] Etienne M, Goubert-Renaudin S, Rousselin Y, Marichal C, Denat F, Lebeau B, Walcarius A. Langmuir, 2009, 25:3137-3145
[54] Lam K F, Chen X, McKay G, Yeung K L. Ind. Eng. Chem. Res., 2008, 47:9376-9383
[55] Vasiliev A N, Golovko L V, Trachevsky V V, Hall G S, Khinast J G. Micropor. Mesopor. Mat., 2009, 118:251-257
[56] Shevchenko N, Zaitsev V, Walcarius A. Environ. Sci. Technol., 2008, 42:6922-6928
[57] Lam K F, Yeung K L, McKay G. Environ. Sci. Technol., 2007, 41:3329-3334
[58] Fan Z. Talanta, 2006, 70:1164-1169
[59] Liu Y, Liu Z, Gao J, Dai J, Wang Y, Xie J, Yan Y. J. Hazard. Mater., 2010, doi: 10.1016/j. jhazmat. 2010.10.105
[60] Jayasundera S, Burleigh M C, Zeinali M, Spector M S, Miller J B, Yan W, Dai S, Markowitz M A. J. Phys. Chem. B., 2005, 109:9198-9201
[61] Billinge S J L, McKimmy E J, Shatnawi M, Kim H J, Petkov V, Wermeille D, Pinnavaia T J. J. Am. Chem. Soc., 2005, 127:8492-8498
[62] Fryxell G E, Liu J, Hauser T A, Nie Z, Ferris K F, Mattigod S, Gong M, Hallen R T. Chem. Mater., 1999, 11:2148-2154
[63] Yoshitake H, Yokoi T, Tatsumi T. Chem. Mater., 2003, 15:1713-1721
[64] Yokoi T, Tatsumi T, Yoshitake H. J. Colloid Interface Sci., 2004, 274:451-457
[65] Tarafdar A, Pramanik P. Micropor. Mesopor. Mat., 2006, 91:221-224
[66] Chen D, Huang C, He M, Hu B. J. Hazard. Mater., 2009, 164:1146-1151
[67] Yoshitake H, Yokoi T, Tatsumi T. Chem. Mater., 2002, 14:4603-4610
[68] Li J, Wang L, Qi T, Zhou Y, Liu C, Chu J, Zhang Y. Micropor. Mesopor. Mat., 2008, 110:442-450
[69] Wang L, Qi T, Zhang Y. Colloids Surfaces A., 2006, 275:73-78
[70] Fried D I, Schlossbauer A, Bein T. Micropor. Mesopor. Mat., 2010, doi: 10.1016/j. micromeso. 2010.08.006
[71] Wu Z, Joo H, Ahna I S, Haama S, Kima J H, Lee K. Chem. Eng. J., 2004, 102:277-282
[72] Wang G, Otuonye A N, Blair E A, Denton K, Tao Z, Asefa T. J. Solid. State. Chem., 2009, 182: 1649-1660
[73] Guan M, Liu W, Shao Y, Huang H, Zhang H. Micropor. Mesopor. Mat., 2009, 123:193-201
[74] Asouhidou D D, Triantafyllidis K S, Lazaridis N K, Matis K A. Colloids Surfaces A, 2009, 346:83-90
[75] Inumaru K, Kiyoto J, Yamanaka S. Chem. Commun., 2000, (11):903-904
[76] Baccile N, Babonneau F. Micropor. Mesopor. Mat., 2008, 110:534-542
[77] Suzuki T M, Mizutani M, Nakamura T, Akimoto Y, Yano K. Micropor. Mesopor. Mat., 2008, 116:284-291
[78] Anbia M, Lashgari M. Chem. Eng. J., 2009, 150:555-560
[79] Yang H, Feng Q. J. Hazard. Mater., 2010, 180:106-114
[80] Wang J, Zheng S, Liu J, Xu Z. Chem. Eng. J., 2010, 165:10-16
[81] Kim Y H, Lee B, Choo K H, Choi S J. Micropor. Mesopor. Mat., 2011, 138:184-190
[82] Sayari A, Hamoudi S, Yang Y. Chem. Mater., 2005, 17:212-216
[83] Burleigh M C, Markowitz M A, Spector M S, Gaber B P. Environ. Sci. Technol., 2002, 36:2515-2518
[84] Joo J B, Park J, Yi J. J. Hazard. Mater., 2009, 168:102-107
[85] Mohamed M M. J. Colloid Interface Sci., 2004, 272:28-34
[86] Fu X, Chen X, Wang J, Liu J. Micropor. Mesopor. Mat., 2010, doi: 10.1016/j. micromeso. 2010.10.004
[87] Huang H, Zhao C, Ji Y, Nie R, Zhou P, Zhang H. J. Hazard. Mater., 2010, 178:680-685
[88] Burleigh M C, Jayasundera S, Spector M S, Thomas C W, Markowitz M A, Gaber B P. Chem. Mater., 2004, 16:3-5
[89] Rivera-Jiménez S M, Méndez-González S, Hernández- Maldonado A. Micropor. Mesopor. Mat., 2010, 132:470-479
