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化学进展 2011, Vol. 23 Issue (0203): 318-327 前一篇   后一篇

所属专题： 锂离子电池

• 综述与评论 •

锂离子电池负极硅基材料

陶占良, 王洪波, 陈军*   

  1. 南开大学先进能源材料化学教育部重点实验室 天津 300071
  • 收稿日期:2010-09-01 修回日期:2010-10-01 出版日期:2011-03-24 发布日期:2011-01-26
  • 通讯作者: e-mail:chenabc@nankai.edu.cn E-mail:chenabc@nankai.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.21076108)、教育部创新团队项目(No.IRT0927)和天津市应用基础及前沿技术研究计划项目(No.08JCZDJC21300,10JCYBJC08400)资助

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Si-Based Materials as the Anode of Lithium-Ion Batteries

Tao Zhanliang, Wang Hongbo, Chen Jun*   

  1. Key Laboratory of Advanced Energy Material Chemistry of Ministry of Education, Nankai University, Tianjin 300071, China
  • Received:2010-09-01 Revised:2010-10-01 Online:2011-03-24 Published:2011-01-26

硅基材料由于其高电化学容量是一种非常有发展前途的锂离子电池负极材料,但其在充放电过程中体积变化大、循环寿命差、首次库仑效率低等是阻碍其商业化的主要问题。本文综述了硅在脱嵌锂时晶体结构及表/界面的变化,以及改善其电化学性能方面的研究进展,并阐述其作为锂离子电池负极材料的研究前景。

关键词： 硅基材料, 负极, 锂离子电池

Silicon-based materials are promising anode materials for lithium-ion batteries (LIBs) due to their high-energy capacity. However, the commercialization of silicon-based materials as the anode of LIBs has been hindered by the huge volume change, poor cycle life and low initial coulombic efficiency during the charge/discharge process. This article reviews the change of both the crystal structure and the surface/interface of Si-based material during the intercalation/deintercalation of lithium, and the methods improving the electrochemical performance. In addition, the prospects of silicon-based materials as the anode of LIBs are also discussed.

Key words: silicon-based materials, anode materials, lithium ion batteries

中图分类号: 

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摘要

锂离子电池负极硅基材料