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化学进展 2011, Vol. 23 Issue (0203): 302-309 前一篇   后一篇

• 综述与评论 •

自由基聚合物——一类新颖的高性能二次电池材料

赵瑞瑞, 朱利敏, 杨汉西*   

  1. 武汉大学化学与分子科学学院 武汉 430072
  • 收稿日期:2010-09-01 修回日期:2010-11-01 出版日期:2011-03-24 发布日期:2011-01-26
  • 通讯作者: e-mail:hxyang@whu.edu.cn E-mail:hxyang@whu.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.20973132)资助

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Radical Polymer——A New Class of High Performance Electrode Materials for Rechargeable Batteries

Zhao Ruirui, Zhu Limin, Yang Hanxi*   

  1. College of Chemistry and Molecule Science, Wuhan University, Wuhan 430072, China
  • Received:2010-09-01 Revised:2010-11-01 Online:2011-03-24 Published:2011-01-26

自由基聚合物是一种新近发展迅速的电荷储存与传输材料,在电化学超级电容器、光电转换器件、二次电池等方面具有诱人的应用前景。本文着重介绍这类新颖电极材料的结构特征、电化学反应机制,以及国内外的研究发展现状;分析了采用自由基聚合物构建新型二次电池的技术途径和发展趋势。

关键词： 自由基聚合物, 电极材料, 二次电池, 高功率密度, 高能量密度

Radical polymers are aliphatic or nonconjugated polymers bearing organic redox radicals as pendant groups on their structural unit. These radical sites populated in large densities allow the electrochemical redox reaction taking place through the polymer layer by redox gradient-driven electron transport and behave as electroactive centers. Since radical polymer can be designed with a large population of redox radicals and electron exchange between the radical sites are usually very fast, they are considered as a new class of charge storage and transport materials with the possibility to provide high electrical storage capacity and high charge-discharge rate capability. Particularly, these polymers are completely organic with the advantage of being fully substainable, they are ideal for the displacement of inorganic materials in diverse applications such as electrochemical supercapacitors, photovoltaic cells and rechargeable batteries.This paper is intended to review the structural characteristics, electrochemical reaction mechanisms and current development status of the radical polymers as electode-active materials, with focus on the technological challenges and ongoing research strategies of these novel electrode materials as used for construction of high capacity and high rate rechargeable batteries. Also, the problems in the development of radical polymer electrodes are discussed.

Key words: radical polymers, electrode-active materials, rechargeable batteries, high-rate performance, high energy density

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