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化学进展 2011, Vol. 23 Issue (0203): 357-365 前一篇   后一篇

所属专题： 锂离子电池

• 综述与评论 •

硼基锂盐电解质在锂离子电池中的应用

仇卫华*, 阎坤, 连芳, 乔亚非   

  1. 北京科技大学 材料科学与工程学院 100083
  • 收稿日期:2010-10-01 修回日期:2010-11-01 出版日期:2011-03-24 发布日期:2011-01-26
  • 通讯作者: e-mail:qiuwh@vip.sina.com E-mail:qiuwh@vip.sina.com
下载PDF ( 2361 ) 引用
导出 被引次数 ( 20 | 4 )

Application of Boron-Based Lithium Salt for Li-Ion Battery

Qiu Weihua*, Yan Kun, Lian Fang, Qiao Yafei   

  1. School of Material Science and Engineering, University of Science & Technology Beijing, Beijing 100083, China
  • Received:2010-10-01 Revised:2010-11-01 Online:2011-03-24 Published:2011-01-26

电解质材料是锂离子电池的关键材料之一,它直接影响电池的性能。新型硼酸锂盐由于种类繁多且环境友好而越来越引起人们的重视。双草酸硼酸锂(LiBOB)是一种新型的锂盐,具有很好的成膜性能和热稳定性,是一种很有潜力替代现有商品化锂盐LiPF6的物质。本文介绍了近期新型硼基锂盐的发展状况,归纳了LiBOB基电解质的研究概况,综述了影响LiBOB基电解质的因素,讨论了LiBOB与正负极材料的相容性,并对LiBOB基聚合物电解质和LiBOB塑晶电解质的应用进行了介绍。

关键词： 锂离子电池, 电解质, 双草酸硼酸锂

Electrolyte is considered as one of the key materials to decide the performance of Li-ion batteries. Novel boron-based lithium salts have attracted people’s interests because of its varieties and environmental-friendly property. Lithium bis(oxalato)borate (LiBOB), as one of boron-based lithium salts, is believed to be a candidate for commercial LiPF6 due to its good film-forming property and high thermal stability. In the paper, the new development of boron-based lithium salts is introduced, and LiBOB is also evaluated as lithium salt of electrolyte for Li-ion battery. The main influencing factors of LiBOB-based electrolyte are summarized. Especially, it has focused on the compatibility of LiBOB-based electrolyte with anode and metal oxide cathode. The application of LiBOB-based polymer electrolyte and LiBOB plastic chip electrolyte are introduced.

Key words: Li-ion battery, electrolyte, lithium bis(oxalato)borate(LiBOB)

中图分类号: 

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