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化学进展 2010, Vol. 22 Issue (12): 2353-2376 前一篇   后一篇

• 综述与评论 •

芴类蓝光生色团在合成有机电致发光材料中的应用

毛炳雪1, 张大鹏1, 华晓阳1, 姜鸿基1,2, 陈润锋1, 邓先宇1   

  1. 1. 有机电子与信息显示国家重点实验室培育基地信息材料与纳米技术研究院南京 邮电大学 南京 210046;
    2. 聚合物分子工程教育部重点实验室复旦大学 上海 200433
  • 出版日期:2010-12-24 发布日期:2010-11-04
  • 作者简介:e-mail:iamhjjiang@njupt.edu.cn
  • 基金资助:

    国家科技部重大科学研究计划(No.2009CB930600)、国家自然科学基金(No.20774043,60706017和20574012)、教育部重点项目(No.104246)、江苏省高校优秀科技创新团队项目(No.TJ207035和TJ209035)、复旦大学聚合物分子工程教育部重点实验室科研基金和南京邮电大学大学生科技创新训练计划(No.0703010123)资助

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Application of Fluorene-Based Blue Light-Emitting Chromophores in Synthesis of Organic Electroluminescent Materials*

Mao Bingxue1, Zhang Dapeng1, Hua Xiaoyang1, Jiang Hongji1,2, Chen Runfeng1, Deng Xianyu1   

  1. 1. Key Laboratory for Organic Electronics & Information Displays, Institute of Advanced Materials, Nanjing University of Posts & Telecommunications, Nanjing 210046, China;
    2. Key Laboratory of Molecular Engineering of Polymers, Ministry of Education, Fudan University, Shanghai 200433, China
  • Online:2010-12-24 Published:2010-11-04

有机电致发光技术在通信、信息、显示和照明等领域显现出巨大的商业应用前景, 十几年来一直是光电信息领域的研究热点之一。相对于无机电致发光材料,有机电致发光材料具有许多优点。芴作为一种具有刚性平面联苯结构的化合物,由于具有宽的能隙、高的发光效率和结构上易于修饰等特点,已成为一类受到各方关注的蓝光生色团。因此,芴类蓝光生色团在合成高效稳定电致蓝光材料、聚芴β相结构的调整、多功能化、主体材料、白光材料、有机激光及有机纳米发光材料等方面得到了广泛的应用。本文从材料合成的角度综述了芴类蓝光生色团在合成有机电致发光材料方面所取得的最新研究进展,讨论了芴类蓝光生色团在上述领域应用过程中所存在的问题和功能拓展方向,并对下一步需要研究的热点问题做了展望。

关键词： 芴, 电致发光, 生色团, 主体材料, 生色团, 纳米材料

The organic electroluminescence (EL) technology, which has been the research focus in the field of electro-optical information, holds a wide range of potential application in domains of communication, information, display and illumination and so on. Organic EL materials have many advantages when compared to their inorganic counterparts. Fluorene, as a kind of rigid plane biphenyl compound with wide band gap, high luminescent efficiency and high flexibility to modify the molecule skeleton, has been a key blue-emitting chromophore in organic EL. In this regard, fluorene-based blue-emitting materials are widely used in synthesis of highly efficient blue light-emitting materials, host materials, white light-emitting materials, organic lasers and organic nanomaterials, among which adjustment of the β phase structure and multiple functionalization are also main research directions. In this review paper, the applications of fluorene-based bule-emitting chromophores in organic EL are discussed in detail, and the progress of polyfluorene and its derivatives in the aspect of host materials and white materials is reviewed. Fluorene-based organic nanomaterials are concisely introduced. The synthesis methods of the polymers are also concisely introduced. Finally, some issues to be addressed and hotspots to be further investigated are discussed.

Contents
1 Introduction
2 Highly efficient fluorene-based blue light-emitting materials
2.1 Synthesis and applications in organic light-emitting diodes of highly efficient and stable fluorene-based materials
2.2 β-Phase of polyfluorenes and its applications
2.3 Synthesis and characterizations of multifunctional blue light-emitting polyfluorenes
3 Fluorene-based host materials
3.1 Characterizations of fluorene-based host materials
3.2 Highly efficient fluorene-based green light-emitting copolymers
3.3 Red light-emitting electrophosphorescent polyfluorenes
3.4 Red-green light-emitting by co-doping dyes in fluorene-based host materials
4 Fluorene-based white light-emitting materials
4.1 Fluorene-based white light-emitting from host–dopants system
4.2 Fluorene-based white light-emitting from blending trichromatic or dichromatic polymers
4.3 Fluorene-based white organic light-emitting diodes with stacked trichromatic or dichromatic multilayer structures
4.4 Fluorene-based single white light-emitting polymers
5 Fluorene-based luminescent conjugated nanomaterials
6 Conclusion and outlook

Key words: fluorene, electroluminescene, blue-light-emitting, host, white-light-emitting, nanomaterials

中图分类号: 

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