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化学进展 2011, Vol. 23 Issue (0203): 310-317 前一篇   后一篇

所属专题： 锂离子电池

• 综述与评论 •

锂离子电池负极材料Li4Ti5O12

杨立*, 陈继章, 唐宇峰, 房少华   

  1. 上海交通大学化学化工学院 上海 200240
  • 收稿日期:2010-09-01 修回日期:2010-10-01 出版日期:2011-03-24 发布日期:2011-01-26
  • 通讯作者: e-mail:liyangce@sjtu.edu.cn E-mail:liyangce@sjtu.edu.cn
  • 基金资助:

    国家高技术发展计划(863)项目(No.2007AA03Z222)和国家重点基础研究发展计划(973)项目(No.2006CB202600)资助

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Li4Ti5O12 Anode Materials Applied in Lithium Ion Batteries

Yang Li*, Chen Jizhang, Tang Yufeng, Fang Shaohua   

  1. School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, China
  • Received:2010-09-01 Revised:2010-10-01 Online:2011-03-24 Published:2011-01-26

Li4Ti5O12具有充放电循环性能好、电压平台平稳、安全性高、价格低、环境友好、易于制备等优点,在锂离子电池负极材料中得到广泛研究。本文基于国内外近期的研究进展,综述了制备Li4Ti5O12的方法,着重介绍了固相、溶胶-凝胶、熔盐、燃烧、喷雾、水/溶剂热等几种主要的合成方法,并针对Li4Ti5O12电导率低的缺点,详细阐述了Li4Ti5O12电化学性能的改善方法,包括元素掺杂和导电材料改性。文章最后对此类材料的发展趋势做了展望。

关键词： Li4Ti5O12, 锂离子电池, 制备方法, 掺杂, 改性

Li4Ti5O12 spinel has advantages of superior cycling performance, long and stable voltage plateau, enhanced safety, low cost, environmental friendliness, and can be easily prepared. It has been widely studied in lithium ion batteries. In this paper, the recent progress in synthesis study of Li4Ti5O12 is systematically reviewed based on the latest literature. Some important synthesis methods such as solid state, sol-gel, molten salt, combustion, spray drying and hydro/solvothermal synthesis are summarized. Improvements to improve the conductivity of Li4Ti5O12 by doping and surface modification are also elaborated in this paper. The problems that should be resolved and the further perspectives are pointed out.

Key words: Li4Ti5O12, lithium ion batteries, synthesis methods, doping, modification

中图分类号: 

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[110] 王瑾(Wang J), 成雪莲(Cheng X L), 王子港(Wang Z G)等. 无机材料学报(J. Inorganic Materials), 2010, 25(3): 235—241

[111] 王辰云(Wang C Y), 华宁(Hua N), 康雪雅(Kang X Y)等. 功能材料(Journal of Functional Materials), 2010, 41: 126—135

[112] 陈京才(Chen J C), 崔燕(Cui Y), 夏信德(Xia X D)等. 电源技术(Chinese Journal of Power Sources), 2010, 134(6): 539—542

[113] 康晓红(Kang X H), 江红(Jiang H). 北京交通大学学报(J. Beijing Jiaotong University), 2010, 34(3): 63—66

[114] 张标(Zhang B), 杜鸿达(Du H D), 李宝华(Li B H)等. 电源技术(Chinese Journal of Power Sources), 2010, 134(3): 226—229

[115] 李星(Li X), 瞿美臻(Qu M Z), 于作龙(Yu Z L). 功能材料(Journal of Functional Materials), 2009, 11(40): 1938—1941

[116] 熊利芝(Xiong L Z), 何则强(He Z Q), 尹周澜(Yi Z L)等. 中国有色金属学会会刊(Trans. Nonferrous Met. Soc. China), 2010, 20: s267—s270

 
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摘要

锂离子电池负极材料Li4Ti5O12