English
往期目录
新闻公告
More
化学进展 2011, Vol. 23 Issue (0203): 284-301 前一篇   后一篇

所属专题： 锂离子电池

• 综述与评论 •

锂离子电池正极材料的结构设计与改性

王兆翔*, 陈立泉, 黄学杰   

  1. 中国科学院物理研究所固态离子学实验室 北京 100190
  • 收稿日期:2010-09-01 修回日期:2010-11-01 出版日期:2011-03-24 发布日期:2011-01-26
  • 通讯作者: e-mail:zxwang@aphy.iphy.ac.cn E-mail:zxwang@aphy.iphy.ac.cn
  • 基金资助:

    国家重点基础研究发展计划(973)项目(No.2009CB220100)资助

下载PDF ( 10269 ) 引用
导出 被引次数 ( 187 | 10 )

Structural Design and Modification of Cathode Materials for Lithium Ion Batteries

Wang Zhaoxiang*, Chen Liquan, Huang Xuejie   

  1. Laboratory for Solid State Ionics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
  • Received:2010-09-01 Revised:2010-11-01 Online:2011-03-24 Published:2011-01-26

正极材料是目前锂离子电池中锂离子的唯一或主要提供者,也是锂离子电池能量密度提高和价格降低的瓶颈。本文在简要介绍几类典型的正极材料结构、性能特点及存在的主要问题后,重点介绍本实验室近年来在正极材料的表面改性和结构设计方面的研究进展。

关键词： 锂离子电池, 正极材料, 表面改性, 结构设计, 掺杂

The cathode (positive electrode) is the single (or major) donor of lithium ions in current lithium ion batteries. It is becoming the bottleneck to the increase of energy density and the decrease of cost of lithium ion batteries. This review presents the research progress in our laboratory in surface modification and structural designing of cathode materials after a brief introduction to the structures, the performance features and the main problems of some typical cathode materials.

Key words: lithium ion battery, cathode materials, surface modifications, structural designing, substitution

中图分类号: 

()

