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化学进展 2011, Vol. 23 Issue (0203): 390-400 前一篇   后一篇

所属专题： 锂离子电池

• 综述与评论 •

锂离子电池电极界面特性研究方法

秦银平1, 庄全超1*, 史月丽1, 江利1, 孙智1, 孙世刚2   

  1. 1. 中国矿业大学材料科学与工程学院 徐州 221116;
    2. 固体表面物理化学国家重点实验室 厦门大学化学化工学院化学系 厦门 361005
  • 收稿日期:2010-10-01 修回日期:2010-11-01 出版日期:2011-03-24 发布日期:2011-01-26
  • 通讯作者: e-mail:zhuangquanchao@126.com E-mail:zhuangquanchao@126.com
  • 基金资助:

    中央高校基本科研业务费专项资金项目(No. 2010LKHX03,2010QNB04,2010QNB05)、中国矿业大学科技攀登计划(No. ON090237)和中国矿业大学青年科技基金项目(No. ON080282)资助

下载PDF ( 2366 ) 引用
导出 被引次数 ( 24 | 7 )

Methods on Investigating Properties of Electrode/Electrolyte Interfaces in Lithium-Ion Batteries

Qin Yinping1, Zhuang Quanchao1*, Shi Yueli1, Jiang Li1, Sun Zhi1   

  1. 1. School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, China;
    2. State Key Lab for Physical Chemistry of Solid Surfaces, Department of Chemistry, Xiamen University, Xiamen 361005, China
  • Received:2010-10-01 Revised:2010-11-01 Online:2011-03-24 Published:2011-01-26

电极界面特性是影响锂离子电池充放电循环容量与稳定性的重要因素。本文总结了目前对电极界面特性进行研究的方法,主要包括传统的电化学方法、显微方法、谱学方法、电化学石英微晶天平等,重点论述了上述研究方法的原理、优缺点和在研究电极界面特性中的应用,以及这些方法相结合所取得的一些研究进展,并指出在今后的工作中,无论是对新材料的研究还是传统材料的研究,这些方法都仍将发挥重要作用。

关键词： 锂离子电池, 固体电解质相界面膜(SEI), 研究方法

The rechargeable lithium-ion battery has been extensively used in mobile communication and portable instruments due to its many advantages, such as high volumetric and gravimetric energy density and low self-discharge rate. In addition, it is the most promising candidate as the power source for (hybrid) electric vehicles and stationary energy storage. The properties of electrode/electrolyte interfaces play an important role in the electrochemical performance of the electrode material and a battery, such as the capacities, irreversible charge “loss”, rate capability and cyclability. In present paper, the methods to investigate the properties of electrode/electrolyte interfaces, for example, traditional electrochemical methods, microscopy methods, spectroscopic methods, electrochemical quartz crystal microgravimetry (EQCM) are summarized. The principles, advantages and disadvantages of these methods and their applications in investigating the properties of electrode/electrolyte interfaces, especially the progress in the combination of these methods to investigate the properties of electrode/electrolyte interfaces, are introduced in detail, and these methods will be considerable to study the new materials or the traditional materials for lithium-ion batteries in the future.

Key words: lithium-ion batteries, solid electrolyte interphase (SEI), methods

中图分类号: 

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