PDF(1217 KB)
PDF(1217 KB)
PDF(1217 KB)
生物质转化为液体燃料2,5-二甲基呋喃 的途径与机理
- 胡磊, 孙勇*, 林鹿*
作者信息
+
Pathways and Mechanisms of Liquid Fuel 2,5-Dimethylfuran from Biomass
- Hu Lei, Sun Yong*, Lin Lu*
Author information
+
文章历史
+
摘要
随着化石燃料的日益减少,寻找可再生的液体生物质燃料已经引起了越来越广泛的关注。由生物质制备得到的2,5-二甲基呋喃(DMF)具有高能量密度、高沸点、高辛烷值和不溶于水等优点,近年来被认为是一种非常有前景的液体燃料。本文归纳和总结了生物质转化为DMF的化学途径、方法和反应机理以及DMF的燃烧性能,并对今后的研究方向进行了展望。
Abstract
With the decrease of fossil fuel reserves, looking for renewable liquid fuels from biomass have attracted increasingly interest. 2,5-Dimethylfuran (DMF) from renewable biomass with special advantages of high energy density, high boiling point, high octane number, and immiscible with water has been considered as a kind of promising liquid fuel. In this paper, the chemical pathways, the production methods, the reaction mechanisms and the combustion performance of DMF from biomass are mainly summarized, and the future research trends are prospected.
Contents
1 Introduction
2 Chemical pathways of production of DMF from biomass
3 Pathways and reaction mechanisms of production of DMF from biomass
3.1 DMF production in biphasic system
3.2 DMF production in N,N-dimethylacetamide
3.3 DMF production in ionic liquids
3.4 DMF production in formic acid
4 The combustion performance of DMF
5 Perspective
关键词
液体燃料 / 生物质 / 2,5-二甲基呋喃 / 5-羟甲基糠醛 / 5-氯甲基糠醛 {{custom_keyword}} /
Key words
liquid fuels / biomass / 2,5-dimethylfuran / 5-hydroxymethylfurfural / 5-chloromethylfurfural {{custom_keyword}} /
中图分类号：
O643.3
TQ517.4
{{custom_clc.code}}
({{custom_clc.text}})
{{custom_sec.title}}
{{custom_sec.title}}
参考文献
[1] Agarwal A K. Prog. Energ. Combust., 2007, 33(3): 233-271
[2] Kintisch E. Science, 2007, 315(5813): 747-747
[3] Atsumi S, Hanai T, Liao J C. Nature, 2008, 451(7174): 86-89
[4] Demirbas M F. Appl. Energ., 2009, 86(S1): S151-S161
[5] Naik S N, Goud V V, Rout P K, Dalai A K. Renew. Sust. Energ. Rev., 2010, 14(2): 578-597
[6] Roman-Leshkov Y, Barrett C J, Liu Z Y, Dumesic J A. Nature, 2007, 447(7147): 982-986
[7] Tian G H, Daniel R, Li H Y, Xu H M, Shuai S J, Richards P. Energy Fuels, 2010, 24(7): 3898-3905
[8] 田国弘 (Tian G H), 徐宏明 (Xu H M), Daniel R, 李海鹰 (Li H Y), 李雁飞 (Li Y F). 汽车安全与节能学报 (Journal of Automotive Safety and Energy), 2010, 1(2): 132-140
[9] Inderwildi O R, King D A. Energy. Environ. Sci., 2009, 2(4): 343-346
[10] Balat M. Energy. Convers. Manage., 2010, 52(2): 858-875
[11] Zhao H B, Holladay J E, Brown H, Zhang Z C. Science, 2007, 316(5831): 1597-1600
[12] Mascal M, Nikitin E B. Angew. Chem., 2008, 120(41): 8042-8044
[13] Schmidt L D, Dauenhauer P J. Nature, 2007, 447: 914-915
[14] Binder J B, Raines R T. J. Am. Chem. Soc., 2009, 131(5): 1979-1985
[15] Tong X L, Ma Y, Li Y D. Appl. Catal. A: Gen., 2010, 385(1/2): 1-13
[16] Jiao C Q, Adams S F, Garscadden A. Jpn. J. Appl. Phys., 2009, 106(1): art. no. 0133061
[17] Chidambaram M, Bell A T. Green Chem., 2010, 12: 1253-1262
[18] 吴学松 (Wu X S), 卫立夏 (Wei L X), 黄佐华 (Huang Z H), 袁涛 (Yuan T), 张奎文 (Zhang K W). 科学通报 (Chinese Science Bulletin), 2008, 53(23): 2872-2880
[19] Zhong S H, Daniel R, Xu H M, Zhang J, Turner D, Wyszynski M L, Richards P. Energy Fuels, 2010, 24(5): 2891-2899
[20] Thananatthanachon T, Rauchfuss T B. Agnew. Chem. Int. Ed., 2010, 49(37): 6616-6618
[21] Luque R, Herrero-Davila L, Campelo J M, Clark J H, Hidalgo J M, Luna D. Energy Environ. Sci., 2008, 1(5): 542-564
[22] Daniel R, Tian G H, Xu H M, Wyszynski M L, Wu X S, Huang Z H. Fuel, 2011, 90(2): 449-458
[23] Yong G, Zhang Y G, Ying J Y. Agnew. Chem. Int. Ed., 2008, 120(48): 9485-9488
[24] Hu S Q, Zhang Z F, Song J L, Zhou Y X, Han B X. Green Chem., 2009, 11(11): 1746-1749
[25] Li C Z, Zhang Z H, Zhao Z B K. Tetrahedron Lett., 2009, 50(38): 5403-5405
[26] Shimizu K I, Uozumi R, Satsuma A. Catal. Commun., 2009, 10(14): 1849-1853
[27] Su Y, Brown H M, Huang X W, Zhou X D, Amonette J E, Zhang Z C. Appl. Catal. A: Gen., 2009, 361(1/2): 117-122
[28] Qi X H, Watanabe M, Aida T M, Smith R L. Chem. Sus. Chem., 3(9): 1071-1077
[29] Zhang Y T, Du H B, Qian X H, Chen E Y X. Energy Fuels, 2010, 24(4): 2410-2417
[30] Chen T M, Lin L. Chin. J. Chem., 2010, 28(9): 1773-1776
[31] Chun J A, Lee J W, Yi Y B, Hong S S, Chung C H. Starch/Stärke, 2010, 62(6): 326-330 《化学进展》近期目次预告 “无涯之知,世代之功”——汪猷的主要科学成就和学术思想 (陈耀全) 功能性无机-晶态纳米纤维素复合材料的研究进展与展望 (徐雁) 多蝶烯及其衍生物的合成与应用 (曹菁 江一 陈传峰) 基于Belousov-Zhabotinsky自振荡反应的智能高分子 (周宏伟 梁恩湘 郑朝晖 丁小斌 彭宇行)
{{custom_fnGroup.title_cn}}
脚注
{{custom_fn.content}}
基金
国家重点基础研究发展计划(973)项目(No. 2010CB732201)、国家自然科学基金项目(No. 50776035)和中央高校基本业务费专项资金项目(No. 2010121077)资助
{{custom_fund}}
/
| 〈 |
|
〉 |