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化学进展 2011, Vol. 23 Issue (0203): 548-556 前一篇   后一篇

• 综述与评论 •

柔性染料敏化太阳电池的制备和性能研究

林原*, 王尚华, 付年庆, 张敬波, 周晓文, 肖绪瑞   

  1. 中国科学院化学研究所 北京分子科学国家实验室 光化学重点实验室 北京 100190
  • 收稿日期:2010-10-01 出版日期:2011-03-24 发布日期:2011-01-26
  • 通讯作者: e-mail:linyuan@iccas.ac.cn E-mail:linyuan@iccas.ac.cn
  • 基金资助:

    国家重点基础研究发展计划(973)项目(No.2006CB202605)、中国科学院创新基金项目(No.KGCX2-YW-386-2)、国家高技术发展计划(863)项目(No.2007AA05Z439)和国家自然科学基金项目(No.20973183)资助

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Preparation and Properties of Flexible Dye-Sensitized Solar Cells

Lin Yuan*, Wang Shanghua, Fu Nianqing, Zhang Jingbo, Zhou Xiaowen, Xiao Xurui   

  1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Received:2010-10-01 Online:2011-03-24 Published:2011-01-26

柔性染料敏化太阳电池作为具有低生产成本的实用化技术受到高度重视。本文研究以金属钛为基底的纳晶TiO2薄膜电极和以导电涂层聚合物为基底的对电极组成的柔性染料敏化太阳电池。为提高光电转换效率,采用直流低场电泳沉积、直流和脉冲电压下的电化学阳极氧化及丝网印刷,结合高温烧结方法,制备金属钛为基底的纳晶TiO2薄膜电极和TiO2纳米管薄膜电极;用恒电流电化学沉积、化学还原等低温技术制备导电涂层聚合物为基底的载铂对电极和碳对电极。对不同的制备方法及优化技术的机制和特点进行了分析探讨,比较了不同方法制备的纳晶TiO2薄膜电极和对电极的性能。在此基础上,研制全柔太阳电池,最大光电转换效率达到6.74%。

关键词： 染料敏化太阳电池, 柔性太阳电池, 纳晶TiO2薄膜电极, 载铂对电极

Flexible dye-sensitized solar cell has attracted much attention due to its advantages of low cost and easy production.Flexible dye-sensitized solar cell comprised of a nanocrystalline TiO2 film electrode based on Ti-metal substrate and a counter-electrode based on plastic substrate is investigated. In order to improve the photovoltaic performance, the different methods including electrophoretic deposition under low DC field, electrochemical anodization by DC and pulse voltages and screen printing in cooperation with high-temperature sintering were employed to prepare Ti substrate based nanocrystalline TiO2 film electrodes and TiO2 nanotube film electrodes, and low-temperature methods of electrochemical deposition and chemical reduction were used to prepare Pt and carbon counter-electrodes on the plastic substrate. The mechanism and characters of these methods and the techniques of optimization were analyzed and discussed. The performance of the nanocrystalline TiO2 film electrodes and counter-electrodes prepared by different methods were measured and evaluated by their photovoltaic behavior measurements. Flexible dye-sensitized solar cells with Ti substrate based TiO2 photoelectrodes and plastic substrate based Pt counter-electrodes prepared by different methods were fabricated. The maximal light to electricity conversion efficiency of 6.74% was achieved.

Key words: dye-sensitized solar cells, flexible solar cells, nanocrystalline TiO2 thin film electrode, Pt counter electrode

中图分类号: 

