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化学进展 2011, Vol. 23 Issue (4): 657-668 前一篇   后一篇

• 综述与评论 •

碳纳米管/半导体复合材料光催化研究进展

肖信1,2, 张伟德1*   

  1. 1. 华南理工大学化学与化工学院 广州 510640;
    2. 华南师范大学化学与环境学院 广州 510006
  • 收稿日期:2010-06-01 修回日期:2010-09-01 出版日期:2011-04-24 发布日期:2011-02-25
  • 通讯作者: e-mail:zhangwd@scut.edu.cn E-mail:zhangwd@scut.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.20773041)和教育部高等学校博士点基金项目(No.20070561008)资助

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Photocatalysis of Carbon Nanotubes/Semiconductor Composites

Xiao Xin1,2, Zhang Weide1*   

  1. 1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China;
    2. School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China
  • Received:2010-06-01 Revised:2010-09-01 Online:2011-04-24 Published:2011-02-25

碳纳米管具有良好的机械性能和导电性、高化学稳定性、大表面积以及独特的一维结构,与半导体光催化剂结合能够增强催化剂的吸附能力、提高光催化效率、扩展光响应范围,而且有利于回收催化剂,极大地提高了半导体光催化剂的综合性能。本文首先分析了半导体光催化剂和碳纳米管的特点,总结了碳纳米管增强半导体光催化的机理,然后分别从复合材料制备方法、复合半导体种类和典型的应用三个不同角度,归纳总结了近年来碳纳米管/半导体复合材料光催化的研究进展,最后对其发展趋势作了展望。

关键词： 碳纳米管, 半导体, 光催化, 合成, 应用

Because of their unique one-dimensional geometric structure, large surface area, high electrical conductivity, elevated mechanical strength and strong chemical inertness, carbon nanotubes (CNTs) provide new features as supports for semiconductor photocatalysts with enhanced catalytic properties. The CNTs not only provide large surface for the dispersion of active semiconductors, but also improve the adsorption of the photocatalysts, enhance their photocatalytic activities, extend the light responding region and make them more easily recycled. The synergistic effect of the carbon nanotubes and semiconductors endows the nanocomposites with superb properties and excellent performance. In this review, based on the analysis and comparison of the advantages and disadvantages of semiconductors and carbon nanotubes, the enhancement mechanisms of the CNTs/semiconductor catalysts are introduced. Afterwards, the relevant literature and advances in photocatalysis of the CNTs/semiconductors are summarized according to (1) the preparation methods of composite materials, for example, direct deposition, sol-gel method, hydrothermal/solvothermal process, chemical vapor deposition and so forth; (2) the type of semiconductors, such as oxides, sulfides, nitrides and complex oxides, and (3) their typical applications, including the degradation of pollutants in water and air, photocatalytic splitting of water for hydrogen generation, used as antibacterial materials and as catalysts for the synthesis of organic compounds. Finally, the prospects and challenge for these composite materials are also discussed.

Key words: carbon nanotubes, semiconductors, photocatalysis, synthesis, applications

中图分类号: 

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