English
往期目录
新闻公告
More
化学进展 2011, Vol. 23 Issue (6): 1090-1099 前一篇   后一篇

• 综述与评论 •

水热法制备LiFePO4正极材料

苏晓飞1, 张校刚1,2*   

  1. 1. 新疆大学 应用化学研究所 化学与化工学院 乌鲁木齐 830046;
    2. 南京航空航天大学材料科学与技术学院 南京 210016
  • 收稿日期:2010-10-01 修回日期:2011-01-01 出版日期:2011-06-24 发布日期:2011-05-29
  • 作者简介:e-mail:azhangxg@163.com
下载PDF ( 1650 ) 引用
导出

Hydrothermal Synthesis of LiFePO4 Cathode

Su Xiaofei1, Zhang Xiaogang1,2*   

  1. 1. Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, China;
    2. College of Materials Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
  • Received:2010-10-01 Revised:2011-01-01 Online:2011-06-24 Published:2011-05-29

本文以制备LiFePO4正极材料存在的问题为主线,从提高产物纯度、控制样品形貌和提高材料性能三方面综述了目前水热合成LiFePO4的研究进展,同时也从节省原料、降低成本及产业化方面对水热合成LiFePO4进行了展望。本文虽以水热制备LiFePO4为主线,但在相关章节也涵盖了对溶剂热、超临界、多元醇和离子热等相关低温合成方法的总结。最后,比较了水热法制备LiFePO4与其他合成方法的优势和劣势,重点讨论了产业化所存在的问题,以及可能的解决措施。

关键词： 锂离子电池, 正极材料, 磷酸铁锂, 水热合成

Hydrothermal synthesis of LiFePO4 cathode is reviewed on the basis of problems hampering the application of LiFePO4, which involves purity, morphology and conductivity. The cost of raw materials and synthetic route are considerd, and a possible way in mass production of LiFePO4 is proposed. Although the article focuses on hydrothermal synthesis of LiFePO4, but other low-temperature synthesis processes, including solvothermal, supercritical, polyol and ionothermal, are also discussed in the related sections. Finally, advantages and disadvantages of hydrothermal synthesis of LiFePO4 cathode are compared with other synthesis processes, with the focuses on the difficulty in mass production of LiFePO4, and the means to solve the problem is presented.

Key words: Li-batteries, cathodes, LiFePO4, hydrothermal synthesis

中图分类号: 

()

