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化学进展 2011, Vol. 23 Issue (0203): 441-448 前一篇   后一篇

• 综述与评论 •

无机质子导体的研究进展

马桂林*, 许佳, 张明, 王小稳, 尹金玲, 徐建红   

  1. 苏州大学材料与化学化工学部 江苏省有机合成重点实验室 苏州 215123
  • 收稿日期:2010-09-01 修回日期:2010-11-01 出版日期:2011-03-24 发布日期:2011-01-26
  • 通讯作者: e-mail:32uumagl@suda.edu.cn E-mail:32uumagl@suda.edu.cn
  • 基金资助:

    国家自然科学基金项目(No. 20171034)资助

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导出 被引次数 ( 7 | 4 )

The Developments of Inorganic Proton Conductors

Ma Guilin*, Xu Jia, Zhang Ming, Wang Xiaowen, Yin Jinling, Xu Jianhong   

  1. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
  • Received:2010-09-01 Revised:2010-11-01 Online:2011-03-24 Published:2011-01-26

无机质子导体是一类重要的功能材料,具有许多潜在的电化学应用,包括燃料电池、氢传感器、氢的电解制备和分离提纯、氢泵、水蒸气泵、氮氧化物消除、有机物的催化氢化和脱氢,核聚变反应堆废气中的氢同位素气体的回收利用,以及常压合成氨等。本文综述了无机质子导体的研究进展,尤其是近年来的最新研究进展,主要包括典型的无机质子导体,无机质子导体的缺陷化学及质子传导机制,无机质子导体材料可能的应用、问题及展望。

关键词： 无机质子导体, 功能材料, 缺陷化学, 质子传导机制

Inorganic proton conductor is a kind of important functional material for many potential electrochemical applications such as fuel cell, hydrogen sensor, electrolytic preparation and separation and purification of hydrogen, hydrogen pump, steam pump, removal of nitrogen oxide, hydrogenation and dehydrogenation of some organic compounds, recover of hydrogen isotopes from nuclear fusion reactor, and ammonia synthesis at atmospheric pressure, etc. In this paper, the recent progress of inorganic proton conductors is reviewed, mainly including typical inorganic proton conductors, their defect chemistry and proton transport mechanism, possible applications, some issues, and expectations for the future.

Key words: inorganic proton conductor, functional materials, defect chemistry, proton transport mechanism

中图分类号: 

