English
往期目录
新闻公告
More
化学进展 2011, Vol. 23 Issue (5): 1014-1021 前一篇   后一篇

• 综述与评论 •

卟啉类光敏剂在染料敏化太阳能电池中的应用

李孜, 贾春阳, 万中全   

  1. 电子科技大学 电子薄膜与集成器件国家重点实验室 微电子与固体电子学院 成都 610054
  • 收稿日期:2010-08-01 修回日期:2010-11-01 出版日期:2011-05-24 发布日期:2011-05-04
  • 基金资助:

    国家自然科学基金项目(No.20602005, 20873015)和四川省科技厅科技支撑项目(No.2009FZ0230)资助

下载PDF ( 1746 ) 引用
导出 被引次数 ( 75 | 4 )

Applications of Porphyrin Derivatives as Dyes for DSSC

Li Zi, Jia Chunyang, Wan Zhongquan   

  1. State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Microelectronics and Solid-State Electronics, University of Electronic Science and Technology of China, Chengdu 610054, China
  • Received:2010-08-01 Revised:2010-11-01 Online:2011-05-24 Published:2011-05-04

染料是染料敏化太阳能电池的核心之一,它的性质直接影响着电池的光电转换效率。多吡啶钌类配合物是目前最有效的染料,但存在合成困难、需要贵金属钌且对环境有一定的污染等缺点,因此近年来纯有机及含廉价金属染料的研究逐渐受到重视。卟啉类染料具有易合成、易修饰及在可见光区有强吸收等特性,这些特性使它在非钌染料的研究中受到青睐。本文从染料结构中的电子给体、电子受体、电子传输通道三方面出发,综述了近几年来关于卟啉类染料的最新研究成果,希望能为研究者设计、合成更优秀的卟啉类染料提供一定的参考。

关键词： 染料敏化太阳能电池, 卟啉, 电子给体, 电子受体, 电子传输通道

Dye is one of important factor for dye-sensitized solar cell (DSSC). Due to the synthetic challenge and precious metals needed for multipyridine ruthenium complex dyes, more and more research focus on the pure organic dyes. Porphyrin derivatives as pure organic dyes attract increasing interests because they have lots of merits, such as short synthetic route, easy modification and strong absorption in visible region. In this paper, with analyzing the influences of electron donor, electron transfer channel and electron acceptor, some important results in recent years for porphyrin derivatives as dyes are reviewed.

Key words: DSSC, porphyrin, electron donor, electron acceptor, electron transmission channel

中图分类号: 

()