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[1] Grtzel M. Inorg. Chem., 2005, 44: 6841-6851
[2] Grtzel M. Prog. Photovoltaics, 2006, 16: 429-442
[3] Kim S S, Yum J H, Sung Y E. J. Photochem. Photobiol. A, 2005, 171: 269-273
[4] Haque S A, Palomares E, Upadhyaya H M, et al. Chem. Commun, 2003, 3008-3009
[5] 李成玉 (Li C Y), 林原 (Lin Y), 李学萍 (Li X P)等. 科学通报(Chinese Science Bullelin), 2005, 50(6): 527-530
[6] Li C Y, Li X P, Ma Y T, et al. Chin. Chem. Lett., 2005, 16 (7): 967-970
[7] Zhang D S, Yoshida T, Furuta K, et al. J. Photochem. Photobiol. A, 2004, 164: 159-166
[8] Oekermann T, Zhang D S, Yoshida T. J. Phys. Chem. B, 2004, 108(7): 2229-2235
[9] Miyasaka T, Kijitori Y, Murakami T N, et al. Chem. Lett., 2002, 31: 1250-1251
[10] Yum J H, Kim S S, Kim D Y. J. Photochem. Photobiol. A, 2005, 173: 1-6
[11] Kim G S, Seo H K, Godble V P, et al. Electrochem. Commun., 2006, 8: 961-966
[12] Lindstrm H, Holmberg A, Magnusson E, et al. Nano Lett., 2001, 1(2): 97-100
[13] Boschloo G, Lindstrm H, Magnusson E, et al. J. Photochem. Photobiol. A, 2002, 148: 11-15
[14] Yamaguchi T, Tobe N, Matsumoto D, et al. Chem. Commun., 2007, 4767-4769
[15] Murakami T N, Kijitori Y, Kawashima N, et al. J. Photochem. Photobiol. A, 2004, 164: 187-191
[16] Hart J N, Menzies D, Cheng Y B, et al. Sol. Energy Mater. Sol. Cells, 2007, 91: 6-16
[17] Uchida S, Tomiha M, Takizawa H, et al. J. Photochem. Photobiol. A, 2004, 164: 93-96
[18] Kang M G, Park N G, Ryu K S, et al. Sol. Energy Mater. Sol. Cells, 2006, 90: 574-581
[19] Park J H, Jun Y, Kang M G, et al. J. Electrochem. Soc., 2008, 155(7): F145-F149
[20] Onoda K, Ngamsinlapasathian S, Fujieda T, et al. Sol. Energy Mater. Sol. Cells, 2007, 91: 1176-1181
[21] Ito S, Ha N L C, Rothenberger G, et al. Chem. Commun., 2006, 4004-4006
[22] Yang D J, Park H, Cho S J, et al. J. Phys. Chem. Solid., 2008, 69: 1272-1275
[23] Kuang D, Brilet J, Chen P, et al. ACS Nano, 2008, 2(6): 1113-1116
[24] Kim S S, Nah Y C, Noh Y Y, et al. Electrochimica Acta, 2006, 51: 3814-3819
[25] Sheppard S A, Campbell S A, Smith J R, et al. Analyst, 1998, 123: 1923-1929
[26] Pichot F, Pitts J R, Gregg B A. Langmuir, 2000, 16: 5626-5630
[27] Tan W W, Yin X, Zhou X W, et al. Electrochimica Acta, 2009, 54: 4467-4472
[28] Tan W W, Chen J M, Zhou X W, et al. J. Solid State Electrochem., 2009, 13: 651-656
[29] Lin Y, Ma Y T, Yang L, et al. J. Electroanal. Chem., 2006, 588: 51-58
[30] Lin Y, Xiao X R, Zhang D S, et al. Chin. Sci. Bull., 2003, 48: 856-858
[31] Gong D W, Grimes C A, Varghese D K. J. Mater. Res., 2001, 16: 3331-3334
[32] Mor G K, Shankar K, Danlose M, et al. Nano Lett., 2006, 6: 215-218
[33] Tao J L, Zhao J L, Wang X X, et al. Electrochem. Commun., 2008, 10: 1161-1163
[34] Shankar K, Bandare J, Paulose M, et al. Nano Lett., 2008, 8(6): 1654-1659
[35] Ong K G, Varghese O K, Mor G K. J. Nanosci. Nanotechnol., 2005, 5: 1801-1808
[36] Ghicov A, Schmuki P. Chem. Commun., 2009, 2791-2808
[37] Papageorgiou N, Maier W F, Grtzel M. J. Electrochem. Soc., 1997, 144(3): 876-884
[38] Chen L L, Tan W W, Zhang J B, et al. Electrochimica Acta, 2010, 55: 3721-3726
[39] Kay A, Grtzel M. Sol. Energy Mater. Sol. Cells, 1996, 44: 99-117
[40] Murakami T N, Ito S, Wang Q, et al. J. Electrochem. Soc., 2006, 153: A2255-A2261
[41] Huang Z, Liu X Z, Li K X, et al. Electrochem. Commun., 2007, 9(4): 596-598
[42] Lee W J, Ramasamy E, Lee D Y, et al. Sol. Energy Mater. Sol. Cells, 2008, 92: 814-818
[43] Wang G Q, Xing W, Zhou S P. J. Power Sources, 2009, 194: 568-573
[44] Chen L L, Liu J, Zhang J B, et al. Chin. Chem. Lett., 2010, 21: 1137-1140
[45] Zhang J B, Sun L, Ichinose K, et al. Phys. Chem. Chem. Phys., 2010, 12: 10494-10502
[46] Yoshida T, Zhang J B, Komatsu D, et al. Adv. Fuct. Mater., 2009, 19: 17-43
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