[1] Tukamoto H, West A R. J. Electrochem. Soc., 1997, 144: 3164-3168
[2] Thomas M, Bruce P G, Goodenough J B. Solid State Ionics, 1986, 18/19: 794-798
[3] Thomas M, Bruce P G, Goodenough J B. Solid State Ionics, 1985, 17: 13-19
[4] Thomas M, Bruce P G, Goodenough J B. J. Electrochem. Soc., 1985, 132: 1521-1528
[5] Reimers J N, Dahn J R. J. Electrochem. Soc., 1992, 139: 2091-2097
[6] Reimers J N, Dahn J R, Sacken U. J. Electrochem. Soc., 1993, 140: 2752-2754
[7] Mizushima K, Jones P C, Wiseman P J, Goodenough J B. Mater. Res. Bull., 1980, 15: 783-789
[8] Goodenough J B, Mizushima K, Takeda K. Jpn. J. Appl. Phys., 1980, 19: 305-313
[9] Mendiboure A, Delmas C, Hagenmuller P. Mater. Res. Bull., 1984, 19: 1383-1392
[10] Ohzuku T, Ueda A, Nagayama M. J. Electrochem. Soc., 1993, 140: 1862-1870
[11] Stoyanova R, Zhecheva E, Zarkova L. Solid State ionics, 1994, 73: 233-240
[12] Waki S, Dokko K, Ito T, Nishizawa M, Abe T, Uchida I. J. Solid State Electrochem., 2000, 4: 205-209
[13] Nazri G A, Rougier A, Kia K F. Mater. Res. Soc. Symp. Proc., 1997, 435: 635-646
[14] Ceder G, Chiang Y M, Sadoway D R, Aydinol M K, Jang Y I, Huang B. Nature, 1998, 392: 694-696
[15] Jang Y I, Ceder G, Chiang Y M, Liu H, Tamura H. J. Electrochem. Soc., 1999, 146: 862-868
[16] Cho J, Kim G B, Lim H S, Kim C S, Yoo S I. Electrochem. Solid-State Lett., 1999, 2: 607-609
[17] Chen Z, Dahn J R. Electrochem. Solid-State Lett., 2002, 5: A213-A216
[18] Wang Z X, Wu C, Liu L J, Huang X J, Chen L Q. J. Electrochem. Soc., 2002, 49: A466-A471
[19] Bruce P G, Lisowska-Oleksiak A, Saidi M, Vincent C. Solid State Ionics, 1992, 57: 353-358
[20] Delmas C, Peres J P, Rougier A, Weill F, Chadwick A, Broussely M, Perton F, Biensan P, Willmann P. J. Power Sources, 1997, 68: 120-125
[21] 孙玉城(Sun Y C). 中国科学院研究生院博士论文(Doctoral Dissertation of Graduate School of Chinese Academy of Sciences), 2004
[22] Yang X Q, Sun X, McBreen J. Electrochem. Commun., 2000, 2: 733-737
[23] Ohzuku T, Ueda A, Harai T. Chem. Express, 1992, 7: 193
[24] Huang Z F, Du F, Wang C Z, Wang D P, Chen G. Phys. Rev. B, 2007, 75: art. no. 054411
[25] 黄友元(Huang Y). 北京大学博士论文(Doctoral Dissertation of Peking University), 2010
[26] Hwang B J, Tsai Y W, Carlier D, Ceder G. Chem. Mater., 2003, 15: 3676-3682
[27] Tsai Y W, Hwang B J, Ceder G, Sheu H S, Liu D G, Lee J F. Chem. Mater., 2005, 17: 3191-3199
[28] Shin Y J, Choi W J, Hong Y S, Yoon S, Ryu K S, Chang S H. Solid State Ionics, 2006, 177: 515-521
[29] Chen C H, Wang C J, Hwang B L. J. Power Sources, 2005, 146: 626-629
[30] Patoux S, Doeff M M. Electrochem. Commun., 2004, 6: 767-772
[31] Reddy M M, Rao G V S, Chowdari B V R. J. Power Sources, 2006, 159: 263-267
[32] Wang Z X, Sun Y C, Chen L Q, Huang X J. J. Electrochem. Soc., 2004, 151: A914-A921
[33] Strobel P, Lambert-Andron B. J. Solid State Chem., 1988, 75: 90-98
[34] Rossouw M R, Liles D C, Thackeray M M. J. Solid State Chem., 1993, 104: 464-466
[35] Johnson C S, Korte S D, Vaughey J T, Thackeray M M, Bofinger T E, Shao-Horn Y, Hackney S A. J. Power Sources, 1999, 81/82: 491-495