[1] Brian O, Gratzel M. Nature, 1991, 353(6346): 737-740
[2] Grtzel M. J. Photochem. Photobiol. A, 2004, 164: 3-14
[3] Grtzel M. Acc. Chem. Res., 2009, 42(11): 1788-1798
[4] Chiba Y, Islam A, Watanabe Y, Komiya R, Koide N, Han L. Jpn. J. Appl. Phys., 2006, 45: 638-640
[5] Wayne M C, Anthony K B, David L, Kenneth W J. Coord. Chem. Rev., 2004, 248(1/2): 1363-1379
[6] Wayne M C, Kenneth W J, Pawel W, Klaudia W, Penny J W, Keith C G, Lukas S M, Mohammad K N, Wang Q, Grtzel M, David L. J. Phys. Chem. C, 2007, 111(32): 11760-11762
[7] Takeru B, Shaik M Z, Chen Y Y, Eric W G D, Grtzel M. Angew. Chem. Int. Ed., 2010, 49(1/5): 6646-6649
[8] Luo L Y, Lin C J, Hung C S, Lo C F, Linc C Y, Eric W G D. Phys. Chem. Chem. Phys., 2010, 12(40): 12973-12977
[9] Eu S, Hayashi S, Umeyama T, Oguro A, Kawasaki M, Kadota N, Matano Y, Imahori H. J. Phys. Chem. C, 2007, 111(8): 3528-3537
[10] Rochford J, Chu D, Hagfeldt A, Galoppini E. J. Am. Chem. Soc., 2007, 129(15): 4655-4665
[11] Lind S J, Gordon K C, Gambhir S, Officer D L. Phys. Chem. Chem. Phys., 2009, 11(27): 5598-5607
[12] Nazeeruddin M K, Humphry B R, Officer D L, Campbell W M, Burrell A K, Grtzel M. Langmuir, 2004, 20(15): 6514-6517
[13] Hayashi S, Tanaka M, Hayashi H, Eu S, Umeyama T, Matano Y, Araki Y, Imahori H. J. Phys. Chem. C, 2008, 112(39): 15576-15585
[14] Wang Q, Wayne M C, Bonfantani E E, Jolley K W, Officer D L, Walsh P J, Gordon K, Humphry B R, Nazeeruddin M K, Grtzel M. J. Phys. Chem. B, 2005, 109(32): 15397-15409
[15] Xu M, Wenger S, Bala H, Shi D, Li R, Zakeeruddin S M, Grtzel M, Wang P. J. Phys. Chem. C, 2009, 113 (7): 2966-2973
[16] Lee C W, Lu H P, Lan C M, Huang Y L, Liang Y R, Yen W N, Liu Y C, Lin Y S, Eric W G D, Yeh C Y. Chem. Eur. J., 2009, 6(15): 1403-1412
[17] Wu S L, Lu H P, Yu H T, Chuang S H, Chiu C L, Lee C W, Diau E W G, Yeh C Y. Energy Environ. Sci., 2010, 3: 949-955
[18] Lo C F, Hsu S J, Wang C L, Cheng Y H, Lu H P, Eric W G D, Lin C Y. J. Phys. Chem. C, 2010, 114(27): 12018-12023
[19] Hsieh C P, Lu H P, Chiu C L, Lee C W, Mai C L, Yen W N, Hsu S J, Diau E W G, Yeh C Y. J. Mater. Chem. , 2010, 20: 1127-1134
[20] Hasselman G M, Watson D F, Stromberg J R, Bocian D F, Holten D, Lindsey J S, Meyer G J. J. Phys. Chem. B, 2006, 110(50): 25430-25440
[21] Jung I, Choi H, Lee J K, Song K H, Kang S O, Ko J. Inorg. Chim. Acta, 2007, 360(11): 3518-3524
[22] Mozer A J, Matthew J G, George T, Pawel W, Gordon G W, Mori S, Sunahara K, Masanori M, John C E, Keith C G, Du L C, Katoh R, Furube A, David L. J. Am. Chem. Soc., 2009, 131(43): 15621-15623
[23] Mozer A J, Wagner P D L, Wallace G G, Wayne M C, Miyashita M, Sunahara K, Mori S. Chem. Commun., 2008, (39): 4741-4743
[24] Wang Z S, Koumura. N, Cui Y, Takahashi M, Sekiguchi H, Mori A, Kubo T, Furube A, Hara K. Chem. Mater., 2008, 20(12): 3993-4003
[25] Mai C L, Huang W K, Lu H P, Lee CW, Chiu C L, Liang Y R, Eric W G D, Yeh C Y. Chem. Commun., 2010, (46): 809-811
[26] Dy J T, Tamaki K, Sanehira Y, Nakazaki J, Uchida S, Kubo T, Segawa H. Electrochem., 2009, 77: 206-209
[27] Jong K P, Chen J P, Lee H R, Park S W, Shinokubo H, Osuka A, Kim D. J. Phys. Chem. C, 2009, 113(52): 21956-21963
[28] Officer D L. Presentation at the 3rd International Conference on the Industrialization of DSC, Nara, Japan, 2009
[29] Odobel F, Blart E, Lagre M, Villieras M, Boujtita H, Murr N E, Caramori S, Bignozzi C A. J. Mater. Chem., 2003, 13(3): 502-510
[30] Odobel F, Fortage J. Comptes Rendus Chimie, 2009, 12(3/4): 437-449
[31] Liu D, Fessenden R W, Hug G L, Kamat P V. J. Phys. Chem. B, 1997, 101(14): 2583-2590
[32] Kim S, Lee J K, Kang S O, Ko J, Yum J H, Fantacci S, Angelis F D, Censo D D, Nazeeruddin M K, Grtzel M. J. Am. Chem. Soc., 2006, 128(51): 16701-16707
[33] Luo L Y, Lin C J, Tsai C Y, Wu H P, Li L L, Lo C F, Lin C Y, Diau E W G. Phys. Chem. Chem. Phys., 2010, 12: 1064-1071
