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化学进展 2011, Vol. 23 Issue (4): 760-771 前一篇   后一篇

• 综述与评论 •

点击化学与活性自由基聚合联用构建特殊结构聚合物

袁伟忠1,2*, 张锦春1, 魏静仁1   

  1. 1. 同济大学材料科学与工程学院 纳米与生物高分子材料研究所 上海 20009;
    2. 先进土木工程材料教育部重点实验室 上海 200092
  • 收稿日期:2010-07-01 修回日期:2010-10-01 出版日期:2011-04-24 发布日期:2011-02-25
  • 通讯作者: e-mail:yuanwz@tongji.edu.cn E-mail:yuanwz@tongji.edu.cn
  • 基金资助:

    国家自然科学基金项目(No. 20804029)资助

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导出 被引次数 ( 11 | 5 )

Synthesis of Well-Defined Polymer via a Combination of Click Chemistry and Living Radical Polymerization

Yuan Weizhong1,2*, Zhang Jinchun1, Wei Jingren1   

  1. 1. Institute of Nano and Bio-polymeric Materials, School of Materials Science and Engineering, Tongji University, Shanghai 20009;
    2. Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, Shanghai 200092, China
  • Received:2010-07-01 Revised:2010-10-01 Online:2011-04-24 Published:2011-02-25

点击化学由于其高效、可靠、高选择性等特点,一经提出便在复杂结构聚合物制备上得到广泛关注,而活性自由基聚合则具有聚合过程和聚合物结构可控等特点。本文综述了点击化学与活性自由基聚合方法如原子转移自由基聚合(ATRP),可逆加成断裂链转移聚合(RAFT),氮氧调控活性自由基聚合(NMP),以及原子转移氮氧自由基聚合反应(ATNRC)等联用构建各种特殊结构聚合物,包括星型,梳型,刷型,蝌蚪型,8字型,H型,树枝状等特殊结构聚合物最新进展,并对点击化学与活性自由基聚合技术联用的发展趋势进行了展望。

关键词： 点击化学, 活性自由基聚合, 联用, 特殊结构聚合物

Considerable attention has focused on the preparation of polymers with complicated structures via click chemistry due to high efficiency,reliable,high selectivity of click chemistry.On the other hand, living radical polymerization can control the polymerization and polymer structures effectively.This review highlights the development of the synthesis of well-defined polymers such as star-shaped,comb-shaped,brush-shaped,tadpole-shaped,figure-of-eight-shaped,H-shaped,and dendrimer-like polymers via a combination of click chemistry and living radical polymerization such as atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer polymerization (RAFT), nitroxide-mediated polymerization (NMP), and atom transfer nitroxide radical coupling (ATNRC).Moreover, based on the recent progress, it has a prospect for the combination of click chemistry and living radical polymerization.

Key words: click chemistry, living radical polymerization, combination, well-defined polymers

中图分类号: 

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