[36] Johnson C S, Thackeray M M. Proc. Electrochem. Soc., 2000, 36: 47
[37] Kim J S, Johnson C S, Thackeray M M. Electrochem. Commun., 2002, 4: 205-209
[38] Wu Y, Murugan A V, Manthiram A. J. Electrochem. Soc., 2008, 155: A635-A641
[39] Eriksson T, Gustafsson T, Thomas J O. Electrochem. Solid-State Lett., 2002, 5: A35-A38
[40] Sun X, Lee H S, Yang X Q, McBreen J. Electrochem. Solid-State Lett., 2001, 4: A184-A186
[41] Sun Y C, Wang Z X, Chen L Q, Huang X J. J. Electrochem. Soc., 2003, 150: A1294-A1298
[42] Padhi A K, Nanjundaswamy K S, Goodenough J B. J. Electrochem. Soc., 1997, 144: 1188-1194
[43] Prosini P P, Lisi M, Zane D, Pasquali M. Solid State Ionics, 2002, 148: 45-51
[44] Padhi A, Nanjundaswamy K, Okada S, Goodenough J B. J. Electrochem. Soc., 1997, 144: 1609-1613
[45] Andersson A S, Thomas J O. J. Power Sources, 2001, 97/98: 498-502
[46] Croce F, D’ Epifanio A, Scrossati B. Electrochem. Solid-State Lett., 2002, 5: A47-A50
[47] Ravet N, Chouinard Y, Magnan J F, Besner S, Gauthier M, Armand M. J. Power Sources, 2001, 97/98: 503-507
[48] Huang H, Yin S C, Nazar L F. Electrochem. Solid-State Lett., 2001, 4: A170-A172
[49] Hu Y S, Guo Y G, Dominko R, Gaberscek M, Jamnik J, Maier J. Adv. Mater., 2007, 19: 1963-1966
[50] Legagneur V, An Y, Mosbah A, Portal R, La Salle A L, Verbaere A, Guyomard D, Piffard Y. Solid State Ionics, 2001, 139: 37-46
[51] Allen J L, Xu K, Zhang S S, Jow T R. Materials Research Society Symposium Proceedings: Materials for Energy Storage, Generation and Transport (Eds. Schwarz R B, Ceder G, Ringgel S A), 2002, vol 730: 4-9
[52] Dong Y Z, Zhao Y M, Fu P, Zhou H, Hou X M, Journal of Alloys and Compounds, 2008, 461: 585-590
[53] Dong Y Z, Zhao Y M, Shi Z D, An X N, Fu P, Chen L. Electrochimica Acta, 2008, 53: 2339-2345
[54] Ellis B L, Makahnouk W R M, Makimura Y, Toghill K, Nazar L F. Nat. Mater., 2007, 6: 749-753
[55] Yamada A, Iwane N, Harada Y, Nishimura S, Koyama Y, Tanaka I. Adv. Mater., 2010, 22: 3583-3587
[56] Nyten A, Abouimrane A, Armand M, Gustafsson T, Thomas J O. Electrochem. Commun., 2005, 7: 156-160
[57] Recham N, Chotard J N, Dupont L, Delacourt C, Walker W, Armand M, Tarascon J M. Nature Mater., 2010, 9: 68-74
[58] Huang H, Yin S C, Kerr T, Taylor N, Nazar L F. Adv. Mater., 2002, 14: 1525-1528
[59] Fu P, Zhao Y M, An X N, Dong Y Z, Hou X M. Electrochim. Acta, 2007, 52: 5281-5285
[60] Yin S C, Herle P S, Higgins A, Taylor N J, Makimura Y, Nazar L F. Chem. Mater., 2006, 18: 1745-1752
[61] Makimura Y, Cahill L S, Iriyama Y, Goward G R, Nazar L F. Chem. Mater., 2008, 20: 4240-4248
[62] Jiang T, Pan W C, Wang J, Bie X F, Du F, Wei Y J, Wang C Z, Chen G. Electrochim. Acta, 2010, 55: 3864-3869
[63] Jiang T, Pan W C, Wang J, Bie X F, Du F, Wei Y J, Wang C Z, Chen G. Electrochim. Acta, 2010, 55: 3864-3869
[64] Shi S Q, Liu L J, Ouyang C Y, Wang D S, Wang Z X, Chen L Q, Huang X J. Phys. Rev. B, 2003, 68: Art. no. 195108
[65] Ouyang C Y, Shi S Q, Wang Z X, Huang X J, Chen L Q. Phys. Rev. B, 2004, 69: Art. no. 104303
