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化学进展 2011, Vol. 23 Issue (0203): 569-588 前一篇   后一篇

• 综述与评论 •

染料敏化太阳能电池用敏化剂

李祥高*, 吕海军, 王世荣, 郭俊杰, 李靖   

  1. 天津大学化工学院 天津 300072
  • 收稿日期:2010-10-01 修回日期:2010-11-01 出版日期:2011-03-24 发布日期:2011-01-26
  • 通讯作者: e-mail: lixianggao@hotmail.com E-mail:lixianggao@hotmail.com
  • 基金资助:

    天津市自然科学基金项目(No.08JCZDJC16900)资助

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Sensitizers of Dye-Sensitized Solar Cells

Li Xianggao*, Lü Haijun, Wang Shirong, Guo Junjie, Li Jing   

  1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • Received:2010-10-01 Revised:2010-11-01 Online:2011-03-24 Published:2011-01-26

染料敏化太阳能电池是太阳能电池的重要发展方向之一,染料敏化剂是影响电池光电转换效率的重要组分,也一直是太阳能电池材料的研究热点。经过20多年的研究,现已开发的光敏染料主要有金属配合物染料和纯有机染料两大类。本文依据染料结构特征,将金属配合物染料分为钌的多吡啶配合物、其它金属(如Os、Pt)的多吡啶配合物、卟啉及酞菁类配合物分别加以讨论,对其光敏性能进行了详细评述。纯有机染料结构主要遵循电子给体-π桥-电子受体的电子推拉体系(donor-π-acceptor,D-π-A),本文将其分为多烯类、香豆素类、咔唑类、吲哚类、芴类和三苯胺类染料分别阐述,详细讨论了各类有机染料结构和光电性能之间的关系。

关键词： 太阳能电池, 敏化染料, 金属配合物染料, 有机染料

Dye-sensitized solar cells (DSSCs) are one of the main development trends of solar cells. Dye sensitizer, which greatly affects the photoelectronic efficiency of solar cells, is all along an important research focus in the field of cell materials. The sensitizers used in DSSC are mainly divided into two types: metal complex dye and organic dye according to research results during recent twenty years. On the basis of different structures, the metal complex sensitizers utilized in DSSC can be classified into polypyridyl complex sensitizers of ruthenium and other metal such as osmium and platinum, metal porphyrin and phthalocyanine sensitizers, and their photoelectric conversion properties are reviewed in detail. Organic dye sensitizers with general structure of “donor (D)-π conjugation bridge-acceptor (A)” are widely used in DSSC because of their high molar extinction coefficient and low cost. The relations of photoelectric conversion properties with structures of organic dye sensitizers including oligoene dye, coumarin dye, carbazole dye, indoline dye, fluorene dye and triphenylamine dye are reviewed in detail.

Key words: dye-sensitized solar cells (DSSCs), dye sensitizers, metal complex dye, organic dye

中图分类号: 

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染料敏化太阳能电池用敏化剂