[1] Whittingham M S. MRS Bulletin, 2008, 33: 411-419
[2] Tarascon J M. Philosophical Transactions of the Royal Society a-Mathematical Physical and Engineering Sciences, 2010, 368: 3227-3241
[3] Wang Y, Cao G Z. Advanced Materials, 2008, 20: 2251-2269
[4] Padhi A K, Nanjundaswamy K S, Goodenough J B. Journal of the Electrochemical Society, 1997, 144: 1188-1194
[5] Ellis B L, Lee K T, Nazar L F. Chemistry of Materials, 2010, 22: 691-714
[6] Yang S, Zhou X, Zhang J, Liu Z. Journal of Materials Chemistry, 2010, 20: 8086-8091
[7] Sun C S, Zhou Z, Xu Z G, Wang D G, Wei J P, Bian X K, Yan J. Journal of Power Sources, 2009, 193: 841-845
[8] Shenouda A Y, Liu H K. Journal of Alloys and Compounds, 2009, 477: 498-503
[9] Ou X Q, Liang G C, Wang L, Xu S Z, Zhao X. Journal of Power Sources, 2008, 184: 543-547
[10] Zhi X K, Liang G C, Wang L, Ou X Q, Zhang J P, Cui J Y. Journal of Power Sources, 2009, 189: 779-782
[11] Gao X G, Hu G R, Peng Z D, Du K. Electrochimica Acta, 2009, 54: 4777-4782
[12] Gibot P, Casas-Cabanas M, Laffont L, Levasseur S, Carlach P, Hamelet S, Tarascon J M, Masquelier C. Nature Materials, 2008, 7: 741-747
[13] Wang G X, Liu H, Liu J A, Qiao S Z, Lu G Q M, Munroe P, Ahn H. Advanced Materials, 2010, 22(44): 4944-4948
[14] Morales J, Trocoli R, Rodriguez-Castellon E, Franger S, Santos-Pena J. Journal of Electroanalytical Chemistry, 2009, 631: 29-35
[15] Ding Y, Jiang Y, Xu F, Yin J, Ren H, Zhuo Q, Long Z, Zhang P. Electrochemistry Communications, 2010, 12: 10-13
[16] Yang Y, Liao X Z, Ma Z F, Wang B F, He L, He Y S. Electrochemistry Communications, 2009, 11: 1277-1280
[17] Wang K, Cai R, Yuan T, Yu X, Ran R, Shao Z P. Electrochimica Acta, 2009, 54: 2861-2868
[18] Wu X L, Jiang L Y, Cao F F, Guo Y G, Wan L J. Advanced Materials, 2009, 21: 2710-2714
[19] Wang Y, Hosono E, Wang K, Zhou H. Angewandte Chemie, 2008, 120: 7571-7575
[20] Winter M, Brodd R J. Chemical Reviews, 2004, 104: 4245-4270
[21] Li H, Wang Z X, Chen L Q, Huang X J. Advanced Materials, 2009, 21: 4593-4607
[22] Bruce P, Scrosati B, Tarascon J M. Angewandte Chemie International Edition, 2008, 47: 2930-2946
[23] Jugovic D, Uskokovic D. Journal of Power Sources, 2009, 190: 538-544
[24] 惠乐(Hui L), 唐子龙(Tang Z L), 罗绍华(Luo S H), 张中太(Zhang Z T). 化学进展(Progress in Chemistry), 2007, 19(10): 1460-1466
[25] 施尔畏(Shi E W), 陈之战(Chen Z Z), 元如林(Yuan R L), 郑燕青(Zheng Y Q). 水热结晶学. 北京: 科学出版社(Beijing: Science Press), 2004.150-151
[26] Yang S F, Zavalij P Y, Whittingham M S. Electrochemistry Communications, 2001, 3: 505-508
[27] Chen J J, Whittingham M S. Electrochemistry Communications, 2006, 8: 855-858
[28] Dokko K, Koizumi S, Nakano H, Kanamura K. Journal of Materials Chemistry, 2007, 17: 4803-4810
[29] Saravanan K, Balaya P, Reddy M V, Chowdari B V R, Vittal J J. Energy & Environmental Science, 2010, 3: 457-464
[30] Yang H, Wu X L, Cao M H, Guo Y G. Journal of Physical Chemistry C, 2009, 113: 3345-3351