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[1] Iwahara H, Shimura T, Matsumoto H. Electrochemistry, 2000, 68: 154-161
[2] Iwahara H, Asakura Y, Katahira K, Tanaka M. Solid State Ionics, 2004, 168: 299-310
[3] Marnellos G., Stoukides M. Science, 1998, 282: 98-100
[4] Nakamura O, Kodama T, Ogino I, Miyake Y. Chem. Lett., 1979, 8: 17-18
[5] Kovy J V D, Cuthbert J D, Petch H E. J. Phys., 1964, 42: 1871-1878
[6] Haile S M, Boysen D A, Chisholm C R I, Merle R B. Nature, 2001, 410: 910-913
[7] Farrington G C, Briant J L. Mat. Res. Bull., 1978, 13: 763-773
[8] Nishimura K. Solid State Commun., 1976, 20: 523-524
[9] Bond G C, Sermon P A. Catal. Rew., 1973, 8: 211-239
[10] Iwahara H, Esaka T, Uchida H, Maeda N. Solid State Ionics, 1981, 3/4: 359-363
[11] Iwahara H, Uchida H, Ono K, Ogaki K. J. Electrochem. Soc., 1988, 135: 529-533
[12] Iwahara H, Yajima T, Hibino T, Ozaki K, Suzuki H. Solid State Ionics, 1993, 61: 65-69
[13] Kreuer K D. Solid State Ionics, 1999, 125: 285-302
[14] Zuo C, Zha S, Liu M, Hatano M, Uchiyama M. Adv. Mater., 2006, 18: 3318-3320
[15] Lv J, Wang L, Lei D, Guo H. J. Alloys Compd., 2009, 467: 376-382
[16] Azad A K, Irvine J T S. Chem. Mater., 2009, 21: 215-222
[17] Shimada T, Wen C, Taniguchi N, Otomo J, Takahashi H. J. Power Sources, 2004, 131: 289-292
[18] Xie K, Yan R, Liu X. Electrochem. Commun., 2009, 11: 1618-1622
[19] Wang H, Peng R, Wu X, Hu J, Xia C. J. Am. Ceram. Soc., 2009, 92: 2623-2629
[20] Yang L, Wang S, Blinn K, Liu M, Liu Z, Cheng Z, Liu M. Science, 2009, 326: 126-129
[21] Zhang J, Wen Z, Han J, Wu J, Huang S, Zhu X. J. Alloys Compd., 2007, 440: 270-275
[22] Lee W, Nowick A S, Boatner L A. Solid State Ionics, 1986, 18/19: 989-993
[23] Fujii H, Katayama Y, Shimura T, Iwahara H. J. Electroceramics, 1998, 2: 119-125
[24] 蒋 凯(Jiang K), 何志奇(He Z Q), 王鸿伟(Wang H W), 梁宏伟(Liang H W), 孟建(Meng J), 任玉芳(Ren Y F), 苏锵(Su Q). 中国科学 (B辑) (Science in China Series B), 1999, 29: 355-360
[25] Lin B, Dong Y, Yan R, Hu M, Zhou Y, Meng G. J. Power Sources, 2009, 186: 446-449
[26] Lin B, Ding H, Dong Y, Zhang X, Fang D, Meng G. J. Power Sources, 2009, 186: 58-61
[27] Xie K, Yan R, Liu B, Liu X, Meng G. J. Membrane Sci., 2008, 325: 6-10
[28] Bi L, Zhang S, Fang S, Tao Z, Peng R, Liu W. Electrochem. Commun., 2008, 10: 1598-1601
[29] Li Z J, Liu R Q, Xie Y H, Feng S, Wang J D. Solid State Ionics, 2005, 176: 1063-1066
[30] Liu R, Xie Y, Wang J, Li Z, Wang B. Solid State Ionics, 2006, 177: 73-76
[31] Wang J, Xie Y, Zhang Z, Liu R, Li Z. Mater. Res. Bull., 2005, 40: 1294-1302
[32] 吕喆(Lü Z), 刘江(Liu J), 黄喜强(Huang X Q), 刘志国(Liu Z G), 刘巍(Liu W), 贺天民(He T M), 苏文辉(Su W H). 高等学校化学学报(Chemical Journal of Chinese Universities), 2001, 22: 630-633
[33] Zhang C, Zhao H, Xu N, Li X, Chen N. Int. J. Hydrogen Energy, 2009, 34: 2739-2746
[34] 彭珍珍(Peng Z Z), 郭瑞松(Guo R S), 尹自光(Yin Z G), 李娟(Li J), 蔡舒(Cai S). 稀有金属材料与工程(Rare Metal Materials and Engineering), 2007, 36: 596-598
[35] Guo Y, Liu B, Yang Q, Chen C, Wang W, Ma G. Electrochem. Commun., 2009, 11: 153-156
[36] Wang W, Cao X, Gao W, Zhang F, Wang H, Ma G. J. Membrane Sci., 2010, 360: 397-403
[37] Ma G, Zhang F, Zhu J, Meng G. Chem. Mater., 2006, 18: 6006-6011
[38] Ishihara T, Matsuda H, Takita Y. J. Am. Chem. Soc., 1994, 116: 3801-3803
[39] Shima D, Haile S M. Solid State Ionics, 1997, 97: 443-455
[40] Ma G, Shimura T, Iwahara H. Solid State Ionics, 1998, 110: 103-110
[41] Ma G, Matsumoto H, Iwahara H. Solid State Ionics, 1999, 122: 237-247
[42] Qiu L, Ma G, Wen D. Solid State Ionics, 2004, 166: 69-75
[43] Nowick A S, Yang D. Solid State Ionics, 1995, 77: 137-146
[44] Yang D, Nowick A S. Solid State Ionics, 1996, 91: 85-91
[45] Shimura T, Suzuki K, Iwahara H. Solid State Ionics, 1997, 104: 79-88
[46] Shimura T, Suzuki K, Iwahara H. Solid State Ionics, 1999, 125: 313-318
[47] Shimura T, Suzuki K, Iwahara H. Solid State Ionics, 1998, 113: 355-361
