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化学进展 2011, Vol. 23 Issue (4): 810-818 前一篇   

• 综述与评论 •

生物乙醇重整制氢反应器

张超1,2, 郎林1, 阴秀丽1*, 吴创之1   

  1. 1. 中国科学院广州能源研究所 中国科学院可再生能源与天然气水合物重点实验室 广州 510640;
    2. 中国科学院研究生院 北京 100049
  • 收稿日期:2010-07-01 修回日期:2010-09-01 出版日期:2011-04-24 发布日期:2011-02-25
  • 通讯作者: e-mail:xlyin@ms.giec.ac.cn E-mail:xlyin@ms.giec.ac.cn
  • 基金资助:

    国家自然科学基金项目(No.50906091)、广东省自然科学基金重点项目(No.10251007006000000)和广东省自然科学基金自由申请项目(No.9151007006000003)资助

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Reactors for Hydrogen Production by Bio-Ethanol Reforming

Zhang Chao1,2, Yin Xiuli1, Wu Chuangzhi1*   

  1. 1. Renewable Energy and Gas Hydrate Key Laboratory of CAS, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;
    2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2010-07-01 Revised:2010-09-01 Online:2011-04-24 Published:2011-02-25

生物乙醇重整制氢是一种具有良好应用前景的制氢技术,是当前低碳能源领域的研究热点。发展生物乙醇重整制氢技术的关键是研发在低温下具有高活性和高选择性的新型重整催化剂,以及开发新式高效的催化反应器。本文着眼于反应器对生物乙醇重整制氢过程的影响,综述了国内外固定床反应器、微通道反应器和膜反应器等生物乙醇重整制氢反应器的研究现状及其动态,并对生物乙醇重整制氢反应器的研制与应用的发展趋势进行了展望。

关键词： 生物乙醇, 重整制氢, 固定床反应器, 微通道反应器, 膜反应器

Bio-ethanol reforming is a type of promising technology for hydrogen production,which is focused on current low-carbon energy research.The key of ethanol reforming is to develop novel reforming catalysts with high activity and high selectivity at low temperature,and new efficient catalytic reactors.The effects of reactors on ethanol reforming process are focused in this paper,and ethanol reforming reactors at home and abroad are reviewed,such as fixed-bed reactors,microchannel reactors and membrane reactors.Based on the extensive discussion of the advantages and weaknesses of various catalytic reactors,the trends in the manufacture and application of bio-ethanol reforming reactors are also prospected.In our opinions,the following aspects need to be studied systematically: (1) strengthening basic theoretical researches,especially the reaction mechanisms of bio-ethanol reforming and the principles of mass/heat transfer; (2) developing novel low-temperature reforming catalysts with high activity,high stability,and low cost; (3) designing highly integrated catalytic reactors for bio-ethanol reforming.

Key words: bio-ethanol, hydrogen production by reforming, fixed-bed reactor, microchannel reactor, membrane reactor

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生物乙醇重整制氢反应器