[31] Murugan A V, Muraliganth T, Manthiram A. Electrochemistry Communications, 2008, 10: 903-906
[32] Rangappa D, Sone K, Kudo T, Honma I. Journal of Power Sources, 2010, 195: 6167-6171
[33] Rangappa D, Sone K, Ichihara M, Kudo T, Honma I. Chemical Communications, 2010, 46(40): 7548-7550
[34] Zhang C H, Huang X, Yin Y S, Dai J H, Zhu Z B. Ceramics International, 2009, 35: 2979-2982
[35] Bilecka I, Hintennach A, Djerdj I, Novak P, Niederberger M. Journal of Materials Chemistry, 2009, 19: 5125-5128
[36] Li L, Tang X, Liu H, Qu Y, Lu Z. Electrochimica Acta, 2010, 56: 995-999
[37] 庄大高(Zhuang D G), 赵新兵(Zhao X B), 曹高劭(Cao G S), 米常焕(Mi C H), 涂健(Tu J), 涂江平(Tu J P). 中国有色金属学报(The Chinese Journal of Nonferrous Metals), 2005, 15(12): 2034-2039
[38] Lee M H, Kim J Y, Song H K. Chemical Communications, 2010, 46: 6795-6797
[39] Dokko K, Shiraishi K, Kanamuraa K. Journal of the Electrochemical Society, 2005, 152: A2199-A2202
[40] Ellis B, Kan W H, Makahnouk W R M, Nazar L F. Journal of Materials Chemistry, 2007, 17: 3248-3254
[41] Ni J F, Morishita M, Kawabe Y, Watada M, Takeichi N, Sakai T. Journal of Power Sources, 2010, 195: 2877-2882
[42] Tarascon J M, Recham N, Armand M, Chotard J N, Barpanda P, Walker W, Dupont L. Chemistry of Materials, 2010, 22: 724-739
[43] Meligrana G, Gerbaldi C, Tuel A, Bodoardo S, Penazzi N. Journal of Power Sources, 2006, 160: 516-522
[44] Tajimi S, Ikeda Y, Uematsu K, Toda K, Sato M. Solid State Ionics, 2004, 175: 287-290
[45] Chen J, Wang S, Whittingham M S. Journal of Power Sources, 2007, 174: 442-448
[46] Huang X J, Yan S J, Zhao H Y, Zhang L, Guo R, Chang C K, Kong X Y, Han H B. Materials Characterization, 2010, 61: 720-725
[47] Kuwahara A, Suzuki S, Miyayama M. Journal of Electroceramics, 2010, 24: 69-75
[48] Liang G C, Wang L, Ou X Q, Zhao X, Xu S Z. Journal of Power Sources, 2008, 184: 538-542
[49] Jin B, Jin E M, Park K H, Gu H B. Electrochemistry Communications, 2008, 10: 1537-1540
[50] Jin E M, Jin B, Jun D K, Park K H, Gu H B, Kim K W. Journal of Power Sources, 2008, 178: 801-806
[51] Muraliganth T, Murugan A V, Manthiram A. Journal of Materials Chemistry, 2008, 18: 5661-5668
[52] Recham N, Armand M, Laffont L, Tarascon J M. Electrochemical and Solid State Letters, 2009, 12: A39-A44
[53] Qian J F, Zhou M, Cao Y L, Ai X P, Yang H X. Journal of Physical Chemistry C, 2010, 114: 3477-3482
[54] Delacourt C, Poizot P, Levasseur S, Masquelier C. Electrochemical and Solid State Letters, 2006, 9: A352-A355
[55] Kim D H, Kim J. Electrochemical and Solid-State Letters, 2006, 9: A439-A442
[56] Kim D H, Kim J S, Kang J W, Kim E J, Ahn H Y, Kim J. Journal of Nanoscience and Nanotechnology, 2007, 7: 3949-3953
[57] Kim T R, Kim D H, Ryu H W, Moon J H, Lee J H, Boo S, Kim J. Journal of Physics and Chemistry of Solids, 68: 1203-1206
