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化学进展 2011, Vol. 23 Issue (6): 1123-1136 前一篇   后一篇

• 综述与评论 •

卟啉-富勒烯络合物的合成

杨绳岩1,2*, 吴振奕2, 万新军1, 晏娟1   

  1. 1. 巢湖学院化学与材料科学系 巢湖 238000;
    2. 厦门大学化学系 厦门 361005
  • 收稿日期:2010-10-01 修回日期:2010-12-01 出版日期:2011-06-24 发布日期:2011-05-29
  • 作者简介:e-mail:yangshengyan19822005@126.com
  • 基金资助:

    巢湖学院院级项目(No.XLY-201009)资助

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Synthesis of Porphyrin-Fullerene Complexes

Yang Shengyan1,2*, Wu Zhenyi2, Wan Xinjun1, Yan Juan1   

  1. 1. Department of Chemistry and Material Science, Chaohu College, Chaohu 238000, China;
    2. Department of Chemistry, Xiamen University, Xiamen 361005, China
  • Received:2010-10-01 Revised:2010-12-01 Online:2011-06-24 Published:2011-05-29

按照卟啉与富勒烯连接方式的不同,卟啉-富勒烯化合物可分为共价键连接和非共价键连接两种类型。共价键连接的卟啉-富勒烯化合物主要是通过环加成反应来合成,如1,3-偶极环加成反应、Diels-Alder环加成反应和Bingel-Hirsch环加成反应;非共价键连接的卟啉-富勒烯化合物主要是通过金属的轴向配位及氢键得到。本文综述了近年来不同类型的卟啉-富勒烯化合物的合成研究,着重介绍了共价键连接卟啉-富勒烯化合物的合成及应用前景,分析目前在合成方法上存在的问题,并对未来的研究提出了展望。

关键词： 卟啉, 富勒烯, 合成, 环加成反应

Fullerenes have been found to make good acceptors, due to their unique three-dimensional structure and remarkably withdrawing electron. Porphyrins are frequently used as ideal donors for their π conjugate structure and plentiful π electron . Also, they are good photosensitizers, and having widely absorbability in UV-Vis region. Porphyrin-fullerene complexes become currently active fields as the property of mimics of the natural photosynthetic recation centers and photoinduced electron transfer. This material is hopeful to be applied in photovoltaic cells and solar cells. In accordance with the different ways to connect porphyrin and fullerene, porphyrin-fullerene complexes can be divided into two types: covalently linked and non-covalently linked. Covalently linked porphyrin-fullerene complexes are synthesized mainly through cycloaddition reactions, such as the 1,3-dipolar cycloaddition reaction, Diels-Alder cycloaddition reaction and Bingel-Hirsch cycloaddition reaction. Non-covalently linked porphyrin-fullerene complexes are obtained maily through the axial coordination of metal and the hydrogen bonding. This review covers the recent progress in synthesis of different types of porphyrin-fullerene complexes, including the synthesis and application prospects of covalently linked porphyrin-fullerene compounds, existing problems in synthetic methods and further prospects in this field.

Key words: porphyrin, fullerene, synthesis, cycloaddition reaction

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摘要

卟啉-富勒烯络合物的合成