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化学进展 2011, Vol. 23 Issue (4): 781-790 前一篇   后一篇

• 综述与评论 •

“Schizophrenic”嵌段共聚物多重胶束化的研究

张晓晖, 艾长军, 马敬红*, 徐坚   

  1. 东华大学纤维材料改性国家重点实验室 上海 201620
  • 收稿日期:2010-07-01 修回日期:2010-10-01 出版日期:2011-04-24 发布日期:2011-02-25
  • 通讯作者: e-mail:mjh68@dhu.edu.cn E-mail:mjh68@dhu.edu.cn
  • 基金资助:

    上海市重点学科建设项目(No.B603)资助

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Schizophrenic Micellization of Block Copolymers

Zhang Xiaohui, Ai Changjun, Ma Jinghong*, Xu Jian   

  1. Department Chemistry, Jilin University, Changc 130023, China
  • Received:2010-07-01 Revised:2010-10-01 Online:2011-04-24 Published:2011-02-25

在不同环境刺激下自组装形成多重胶束的“schizophrenic”嵌段共聚物由于诱人的潜在应用而引起广泛的关注。本文综述了各种刺激诱导形成多重胶束的“schizophrenic”嵌段共聚物研究情况,介绍了多重胶束化不同形态的影响因素和胶束稳定方面的进展。并对“schizophrenic”嵌段共聚物的合成与表征技巧进行了总结,最后讨论了当前研究中仍需解决的问题,并对其应用前景做了展望。

关键词： “schizophrenic”嵌段共聚物, 自组装, 多重胶束化, 环境诱导

The schizophrenic micellization of block copolymers who can self-assembled into well-defined structures in aqueous solution in response to specific stimuli such as temperature,pH,ionic strength and light has draw much attention due to the attractive protential applications.A typical case in this new sub-field involved environmental-sensitive AB diblock copolymer synthesized by group transfer polymerization (GTP) or living radical polymerisation (ATRP or RAFT),allowing the formation of two distinct types of micelle structures (A-core / B-corona and B-core / A-corona structures) in response to external stimuli and the two structures can be reversibly converted into each other.This remarkable property was introduced by Armes and coworkers for 'smart’ pH-dependent micelles of poly [2- (diethylamino) ethyl methacrylate] -block- poly[2- (N-morpholino) ethyl meth-acrylate].Recent progress in synthesis and environmental-induced schizophrenic micellization of block copolymers,the morphology of aggregations self-assembled from schizophrenic block copolymers and fixed structure of micelles by crosslinker have been reviewed.Technical problems in synthesis and characterization of schizophrenic micellization are also discussed,including 1H-NMR spectra,zeta potential,light scattering,transmittance of the solution and stopped-flow spectrophotometric techniques.Furthermore,the problems in schizophrenic micellization those still should be resolved are pointed out,and the direction of this research field is discussed.

Key words: “schizophrenic&rdquo, block copolymer, self-asembly, schizophrenic micellization, environment variation

中图分类号: 

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