[58] Martha S K, Markovsky B, Grinblat J, Gofer Y, Haik O, Zinigrad E, Aurbach D, Drezen T, Wang D, Deghenghi G, Exnar I. Journal of the Electrochemical Society, 2009, 156: A541-A552
[59] Wang D, Buqa H, Crouzet M, Deghenghi G, Drezen T, Exnar I, Kwon N H, Miners J H, Poletto L, Grtzel M. Journal of Power Sources, 2009, 189: 624-628
[60] Song H K, Lee K T, Kim M G, Nazar L F, Cho J. Advanced Functional Materials, 2010, 20(22): 3818-３８３４
[61] Murugan A V, Muraliganth T, Manthiram A. Journal of Physical Chemistry C, 2008, 112: 14665-14671
[62] Murugan A V, Muraliganth T, Manthiram A. Journal of the Electrochemical Society, 2009, 156: A79-A83
[63] Recham N, Dupont L, Courty M, Djellab K, Larcher D, Armand M, Tarascon J M. Chemistry of Materials, 2009, 21: 1096-1107
[64] Nytén A, Abouimrane A, Armand M, Gustafsson T, Thomas J O. Electrochemistry Communications, 2005, 7: 156-160
[65] Recham N, Chotard J N, Jumas J C, Laffont L, Armand M, Tarascon J M. Chemistry of Materials, 2009, 22: 1142-1148
[66] Recham N, Chotard J N, Dupont L, Delacourt C, Walker W, Armand M, Tarascon J M. Nat. Mater., 2010, 9: 68-74
[67] Ellis B L, Makahnouk W R M, Makimura Y, Toghill K, Nazar L F. Nat. Mater., 2007, 6: 749-753
[68] Ati M, Dupont L, Recham N, Chotard J N, Walker W T, Davoisne C, Barpanda P, Sarou-Kanian V, Armand M, Tarascon J M. Chemistry of Materials, 2010, 22: 4062-4068
[69] Aimable A, Aymes D, Bernard F, Le Cras F. Solid State Ionics, 2009, 180: 861-866
[70] Xu C B, Lee J, Teja A S. Journal of Supercritical Fluids, 2008, 44: 92-97
[71] Yuan L X, Wang Z H, Zhang W X, Hu X L, Chen J T, Huang Y H, Goodenough J B. Energy & Environmental Science, 2011, 4(2): 269-284
[1] 朱国辉, 还红先, 于大伟, 郭学益, 田庆华. 废旧锂离子电池选择性提锂[J]. 化学进展, 2023, 35(2): 287-301.
[2] 李芳远, 李俊豪, 吴钰洁, 石凯祥, 刘全兵, 彭翃杰. “蛋黄蛋壳”结构纳米电极材料设计及在锂/钠离子/锂硫电池中的应用[J]. 化学进展, 2022, 34(6): 1369-1383.
[3] 李婧婧, 李洪基, 黄强, 陈哲. 掺杂对钠离子电池正极材料性能影响机制的研究[J]. 化学进展, 2022, 34(4): 857-869.
[4] 冯小琼, 马云龙, 宁红, 张世英, 安长胜, 李劲风. 铝离子电池中过渡金属硫族化合物正极材料[J]. 化学进展, 2022, 34(2): 319-327.
[5] 王才威, 杨东杰, 邱学青, 张文礼. 木质素多孔碳材料在电化学储能中的应用[J]. 化学进展, 2022, 34(2): 285-300.
[6] 陈阳, 崔晓莉. 锂离子电池二氧化钛负极材料[J]. 化学进展, 2021, 33(8): 1249-1269.
[7] 陆嘉晟, 陈嘉苗, 何天贤, 赵经纬, 刘军, 霍延平. 锂电池用无机固态电解质[J]. 化学进展, 2021, 33(8): 1344-1361.
[8] 高金伙, 阮佳锋, 庞越鹏, 孙皓, 杨俊和, 郑时有. 高电压锂离子正极材料LiNi0.5Mn1.5O4高温特性[J]. 化学进展, 2021, 33(8): 1390-1403.
[9] 蔡克迪, 严爽, 徐天野, 郎笑石, 王振华. 锂离子电容电池关键电极材料[J]. 化学进展, 2021, 33(8): 1404-1413.
[10] 黄国勇, 董曦, 杜建委, 孙晓华, 李勃天, 叶海木. 锂离子电池高压电解液[J]. 化学进展, 2021, 33(5): 855-867.
[11] 周世昊, 吴贤文, 向延鸿, 朱岭, 刘志雄, 赵才贤. 水系锌离子电池锰基正极材料[J]. 化学进展, 2021, 33(4): 649-669.
[12] 张长欢, 李念武, 张秀芹. 柔性锂离子电池的电极[J]. 化学进展, 2021, 33(4): 633-648.
[13] 穆德颖, 刘铸, 金珊, 刘元龙, 田爽, 戴长松. 废旧锂离子电池正极材料及电解液的全过程回收及再利用[J]. 化学进展, 2020, 32(7): 950-965.
[14] 庄全超, 杨梓, 张蕾, 崔艳华. 锂离子电池的电化学阻抗谱分析研究进展[J]. 化学进展, 2020, 32(6): 761-791.
[15] 吴战, 李笑涵, 钱奥炜, 杨家喻, 张文魁, 张俊. 基于无机电致变色材料的变色储能器件[J]. 化学进展, 2020, 32(6): 792-802.
阅读次数
全文


摘要

水热法制备LiFePO4正极材料