[90] Murakami K, Yu X, Watanabe S, Kato T, Inoue Y, Sugawara K. J. Colloid Interf. Sci., 2010, doi: 10.1016/j. jcis. 2010.10.040
[91] Huang H Y, Yang R T, Chinn D, Munson C L. Ind. Eng. Chem. Res., 2003, 42:2427-2433
[92] Kim S, Ida J, Guliants V V, Lin J Y S. J. Phys. Chem. B., 2005, 109:6287-6293
[93] Hiyoshi N, Yogo K, Yashima T. Micropor. Mesopor. Mat., 2005, 84:357-365
[94] Chang F Y, Chao K J, Cheng H H, Tan C S. Sep. Purif. Technol., 2009, 70:87-95
[95] Knowles G P, Graham J V, Delaney S W, Chaffee A L. Fuel. Process. Technol., 2005, 86:1435-1448
[96] Harlick P J E, Sayari A. Ind. Eng. Chem. Res., 2007, 46:446-458
[97] Knowles G P, Delaney S W, Chaffee A L. Ind. Eng. Chem. Res., 2006, 45:2626-2633
[98] Bhagiyalakshmi M, Anuradha R, Park S D, Jang H T. Micropor. Mesopor. Mat., 2010, 131:265-273
[99] Wei J, Shi J, Pan H, Zhao W, Ye Q, Shi Y. Micropor. Mesopor. Mat., 2008, 116:394-399
[100] Franchi R S, Harlick P J E, Sayari A. Ind. Eng. Chem. Res., 2005, 44:8007-8013
[101] Chen C, Son W J, You K S, Ahn J W, Ahn W S. Chem. Eng. J., 2010, 161:46-52
[102] Xu X, Song C, Andresen J M, Miller B G, Scaroni A W. Energy. Fuels, 2002, 16:1463-1469
[103] Yue M B, Chun Y, Cao Y, Dong X, Zhu J H. Adv. Funct. Mater., 2006, 16:1717-1722
[104] Lin L Y, Bai H. Micropor. Mesopor. Mat., 2010, 136:25-32
[105] Wei J, Liao L, Xiao Y, Zhang P, Shi Y. J. Environ. Sci., 2010, 22:1558-1563
[106] Leal O, Bolivar C, Ovalles C, Garcia J J, Espidel Y. Inorg. Chim. Acta, 1995, 240:183-189
[107] Zeleňák V, Badani ová M, Halamová D, ejka J, Zukal A, Murafa N, Goerigk G. Chem. Eng. J., 2008, 144:336-342
[108] Serna-Guerrero R, Belmabkhout Y, Sayari A. Chem. Eng. J., 2010, 161:173-181
[109] Serna-Guerrero R, Sayari A. Chem. Eng. J., 2010, 161:182-190
[110] Liang Z, Fadhel B, Schneider C J, Chaffee A L. Micropor. Mesopor. Mat., 2008, 111:536-543
[111] Hicks J C, Drese J H, Fauth D J, Gray M L, Qi G, Jones C W. J. Am. Chem. Soc., 2008, 130:2902-2903
[112] Fadhel B, Heam M, Chaffee A. Micropor. Mesopor. Mat., 2009, 123:140-149
[113] Bhagiyalakshmi M, Park S D, Cha W S, Jang H T. Appl. Surf. Sci., 2010, 256:6660-6666
[114] Bhagiyalakshmi M, Yun L J, Anuradha R, Jang H T. J. Hazard. Mater., 2010, 175:928-938
[115] Hu Q, Li J J, Hao Z P, Li L D, Qiao S Z. Chem. Eng. J., 2009, 149:281-288
[116] Zhao X S, Lu G Q. J. Phys. Chem. B., 1998, 102:1556-1561
[117] Patel D B, Singh S, Bandyopadhyaya R. Micropor. Mesopor. Mat., 2011, 137:49-55
[118] Srisuda S, Virote B. J. Environ. Sci. (China), 2008, 20:379-384
[119] 孙鹤(Sun H),石方(Shi F). 环境科学学报(Acta Scientiae Circumstantiae), 2000, 20(1):38-41
[120] Yang J Y, Yang J, Zhou Y, Lin W G, Wang H J, Zhu J H. J. Hazard. Mater., 2010, 176:602-608
[121] Jung J H, Han W S, Rim J A, Lee S J, Cho S J, Kim S Y, Kang J K, Shinkai S. Chem. Lett., 2006, 35:32-33
[122] Khatri R A, Chuang S S C, Soong Y, Gray M. Energy Fuels, 2006, 20: 1514-1520
[123] Yeoh F Y, Matsumoto A, Iwase Y, Baba T. Catal. Today, 2008, 132: 46-51
[124] Hudson M J, Knowles J P, Harris P J F, Jackson D B, Chinn M J, Ward J L. Micropor. Mesopor. Mat., 2004, 75:121-128
[125] Hoang T K A, Hamaed A, Trudeau M, Antonelli D M. J. Phys. Chem. C., 2009, 113:17240-17246
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