[48] Haugsrud R, Norby T. Nat. Mater., 2006, 5: 193-196
[49] Haugsrud R, Norby T. Solid State Ionics, 2006, 177: 1129-1135
[50] Shimura T, Komori M, Iwahara H. Solid State Ionics, 1996, 86/88: 685-689
[51] Nigara Y, Yashiro K, Kawada T, Mizusaki J. Solid State Ionics, 2003, 159: 135-141
[52] Norby T, Kofstad P. J. Am. Ceram. Soc., 1984, 67: 786-792
[53] Amezawa K, Maekawa H, Tomii Y, Yamamoto N. Solid State Ionics, 2001, 145: 233-240
[54] Shimura T, Fujimoto S, Iwahara H. Solid State Ionics, 2001, 143: 117-123
[55] Baranov A I, Duda V M, Jones D J, Roziere J, Sinitsyn V V. Solid State Ionics, 2001, 145: 241-247
[56] Kwon K, Yano M, Sun H, Park J. 2005, US 20050221143, A1: 1-4
[57] Gover R K B, Withers N D, Allen S, Withers R L, Evans J S O. J. Solid State Chem., 2002, 166: 42-48
[58] Nagao M, Kamiya T, Heo P, Tomita A, Hibino T, Sano M. J. Electrochem. Soc., 2006, 153: A1604-A1609
[59] Genzaki K, Heo P, Sano M, Hibino T. J. Electrochem. Soc., 2009, 156: B806-B810
[60] Tomita A, Nakajima J, Hibino T. Angew. Chem. Int. Ed., 2008, 47: 1462-1464
[61] Wu X, Verma A, Scott K. Fuel Cells, 2008, 8: 453-458
[62] Sun X, Wang S, Wang Z, Ye X, Wen T, Huang F. Solid State Ionics, 2008, 179: 1138-1141
[63] 李永生(Li Y S), 汪伟(Wang W), 耿浩然(Geng H R), 柳晓飞(Liu X F). 济南大学学报 (自然科学版) (Journal of University of Jinan (Science and Technology)), 2009, 23: 131-133
[64] 车全通(Che Q T), 王东(Wang D), 何荣桓(He R H). 应用化学(Chinese Journal of Applied Chemistry), 2009, 26: 1015-1018
[65] Wang H, Liu J, Wang W, Ma G. J. Power Sources, 2010, 195: 5596-5600
[66] Wang H, Zhang H, Xiao G, Zhang F, Yu T, Xiao J, Ma G. J. Power Sources, 2011, 196: 683-687
[67] Wang H, Xiao J, Zhou Z, Zhang F, Zhang H, Ma G. Solid State Ionics, 2010, 181: 1521-1524
[68] Uchida H., Maeda N, Iwahara H. Solid State Ionics, 1983, 11: 117-124
[69] Uchida H, Yoshikawa H, Iwahara H. Solid State Ionics, 1989, 34: 103-110
[70] Hibino T, Mizutani K, Yajima T, Iwahara H. Solid State Ionics, 1992, 58: 85-88
[71] Yugami H, Shibayama Y, Hattori T, Ishigame M. Solid State Ionics, 1995, 79: 171-176
[72] Sata N, Hiramoto K, Ishigame M, Hosoya S, Niimura N, Shin S. Phys. Rev. B, 1996, 54: 15795-15799
[73] Yugami H, Matsuo S, Ishigame M. Solid State Ionics, 1995, 77: 195-200
[74] Yugami H, Chiba Y, Ishigame M. Solid State Ionics, 1995, 77: 201-206
[75] Sata N, Matsuta H, Akiyama Y, Chiba Y, Shin S, Ishigame M. Solid State Ionics, 1997, 97: 437-441
[76] Shimojo F, Hoshino K, Okazaki H. J. Phys. Soc. Jpn., 1998, 67: 2008-2011
[77] Iwahara H, Uchida H, Maeda N. J. Power Sources, 1982, 7: 293-301
[78] Zhu B, Albinsson I, Mellander B-E, Meng G. Solid State Ionics, 1999, 125: 439-446
[79] 马桂林(Ma G L), 顾仁敖(Gu R A), 石慧(Shi H), 陈蓉(Chen R), 仇立于(Qiu L Y), 贾定先(Jia D X). 化学学报(Acta Chimica Sinica), 2001, 59: 2084-2088
[80] Iwahara H, Yajima T, Hibino T, Ushida H. J. Electrochem. Soc., 1993, 140: 1687-1691
[81] Hibino T, Hashimoto A, Suzuki M, Yano M, Yoshida S. Sano M. J. Electrochem. Soc., 2002, 149: A1503-A1508
[82] Yajima T, Koide K, Fukatsu N, Ohashi T, Iwahara H. Sensor Actuat. B, 1993, 14: 697-699
[83] Fukatsu N, Kurita N, Koid K, Ohashi T. Solid State Ionics, 1998, 113-115: 219-227
[84] 陈威(Chen W), 王常珍(Wang C Z), 刘亮(Liu L). 金属学报(Acta Metallurgica Sinica), 1995, 31: B305-B310
[85] 郭红霞(Gao H X), 吕敬德(Lü J D), 王岭(Wang L), 唐晓微(Tang X W). 无机化学学报(Chinese Journal of Inorganic Chemistry), 2008, 24: 1631-1635
[86] Kobayashi T, Abe K, Ukyo Y, Matsumoto H. Solid State Ionics, 2001, 138: 243-251
[87] Iwahara H, Esaka T, Uchida H, Yamauchi T, Ogaki K. Solid State Ionics, 1986, 18-19: 1003.
[88] Hamakawa S, Hibino T, Iwahara H. J. Electrochem. Soc., 1994, 141: 1720-1725
[89] Kobayashi T, Morishita S, Abe K, Iwahara H. Solid State Ionics, 1996, 86: 603-607
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摘要

无机质子导体的研究进展