[34] Myahkostupov M, Piotrowiak P, Wang D, Galoppini E. J. Phys. Chem. C, 2007, 111(7): 2827-2829
[35] Lu H P, Mai C L, Tsia C Y, Hsu S J, Hsieh C P, Chiu C L, Yeh C Y, Diau E W G. Phys. Chem. Chem. Phys., 2009, 11: 10270-10274
[36] Lin C Y, Wang Y C, Hsu S J, Lo C F, Diau E W G. J. Phys. Chem. C, 2010, 114(1): 687-693
[37] Lo C F, Luo L Y, Diau E W G, Chang I J, Lin C Y. Chem. Commun., 2006, (13): 1430-1432
[38] Liu Y J, Xiang N, Feng X M, Shen P, Zhou W P, Weng C, Zhao B, Tan S T. Chem. Commun., 2009, (18): 2499-2501
[39] Cattarin S, Ceroni P, Guldi D M, Maggini M, Menna N, Paolucci F, Roffia S, Scorrano G. J. Mater. Chem., 1999, 9(11): 2743-2750
[40] Ma R M, Guo P. J. Mol. Structr., 2010, 942(1/3): 131-136
[41] Ma R M, Guo P. J. Phys. Chem. A, 2009, 113(37): 10119-10124
[42] Balanay M P. Sol. Energy. Mater. Sol. Cells, 2007, 91(19): 1775-1781
[43] Hirayama D, Takimiya F, AsoT, Otsu T, Hasobe T, Yamada H, Imahori H, Fukuzumi T, Sakata Y. J. Am. Chem. Soc., 2002, 124(4): 532-533
[44] Yamanaka K, Fujitsuka M, Araki Y, Ito O, Aoshima T, Fukushima T, Miyashi T. J. Phys. Chem. A, 2004, 108(2): 250-256
[45] Hattori S, Ohkubo K, Urano K, Sunahara H, Nagano H, Wada Y, Tkachenko N V, Lemmetyinen H, Fukuzumi S. J. Phys. Chem. B, 2005, 109(32): 15368-15375
[46] Imahori H, Hagiwara K, Aoki M, Akiyama T, Taniguchi S, Okada T, Shirakawa M, Sakata Y. J. Am. Chem. Soc., 1996, 118(47): 11771-11782
[47] Imahori H, Yamada H, Nishimura Y, Yamazaki I, Sakata Y. J. Phys. Chem. B, 2000, 104(9): 2099-2108
[48] Liddell A, Kodis A, Moore L, Moore T A, Gust D. J. Am. Chem. Soc., 2002, 124(26): 7668-7669
[49] Imahori H, Liu J C, Hosomizu K, Sato T, Mori Y, Hotta H, Matano Y, Araki Y, Ito O, Maruyama N, Fujita S. Chem. Commun., 2004, (18): 2066-2067
[50] Imahori H, Kashiwagi Y, Hasobe T, Kimura M, Hanada T, Nishimura Y, Yamazaki I, Araki Y, Ito O, Fukuzumi S. Thin Solid Films, 2004, 451/452: 580-588
[51] Hasobe T, Imahori H, Kamat P V, Fukuzumi S. J. Am. Chem. Soc., 2003, 125(49): 14962-14963
[52] Balanay M P, Dipaling C V P, Lee S H, Kim D H, Lee K H. Sol. Energy Mater. Sol. Cells, 2007, 91(13): 1775-1781
[53] Tohru S, Motohiro T. Thin Solid Films, 2008, 516(6): 1204-1208
[54] Cheng P, Wilson S R, Schuster D I. Chem. Commun., 1999, (1): 89-90
[55] Schuster D I, Cheng P, Wilson S R, Prokhorenko V, Katterle M, Holzwarth A R, Braslavsky S E, Klihm G, Williams R M, Luo C. J. Am. Chem. Soc., 1999, 121(49): 11599-11600
[56] David I S. Carbon, 2000, 38: 1607-1614
[57] David I S, Cheng P, Jarowski P D, Guldi D M, Luo C, Echegoyen L, Pyo S, Holzwarth A R, Braslavsky S E, Williams R M, Klihm G. J. Am. Chem. Soc., 2004, 126(23): 7257-7270
[58] Galili T, Regev A, Levanon H, Schuster D I, Guldi D M. J. Phys. Chem. A, 2004, 108(48): 10632-10639
[59] Fazio M A, Durandin A. Chem. Eur. J., 2009, 15(31): 7698-7705
[60] Vilmercati P, Cudia C C, Larciprete R, Cepek C, Zampieri G, Sangaletti L, Pagliara S, Verdini A, Cossaro A, Floreano L, Morgante A, Petaccia L, Lizzit S, Battocchio C, Polzonetti G, Goldoni A. Surf. Sci., 2006, 600(18): 4018-4023
[61] Miguel G, Paul A L, Gerdenis K, Bradley J B, Christopher R J, James W B, Ana L M, Thomas A M, Devens G. Photochem. Photobiol. Sci., 2010, 9(7): 890-900
[62] Ma T L, Inoue K, Noma H, Yao K, Abe E. J. Photochem. Photobiol. A, 2002, 152(1/3): 207-212
[63] Baik C, Kim D, Kang M S, Kang S O, Ko J, Nazeeruddin M K, Grtzel M. J. Photochem. Photobiol. A, 2009, 201(2/3): 168-174
[64] Odobel F, Blart E, Marie L, Villieras M, Hamada B, Murr N, Caramoric S, Carlo A B. J. Mater. Chem., 2003, 13(3): 502-510
[65] Ma T L, Inoue K, Yao K, Yu J, Wang X, Zhang B. J. Electroanal. Chem., 2002, 537(1/2): 31-38
[66] 吴迪(Wu D), 沈珍(Shen Z), 薛兆历(Xue Z L), 游效曾(You X Z). 无机化学学报(Chinese Journal of Inorganic Chemistry), 2007, 23(1): 1-14 S, Sunahara K, Masanori M, John C E, Keith C G, Du L C, Katoh R, Furube A, David L. J. Am. Chem. Soc., 2009, 131(43): 15621-15623

