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钌基氨合成催化剂的制备方法

张留明, 林建新, 倪军, 林炳裕, 王榕, 魏可镁   

  1. 福州大学化肥催化剂国家工程研究中心 福州 350002
  • 收稿日期:2011-03-01 修回日期:2011-06-01 出版日期:2011-11-24 发布日期:2011-08-30
  • 通讯作者: 林建 E-mail:lin3jx@fzu.edu.cn
  • 基金资助:

    中国石油科技创新基金研究项目(No.2010D-5006-0502) 资助

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导出 被引次数 ( 7 | 2 )

Preparation Methods of Ruthenium Catalysts for Ammonia Synthesis

Zhang Liuming, Lin Jianxin, Ni Jun, Lin Bingyu, Wang Rong, Wei Kemei   

  1. National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China
  • Received:2011-03-01 Revised:2011-06-01 Online:2011-11-24 Published:2011-08-30
  • Contact: Lin Jianxin E-mail:lin3jx@fzu.edu.cn

与铁催化剂相比较,钌基氨合成催化剂具有低温、低压、高活性的特点。对于不同的载体、制备方法和制备条件对催化剂性能影响较大。本文从载体的前处理、活性组分钌和助剂的加入方式等方面简要阐述了钌基氨合成催化剂制备方法的研究进展,介绍了熔融法、升华法、离子交换法、超声法、沉淀法、溶胶-凝胶法、浸渍法、微波辅助法等钌基氨合成催化剂制备方法,指出了一些制备方法的不足之处,并展望了钌基氨合成催化剂制备方法的研究方向。

关键词： 钌, 氨合成, 催化剂, 制备方法

The ruthenium catalysts for ammonia synthesis have higher activity than the iron catalyst, especially under the condition of low temperature and pressure. Different preparation methods and preparation conditions will influence the ruthenium catalyst activity with different support materials. This paper describes the preparation methods of Ru catalysts for ammonia synthesis from three aspects, including the pretreatment of supports, the loading of Ru and the addition of promoters. Different methods such as melting method, sublimation method, ion exchange, ultrasound method, precipitation, sol-gel method, impregnate method, microwave-assisted method are reviewed and the shortages of some methods are discussed. The development trends of the preparation of Ru catalyst are also proposed.

Contents
1 Introduction
2 Pretreatment of supports
2.1 Heat treatment
2.2 Oxidation treatment
2.3 Other treatment methods
3 Preparation methods of ruthenium catalysts and promoters
3.1 Melting method
3.2 Sublimation method
3.3 Ion exchange method
3.4 Sol-gel method
3.5 Microwave-assisted synthesis
3.6 Ultrasound-assisted synthesis
3.7 Precipitation method
3.8 Impregnation method
4 Conclusions and outlook

Key words: ruthenium, ammonia synthesis, catalysts, preparation methods

中图分类号: 

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钌基氨合成催化剂的制备方法