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化学进展 2011, Vol. 23 Issue (6): 1174-1180 前一篇   后一篇

• 综述与评论 •

聚烯烃/聚酯(聚醚)共聚物的合成及其应用

李启蒸1,2, 张国艺2, 袁聪1,2, 魏柳荷1*, 马志2*   

  1. 1. 郑州大学化学系 郑州 450001;
    2. 中国科学院上海有机化学研究所 上海 200032
  • 收稿日期:2010-09-01 修回日期:2010-11-01 出版日期:2011-06-24 发布日期:2011-05-29
  • 作者简介:e-mail: mazhi728@mail.sioc.ac.cn; weiliuhe@zzu.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.20604032,21074146)资助

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Synthesis and Application of Polyolefin/Polyester (Polyether) Copolymers

Li Qizheng1,2, Zhang Guoyi2, Yuan Cong1,2, Wei Liuhe1*, Ma Zhi2*   

  1. 1. Department of Chemistry, Zhengzhou University, Zhengzhou 45000;
    2. Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
  • Received:2010-09-01 Revised:2010-11-01 Online:2011-06-24 Published:2011-05-29

本文首先详细评述了聚烯烃/聚酯(聚醚)共聚物的合成方法: 聚合机理转换法和聚合物偶联法。其中,聚合机理转换法又分为: (1) 链转移剂控制烯烃聚合/阴离子开环聚合; (2) 链转移剂控制烯烃聚合/配位-插入开环聚合; (3) 烯烃阴离子活性聚合/阴离子开环聚合; (4) 烯烃阴离子活性聚合/配位-插入开环聚合; (5) 叶立德活性聚合/配位-插入开环聚合等5种方法。其次,对聚烯烃/聚酯(聚醚)共聚物的性能及其应用进行了介绍; 最后,对这些功能化聚烯烃共聚物的合成方法及其应用前景进行了展望。

关键词： 聚烯烃功能化, 聚酯, 聚醚, 开环聚合, 共聚物

Firstly, two synthetic methods of polyolefin/polyester (polyether)copolymers, transformation of polymerization mechanism and polymer coupling, are reviewed. The first one can be divided into five methodologies: (1) the chain transfer reaction in the polyolefin polymerization/anionic ring-opening polymerization; (2) the chain transfer reaction in the polyolefin polymerization/coordination-insertion ring-opening polymerization; (3) the living anionic polymerization/ anionic ring-opening polymerization; (4) the anion living polymerization/anionic ring-opening polymerization; (5) the living polymerization of ylides/coordination-insertion ring-opening polymerization. Then, the application of such polyolefin/polyester (polyether) copolymers is described. Finally, the prospect of the synthesis and application of the functional polyolefin is also foreseen.

Key words: functionalization of polyolefin, polyester, polyether, ring-opening polymerization, copolymer

中图分类号: 

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