[66] Zane D, Carewska M, Scaccia S, Cardellini F, Prosini P P. Electrochim. Acta, 2004, 13: 4259-4271
[67] Fisher C A J, Prieto V M H, Islam M S. Chem. Mater., 2008, 20: 5907-5915
[68] Zhou F, Kang K S, Maxisch T, Ceder G, Morgan D. Solid State Commun., 2004, 132: 181-186
[69] Amin R, Balaya P, Maier J. Electrochem. Solid State Lett., 2007, 10: A13-A16
[70] Ouyang C Y, Shi S Q, Wang Z X, Li H, Huang X J, Chen L Q. J. Phys. Condens. Matt., 2004, 16: 2265-2272
[71] 王德宇(Wang D Y). 中国科学院研究生院博士论文(Doctoral Dissertation of Graduate School of Chinese Academy of Sciences), 2005
[72] Ouyang C Y, Wang D Y, Shi S Q, Wang Z X, Li H, Huang X J, Chen L Q. Chin. Phys. Lett., 2006, 23: 61-64
[73] 欧阳楚英 (Ouyang C Y). 中国科学院研究生院博士论文(Doctoral Dissertation of Graduate School of Chinese Academy of Sciences), 2005
[74] Liu Z J, Huang X J, Wang D S. Solid State Commun., 2008, 147: 505-509
[75] Wang B, Chakoumakos B C, Sales B C, Kwak B S, Bates J B. J. Solid State Chem., 1995, 115: 313-323
[76] Wang X J, Yu X Q, Li H, Yang X Q, McBreen J, Huang X J. Electrochem. Commun., 2008, 10: 1347-1350
[77] McManis G E, Fletcher A N, Bliss D. E, Miles M H. J. Electroanal. Chem., 1985, 190: 171-183
[78] Aurbach D, Markovsky B, Levi M D, Schechter A, Moshkovich M, Cohen Y. J. Power Sources, 1999, 81/82: 95-111
[79] Ostrovskii D, Ronci F, Scrosati B, Jacobsson P. J. Power Sources, 2001, 103: 10-17
[80] Du Pasquier A, Blyr A, Courjal P, Cressent A, Lenain C, Amatucci G, Gerand B, Tarascon J M. J. Electrochem. Soc., 1999, 146: 428-436
[81] Du Pasquier A, Blyr A, Cressent A, Lenain C, Amatucci G, Tarascon J M. J. Power Sources, 1999, 81/82: 54-59
[82] Matsuo Y, Kostecki R, McLarnon F. J. Electrochem. Soc., 2001, 148: A687-A692
[83] Wang Z X, Huang X J, Chen L Q. J. Electrochem. Soc., 2003, 150: A199-A208
[84] Wang Z X, Liu L J, Chen L Q, Huang X J. Solid State Ionics, 2002, 148: 335-342
[85] Wang Z X, Chen L Q. J. Power Sources, 2005, 146: 254-258
[86] Wang Z X, Dong H, Chen L Q, Mo Y J, Huang X J. Solid State Ionics, 2004, 175: 239-242
[87] Wang Z X, Huang X J, Chen L Q. J. Electrochem. Soc., 2004, 151: A1641-A1652
[88] Wang Z X, Dong H, Huang X J, Mo Y J, Chen L Q. Electrochem. Solid-State Lett., 2004, 7: A353-A357
[89] Bai Y, Liu N, Liu J Y, Wang Z X, Chen L Q. Electrochem. Solid-State Lett., 2006, 9: A552-A556
[90] Iriyama Y, Kurita H, Yamada I, Abe T, Ogumi Z. J. Power Sources, 2004, 137: 111-116
[91] Oh S, Lee J K, Byun D, Cho Y I, Cho B W. J. Power Sources, 2004, 132: 249-255
[92] Gnanaraj J S, Pol V G, Gedanken A, Aurbach D. Electrochem. Commun., 2003, 5: 940-945
[93] Kweon H J, Park J, Seo J, Kim G, Jung B, Lim H S. J. Power Sources, 2004, 126: 156-162
[94] Cho J. Electrochim. Acta, 2003, 48: 2807-2811
[95] Cho J, Kim Y J, Park B. Chem. Mater., 2000, 12: 3788-3791
[96] Fang T, Duh T G, Sheen S R. J. Electrochem. Soc., 2005, 152: A1701-A1706
[97] Hong W, Chen M C. Electrochem. Solid-State Lett., 2006, 9: A82-A85
[98] Cho J, Kim Y J, Kim T J, Park B. Angew. Chem. Int. Ed., 2001, 40: 3367-3369
