分子筛膜包覆型催化剂的制备和应用

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化学进展 ›› 2011, Vol. 23 ›› Issue (10) : 2021-2030.

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金炜阳, 程党国, 陈丰秋, 詹晓力. 分子筛膜包覆型催化剂的制备和应用[J]. 化学进展, 2011, 23(10): 2021-2030 Jin Weiyang, Cheng Dangguo, Chen Fengqiu, Zhan Xiaoli. Synthesis and Application of Zeolite Membrane Encapsulated Catalysts[J]. Progress in Chemistry, 2011, 23(10): 2021-2030

综述与评论

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分子筛膜包覆型催化剂的制备和应用

金炜阳, 程党国, 陈丰秋*, 詹晓力

作者信息 +

Synthesis and Application of Zeolite Membrane Encapsulated Catalysts

Jin Weiyang, Cheng Dangguo, Chen Fengqiu*, Zhan Xiaoli

Author information +

文章历史 +

摘要

均匀、连续、致密分子筛膜的合成和应用受到广泛关注。利用分子筛膜具有的筛分和催化作用,在传统颗粒催化剂或载体表面包覆分子筛膜形成复合型催化剂,可以实现膜基分离和催化过程的耦合,增加反应物选择性,提高目标产物收率。本文综述了近年来在不同类型颗粒催化剂或载体表面合成分子筛膜的制备方法,描述了分子筛膜包覆型复合催化剂用于不同催化反应体系的研究结果。同时,在归纳和总结已有研究成果基础上展望了分子筛膜包覆型催化剂的研究发展趋势。

Abstract

Increasing attention has been drawn on the synthesis and application of homogeneous, continuous and dense zeolite membranes. By the use of separation and catalysis performance of zeolite membrane, the traditional particle catalyst coated with a zeolite film can act as a zeolite membrane reactor and enhance catalytic effects obviously. In this paper, preparation methods and applications of zeolite encapsulated catalysts were reviewed. The recent progresses on the study of zeolite-coated catalysts based on different supports were also introduced. And the technical trends in zeolite encapsulated catalysts were prospected.

Contents
1 Introduction
2 Preparation methods of encapsulated catalysts
2.1 Direct hydrothermal synthesis
2.2 Secondary growth on seeded supports
2.3 Dry gel conversion
2.4 Dip-coating
3 Preparation and applications of encapsulated catalysts on different supports
3.1 Silica
3.2 Alumina
3.3 Cordierite honeycomb monoliths
3.4 Activated carbon
4 Conclusion and prospects

关键词

分子筛膜 / 包覆 / 载体 / 膜催化反应器

Key words

zeolite membrane / encapsulated / supports / catalytic membrane reactor

中图分类号： O643.36 TB43

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