[23] Mozer A J, Wagner P D L, Wallace G G, Wayne M C, Miyashita M, Sunahara K, Mori S. Chem. Commun., 2008, (39): 4741-4743

[24] Wang Z S, Koumura. N, Cui Y, Takahashi M, Sekiguchi H, Mori A, Kubo T, Furube A, Hara K. Chem. Mater., 2008, 20(12): 3993-4003

[25] Mai C L, Huang W K, Lu H P, Lee CW, Chiu C L, Liang Y R, Eric W G D, Yeh C Y. Chem. Commun., 2010, (46): 809-811

[26] Dy J T, Tamaki K, Sanehira Y, Nakazaki J, Uchida S, Kubo T, Segawa H. Electrochem., 2009, 77: 206-209

[27] Jong K P, Chen J P, Lee H R, Park S W, Shinokubo H, Osuka A, Kim D. J. Phys. Chem. C, 2009, 113(52): 21956-21963

[28] Officer D L. Presentation at the 3rd International Conference on the Industrialization of DSC, Nara, Japan, 2009

[29] Odobel F, Blart E, Lagre M, Villieras M, Boujtita H, Murr N E, Caramori S, Bignozzi C A. J. Mater. Chem., 2003, 13(3): 502-510

[30] Odobel F, Fortage J. Comptes Rendus Chimie, 2009, 12(3/4): 437-449

[31] Liu D, Fessenden R W, Hug G L, Kamat P V. J. Phys. Chem. B, 1997, 101(14): 2583-2590

[32] Kim S, Lee J K, Kang S O, Ko J, Yum J H, Fantacci S, Angelis F D, Censo D D, Nazeeruddin M K, Grtzel M. J. Am. Chem. Soc., 2006, 128(51): 16701-16707

[33] Luo L Y, Lin C J, Tsai C Y, Wu H P, Li L L, Lo C F, Lin C Y, Diau E W G. Phys. Chem. Chem. Phys., 2010, 12: 1064-1071

[34] Myahkostupov M, Piotrowiak P, Wang D, Galoppini E. J. Phys. Chem. C, 2007, 111(7): 2827-2829

[35] Lu H P, Mai C L, Tsia C Y, Hsu S J, Hsieh C P, Chiu C L, Yeh C Y, Diau E W G. Phys. Chem. Chem. Phys., 2009, 11: 10270-10274