[99] Chen Z H, Dahn J R. Electrochim. Acta, 2004, 49: 1079-1090
[100] Cho J, Kim C S, Yoo S. Electrochem. Solid-State Lett., 2000, 3: 362-365
[101] Fey G T K, Muralidharan P, Lu C Z. Solid State Ionics, 2005, 176: 2759-2767
[102] Kim J S, Johnson C S, Vaughey J T, Hackney S A, Walz K A, Zeltner W A, Anderson M A, Thackeray M M. J. Electrochem. Soc., 2004, 151: A1755-A1761
[103] Kannan A M, Rabenberg L, Manthiram A. Electrochem. Solid-State Lett., 2003, 6: A16-A18
[104] Van Landschoot N, Kelder E M, Kooyman P J, Kwakernaak C, Schoonman J. J. Power Sources, 2004, 138: 262-270
[105] Liu J Y, Liu N, Liu D T, Bai Y, Shi L H, Wang Z X, Chen L Q, Hennige V, Schuch A. J. Electrochem. Soc., 2007, 154: A55-A63
[106] Boese O, Unger W E S, Kemnitz E, Schroeder S L M. Phys. Chem. Chem. Phys., 2002, 4: 2824-2832
[107] Xi J Y, Tang X Z. Chem. Phys. Lett., 2004, 393: 271-276
[108] Yang Z Y, Wang L, Drysdale N E. Macromolecules, 2003, 36: 8205-8207
[109] Bai Y, Shi H J, Wang Z X, Chen L Q. J. Power Sources, 2007, 167: 504-509
[110] Amine K, Tukamoto H, Yasuda H, Fujita Y. J. Electrochem. Soc., 1996, 143: 1607-1613
[111] Sun Y C, Wang Z X, Huang X J, Chen L Q. J. Power Sources, 2004, 132: 161-164
[112] Li G H, Azuma H, Tohda M. Electrochem. Solid-State Lett., 2002, 5: A135-A137
[113] Amine K, Yasuda H, Yamachi M. Electrochem. Solid-State Lett., 2000, 3: 178-179
[114] 王小建(Wang X J). 中国科学院研究生院博士学位论文 (Doctoral Dissertation of Graduate School of Chinese Academy of Sciences), 2008
[115] Zhou F, Cococcioni M, Kang K, Ceder G. Electrochem. Commun., 2004, 6: 1144-1148
[116] Armand M, Tarascon J M. Nature, 2008, 451: 652-657
[117] Li T, Li L, Cao Y L, Ai X P, Yang H X. J. Phys. Chem. C, 2010, 114: 3190-3195
[118] Amatucci G G, Pereira N. J. Fluor. Chem., 2007, 128: 243-262
[1] 牛文辉, 张达, 赵振刚, 杨斌, 梁风. 钠基-海水电池的发展:“关键部件及挑战”[J]. 化学进展, 2023, 35(3): 407-420.
[2] 朱国辉, 还红先, 于大伟, 郭学益, 田庆华. 废旧锂离子电池选择性提锂[J]. 化学进展, 2023, 35(2): 287-301.
[3] 邬学贤, 张岩, 叶淳懿, 张志彬, 骆静利, 符显珠. 面向电子应用的聚合物化学镀前表面处理技术[J]. 化学进展, 2023, 35(2): 233-246.
[4] 张永, 张辉, 张逸, 高蕾, 卢建臣, 蔡金明. 表面合成异质原子掺杂的石墨烯纳米带[J]. 化学进展, 2023, 35(1): 105-118.
[5] 李芳远, 李俊豪, 吴钰洁, 石凯祥, 刘全兵, 彭翃杰. “蛋黄蛋壳”结构纳米电极材料设计及在锂/钠离子/锂硫电池中的应用[J]. 化学进展, 2022, 34(6): 1369-1383.
[6] 李婧婧, 李洪基, 黄强, 陈哲. 掺杂对钠离子电池正极材料性能影响机制的研究[J]. 化学进展, 2022, 34(4): 857-869.
[7] 牛小连, 刘柯君, 廖子明, 徐慧伦, 陈维毅, 黄棣. 基于骨组织工程的静电纺纳米纤维[J]. 化学进展, 2022, 34(2): 342-355.
[8] 冯小琼, 马云龙, 宁红, 张世英, 安长胜, 李劲风. 铝离子电池中过渡金属硫族化合物正极材料[J]. 化学进展, 2022, 34(2): 319-327.
[9] 王才威, 杨东杰, 邱学青, 张文礼. 木质素多孔碳材料在电化学储能中的应用[J]. 化学进展, 2022, 34(2): 285-300.
[10] 孟鹏飞, 张笑容, 廖世军, 邓怡杰. 金属/非金属元素掺杂提升原子级分散碳基催化剂的氧还原性能[J]. 化学进展, 2022, 34(10): 2190-2201.
[11] 卢赟, 史宏娟, 苏岳锋, 赵双义, 陈来, 吴锋. 元素掺杂碳基材料在锂硫电池中的应用[J]. 化学进展, 2021, 33(9): 1598-1613.
[12] 陈阳, 崔晓莉. 锂离子电池二氧化钛负极材料[J]. 化学进展, 2021, 33(8): 1249-1269.
[13] 陆嘉晟, 陈嘉苗, 何天贤, 赵经纬, 刘军, 霍延平. 锂电池用无机固态电解质[J]. 化学进展, 2021, 33(8): 1344-1361.
[14] 高金伙, 阮佳锋, 庞越鹏, 孙皓, 杨俊和, 郑时有. 高电压锂离子正极材料LiNi0.5Mn1.5O4高温特性[J]. 化学进展, 2021, 33(8): 1390-1403.
[15] 赵依凡, 毛琦云, 翟晓雅, 张国英. 钼酸铋光催化剂的结构缺陷调控[J]. 化学进展, 2021, 33(8): 1331-1343.