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化学进展 2010, Vol. 22 Issue (12): 2316-2327 前一篇   后一篇

• 综述与评论 •

基于离子液体电解液的有机电化学反应

褚道葆, 周莹, 张雪娇, 李艳, 宋奇   

  1. 安徽省功能性分子固体、分子基材料重点实验室,安徽师范大学化学与材料科学学院 芜湖 241000
  • 出版日期:2010-12-24 发布日期:2010-11-04
  • 作者简介:e-mail:dbchu@sina.com
  • 基金资助:

    国家自然科学基金(No. 20476001)、安徽省自然科学基金(No. 070414160)及高校自然科学重点基金(KJ2007A010)资助

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导出 被引次数 ( 15 | 1 )

Organic Electrochemical Reactions Based on Ionic Liquid Electrolytes

Chu Daobao, Zhou Ying, Zhang Xuejiao, Li Yan, Song Qi   

  1. Anhui Key Laboratory of Functional Molecular Solids and Molecular Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Wuhu 241000, China
  • Online:2010-12-24 Published:2010-11-04

室温离子液体(RTILs) 作为一类在室温时呈液态且具有良好导电性的新型绿色溶剂, 在有机电化学反应体系中的应用前景广阔。本文介绍了近年报道过的新型离子液体及离子液体电解液的特性,阐述了基于离子液体电解液的电化学实验方法,重点综述了离子液体中的各种有机电化学反应,包括电化学还原反应、CO2在离子液体中的电化学固定、电化学氧化反应、烯烃的环氧化、选择性氟化反应、偶联反应、功能化有机硅氧烷的合成、电化学氟化脱硫反应、电化学聚合反应等,并展望了发展趋势。

关键词： 有机电化学反应, 离子液体, 电合成, 电化学方法

Room-temperature ionic liquids (RTILs),as a class of novel  "green solvents" that exist in the liquid state around room-temperature and possess excellent ionic conductivity, have many promising applications in organic electrochemical reaction. In the review, new type of ionic liquids reported in recent years and the properties of ionic liquid electrolyte are described. The electrochemical experimental methods based on ionic liquid electrolyte are also discussed. Various organic electrochemical reactions in ionic liquid,including electrochemical reduction, electroreduction fixation of CO2, electrochemical oxidation, olefin epoxidation, selective fluorination reaction, coupling reaction,the synthesis of functional organic siloxane, electrochemical fluorination desulfurization,electrochemical polymerization reaction, etc, are reviewed specifically, and the development trend is given.

Contents
1 Introduction
2 The new ionic liquids
3 Properties of ionic liquid electrolytes
3.1 Viscosity
3.2 Conductivity
3.3 Diffusion of electroactive solutes
3.4 Effects of impurities
3.5 Electrochemical windows
4 The experimental methods based on ionic liquid electrolytes
5 Organic electrochemical reactions in ionic liquids
5.1 Electrochemical reduction
5.2 Fixation of CO2 in ionic liquids
5.3 Electrochemical oxidation
5.4 Olefin epoxidation
5.5 Selective fluorination reaction
5.6 Coupling reaction
5.7 The synthesis of functional organic siloxane
5.8 Electrochemical fluorination desulfurization
5.9 Electrochemical polymerization reaction
6 Conclusion and perspective

Key words: organic electrochemical reactions, ionic liquids, electrosynthesis, electrochemical methods

中图分类号: 

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