[36] Lin C Y, Wang Y C, Hsu S J, Lo C F, Diau E W G. J. Phys. Chem. C, 2010, 114(1): 687-693

[37] Lo C F, Luo L Y, Diau E W G, Chang I J, Lin C Y. Chem. Commun., 2006, (13): 1430-1432

[38] Liu Y J, Xiang N, Feng X M, Shen P, Zhou W P, Weng C, Zhao B, Tan S T. Chem. Commun., 2009, (18): 2499-2501

[39] Cattarin S, Ceroni P, Guldi D M, Maggini M, Menna N, Paolucci F, Roffia S, Scorrano G. J. Mater. Chem., 1999, 9(11): 2743-2750

[40] Ma R M, Guo P. J. Mol. Structr., 2010, 942(1/3): 131-136

[41] Ma R M, Guo P. J. Phys. Chem. A, 2009, 113(37): 10119-10124

[42] Balanay M P. Sol. Energy. Mater. Sol. Cells, 2007, 91(19): 1775-1781

[43] Hirayama D, Takimiya F, AsoT, Otsu T, Hasobe T, Yamada H, Imahori H, Fukuzumi T, Sakata Y. J. Am. Chem. Soc., 2002, 124(4): 532-533

[44] Yamanaka K, Fujitsuka M, Araki Y, Ito O, Aoshima T, Fukushima T, Miyashi T. J. Phys. Chem. A, 2004, 108(2): 250-256

[45] Hattori S, Ohkubo K, Urano K, Sunahara H, Nagano H, Wada Y, Tkachenko N V, Lemmetyinen H, Fukuzumi S. J. Phys. Chem. B, 2005, 109(32): 15368-15375

[46] Imahori H, Hagiwara K, Aoki M, Akiyama T, Taniguchi S, Okada T, Shirakawa M, Sakata Y. J. Am. Chem. Soc., 1996, 118(47): 11771-11782

[47] Imahori H, Yamada H, Nishimura Y, Yamazaki I, Sakata Y. J. Phys. Chem. B, 2000, 104(9): 2099-2108

[48] Liddell A, Kodis A, Moore L, Moore T A, Gust D. J. Am. Chem. Soc., 2002, 124(26): 7668-7669

[49] Imahori H, Liu J C, Hosomizu K, Sato T, Mori Y, Hotta H, Matano Y, Araki Y, Ito O, Maruyama N, Fujita S. Chem. Commun., 2004, (18): 2066-2067

[50] Imahori H, Kashiwagi Y, Hasobe T, Kimura M, Hanada T, Nishimura Y, Yamazaki I, Araki Y, Ito O, Fukuzumi S. Thin Solid Films, 2004, 451/452: 580-588

[51] Hasobe T, Imahori H, Kamat P V, Fukuzumi S. J. Am. Chem. Soc., 2003, 125(49): 14962-14963

[52] Balanay M P, Dipaling C V P, Lee S H, Kim D H, Lee K H. Sol. Energy Mater. Sol. Cells, 2007, 91(13): 1775-1781

[53] Tohru S, Motohiro T. Thin Solid Films, 2008, 516(6): 1204-1208

[54] Cheng P, Wilson S R, Schuster D I. Chem. Commun., 1999, (1): 89-90

[55] Schuster D I, Cheng P, Wilson S R, Prokhorenko V, Katterle M, Holzwarth A R, Braslavsky S E, Klihm G, Williams R M, Luo C. J. Am. Chem. Soc., 1999, 121(49): 11599-11600

[56] David I S. Carbon, 2000, 38: 1607-1614

[57] David I S, Cheng P, Jarowski P D, Guldi D M, Luo C, Echegoyen L, Pyo S, Holzwarth A R, Braslavsky S E, Williams R M, Klihm G. J. Am. Chem. Soc., 2004, 126(23): 7257-7270

[58] Galili T, Regev A, Levanon H, Schuster D I, Guldi D M. J. Phys. Chem. A, 2004, 108(48): 10632-10639

[59] Fazio M A, Durandin A. Chem. Eur. J., 2009, 15(31): 7698-7705

[60] Vilmercati P, Cudia C C, Larciprete R, Cepek C, Zampieri G, Sangaletti L, Pagliara S, Verdini A, Cossaro A, Floreano L, Morgante A, Petaccia L, Lizzit S, Battocchio C, Polzonetti G, Goldoni A. Surf. Sci., 2006, 600(18): 4018-4023

[61] Miguel G, Paul A L, Gerdenis K, Bradley J B, Christopher R J, James W B, Ana L M, Thomas A M, Devens G. Photochem. Photobiol. Sci., 2010, 9(7): 890-900

[62] Ma T L, Inoue K, Noma H, Yao K, Abe E. J. Photochem. Photobiol. A, 2002, 152(1/3): 207-212

[63] Baik C, Kim D, Kang M S, Kang S O, Ko J, Nazeeruddin M K, Grtzel M. J. Photochem. Photobiol. A, 2009, 201(2/3): 168-174

[64] Odobel F, Blart E, Marie L, Villieras M, Hamada B, Murr N, Caramoric S, Carlo A B. J. Mater. Chem., 2003, 13(3): 502-510

[65] Ma T L, Inoue K, Yao K, Yu J, Wang X, Zhang B. J. Electroanal. Chem., 2002, 537(1/2): 31-38

[66] 吴迪(Wu D), 沈珍(Shen Z), 薛兆历(Xue Z L), 游效曾(You X Z). 无机化学学报(Chinese Journal of Inorganic Chemistry), 2007, 23(1): 1-14

 
[1] 唐晨柳, 邹云杰, 徐明楷, 凌岚. 金属铁络合物光催化二氧化碳还原[J]. 化学进展, 2022, 34(1): 142-154.
[2] 陈茂龙, 尹帮少, 宋建新. 铃木偶联反应构筑卟啉阵列的研究进展[J]. 化学进展, 2015, 27(6): 641-654.
[3] 宋成杰, 王二静, 董兵海, 王世敏. 非富勒烯类有机小分子受体材料[J]. 化学进展, 2015, 27(12): 1754-1763.
[4] 牛凡凡, 聂昌军, 陈勇, 孙小玲. 非官能化烯烃的不对称催化环氧化反应[J]. 化学进展, 2014, 26(12): 1942-1961.
[5] 王桂强, 段彦栋, 张娟, 林原, 禚淑萍. 染料敏化太阳能电池掺杂TiO2纳晶光阳极[J]. 化学进展, 2014, 26(07): 1255-1264.
[6] 庄长福, 刘建路, 戴文, 吴中平, 王瑛, 高爽*. 卟啉金属有机骨架材料的合成及其在催化反应[J]. 化学进展, 2014, 26(0203): 277-292.
[7] 王志鹏, 张艳, 王晓青*. 金属酶中双氧活化的模型研究及应用[J]. 化学进展, 2013, 25(06): 915-926.
[8] 青木百合子*, 顾凤龙*. 增长法在离域体系纳米线中的应用[J]. 化学进展, 2012, 24(06): 886-909.
[9] 汤雅芸, 梅群波, 徐志杰, 凌启淡. 卟啉化合物在有机染料敏化太阳能电池中的研究[J]. 化学进展, 2011, 23(9): 1915-1928.
[10] 杨绳岩, 吴振奕, 万新军, 晏娟. 卟啉-富勒烯络合物的合成[J]. 化学进展, 2011, 23(6): 1123-1136.
[11] 殷晓春, 王荣民, 何玉凤, 朱永峰, 裴菲. 人工氧载体研究进展[J]. 化学进展, 2011, 23(5): 963-973.
[12] 杨正龙, 卜弋龙, 陈秋云. 高效率窄带隙聚合物太阳能电池材料[J]. 化学进展, 2011, 23(12): 2607-2616.
[13] 屠闻文, 雷建平, 鞠熀先. 卟啉纳米组装与生物传感[J]. 化学进展, 2011, 23(10): 2113-2118.
[14] 秦达, 郭晓枝, 孙惠成, 罗艳红, 孟庆波, 李冬梅. 染料敏化太阳能电池固态电解质[J]. 化学进展, 2011, 23(0203): 557-568.
[15] 兰章 吴季怀. 柔性染料敏化太阳能电池*[J]. 化学进展, 2010, 22(11): 2248-2253.